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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Sulfonylbut-1-ene —— C4H6O2S
    4-Sulfonylbut-1-ene
    —— 1-Ethyl-3-methylsulfanylpyrrole-2,5-diol —— C7H11NO2S
    1-Ethyl-3-methylsulfanylpyrrole-2,5-diol
    —— 4-(2-tert-butyl-4,5-dichlorophenyl)-3-[5-(trifluoromethyl)pyridin-2-yl]sulfanyl-1H-1,2,4-triazol-5-one —— C18H15Cl2F3N4OS
    4-(2-tert-butyl-4,5-dichlorophenyl)-3-[5-(trifluoromethyl)pyridin-2-yl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 1-Benzyl-4-(3,5-dichlorophenyl)sulfanyl-3-propan-2-yl-5-[[2-(pyridin-4-ylmethyl)pyrrol-2-yl]methyl]imidazol-2-one —— C30H28Cl2N4OS
    1-Benzyl-4-(3,5-dichlorophenyl)sulfanyl-3-propan-2-yl-5-[[2-(pyridin-4-ylmethyl)pyrrol-2-yl]methyl]imidazol-2-one
    —— 5-[[4-Chloro-2-(1-methylimidazol-2-yl)sulfanyl-1,3-thiazol-5-yl]methylidene]-1-(4-chlorophenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione —— C18H11Cl2N5O2S3
    5-[[4-Chloro-2-(1-methylimidazol-2-yl)sulfanyl-1,3-thiazol-5-yl]methylidene]-1-(4-chlorophenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 3-Methyl-4-(3-methyl-1,2-oxazol-5-yl)-5-methylsulfanylthiophene-2-carbonitrile;3-methyl-4-(5-methyl-1,2-oxazol-3-yl)-5-methylsulfanylthiophene-2-carbonitrile —— C22H20N4O2S4
    3-Methyl-4-(3-methyl-1,2-oxazol-5-yl)-5-methylsulfanylthiophene-2-carbonitrile;3-methyl-4-(5-methyl-1,2-oxazol-3-yl)-5-methylsulfanylthiophene-2-carbonitrile
    —— 1-Amino-3-[2-methyl-5-(2-propylpentylsulfanyl)phenyl]propan-2-ol —— C18H31NOS
    1-Amino-3-[2-methyl-5-(2-propylpentylsulfanyl)phenyl]propan-2-ol
    —— 2-(4-methylsulfanylphenyl)-6,7-dihydro-4H-[1,3]thiazolo[5,4-c]pyridine-5-carboxylic acid —— C14H14N2O2S2
    2-(4-methylsulfanylphenyl)-6,7-dihydro-4H-[1,3]thiazolo[5,4-c]pyridine-5-carboxylic acid
    —— 2-[4-(2,4-Dibromophenyl)thiadiazol-5-yl]sulfanylacetamide —— C10H7Br2N3OS2
    2-[4-(2,4-Dibromophenyl)thiadiazol-5-yl]sulfanylacetamide
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-(2-thiophen-2-ylethyl)-7H-purin-3-ium-6-amine —— C18H15BrN5O2S2+
    8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-(2-thiophen-2-ylethyl)-7H-purin-3-ium-6-amine
    —— 2-[5-(hydroxyamino)-5-oxopentoxy]-N-methyl-6-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide —— C27H27N5O4S
    2-[5-(hydroxyamino)-5-oxopentoxy]-N-methyl-6-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide
    —— 5-[[4-chloro-5-methyl-2-[(4-methylphenyl)sulfanylmethylidene]-1H-pyrrol-3-ylidene]methyl]-6-hydroxy-1-prop-2-enyl-2-sulfanylidenepyrimidin-4-one —— C21H20ClN3O2S2
    5-[[4-chloro-5-methyl-2-[(4-methylphenyl)sulfanylmethylidene]-1H-pyrrol-3-ylidene]methyl]-6-hydroxy-1-prop-2-enyl-2-sulfanylidenepyrimidin-4-one
    —— 6-(3-ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)-N-(6-hydroxyhexyl)hexanamide —— C18H32N2O4S
    6-(3-ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)-N-(6-hydroxyhexyl)hexanamide
    —— 4-methoxy-3-(4-methylsulfanylphenyl)-2H-furan-5-one;(4-methylsulfanylphenyl)boronic acid —— C19H21BO5S2
    4-methoxy-3-(4-methylsulfanylphenyl)-2H-furan-5-one;(4-methylsulfanylphenyl)boronic acid
    —— Methyl 2-chloro-2-pyridin-2-ylsulfanylacetate —— C8H8ClNO2S
    Methyl 2-chloro-2-pyridin-2-ylsulfanylacetate
    —— 4-[(2R,3S)-3-(4-fluorophenyl)-3-[(5-methylsulfanyl-1,2,4-triazol-1-yl)methyl]oxiran-2-yl]pyridine —— C17H15FN4OS
    4-[(2R,3S)-3-(4-fluorophenyl)-3-[(5-methylsulfanyl-1,2,4-triazol-1-yl)methyl]oxiran-2-yl]pyridine
    —— 2-Methylsulfanylpyridine-3,4-dicarbonitrile —— C8H5N3S
    2-Methylsulfanylpyridine-3,4-dicarbonitrile
    —— 1,1,1-Trifluoro-4-methylsulfanylbut-2-ene —— C5H7F3S
    1,1,1-Trifluoro-4-methylsulfanylbut-2-ene
    —— 4-[[2-(4-Aminophenyl)sulfanylpyridin-3-yl]methyl]pyrimidin-2-amine —— C16H15N5S
    4-[[2-(4-Aminophenyl)sulfanylpyridin-3-yl]methyl]pyrimidin-2-amine
    —— S-phenyl N-(2-methoxyethyl)-N-methylcarbamothioate —— C11H15NO2S
    S-phenyl N-(2-methoxyethyl)-N-methylcarbamothioate
    —— 2-But-2-enyl-2-[[4-(trifluoromethylsulfanyl)phenyl]methyl]propanedinitrile —— C15H13F3N2S
    2-But-2-enyl-2-[[4-(trifluoromethylsulfanyl)phenyl]methyl]propanedinitrile
    —— (3R,4aS,8aS)-3-methyl-1,2,3,4,4a,5,6,7,8,8a-decahydroisoquinoline;methyl N-[(2R)-4-chloro-3-hydroxy-1-phenylsulfanylbutan-2-yl]carbamate —— C22H35ClN2O3S
    (3R,4aS,8aS)-3-methyl-1,2,3,4,4a,5,6,7,8,8a-decahydroisoquinoline;methyl N-[(2R)-4-chloro-3-hydroxy-1-phenylsulfanylbutan-2-yl]carbamate
    —— 2-[(4-Amino-1-methyl-2-methylsulfanyl-6-oxopyrimidin-5-yl)methyl]-5,5-dimethylcyclohexane-1,3-dione —— C15H21N3O3S
    2-[(4-Amino-1-methyl-2-methylsulfanyl-6-oxopyrimidin-5-yl)methyl]-5,5-dimethylcyclohexane-1,3-dione
    —— 2-Methylsulfonyl-6-phenyl-2-prop-2-ynoxyhexanamide —— C16H21NO4S
    2-Methylsulfonyl-6-phenyl-2-prop-2-ynoxyhexanamide
    —— Ethenylidene-ethyl-ethyl-methylidene-lambda6-sulfane —— C7H13S-
    Ethenylidene-ethyl-ethyl-methylidene-lambda6-sulfane
    —— ethyl 6-propylspiro[1,5-dihydropyrazolo[3,4-b]pyridine-4,3'-2H-1-benzothiophene]-5-carboxylate —— C19H21N3O2S
    ethyl 6-propylspiro[1,5-dihydropyrazolo[3,4-b]pyridine-4,3'-2H-1-benzothiophene]-5-carboxylate
    —— 3-Amino-1-[3-(cyclohexylmethylsulfanyl)phenyl]propane-1,1-diol —— C16H25NO2S
    3-Amino-1-[3-(cyclohexylmethylsulfanyl)phenyl]propane-1,1-diol
    —— S-[4-chloro-6-[(4-fluorophenyl)methylamino]pyrimidin-2-yl] ethanethioate —— C13H11ClFN3OS
    S-[4-chloro-6-[(4-fluorophenyl)methylamino]pyrimidin-2-yl] ethanethioate
    —— 2-(Hydroxymethyl)icosa-4,8,11,14,17-pentaenethial —— C21H32OS
    2-(Hydroxymethyl)icosa-4,8,11,14,17-pentaenethial
    —— (2S,6S)-N-(cyanomethyl)-3-[(4-fluorophenyl)sulfanylmethyl]bicyclo[4.1.0]heptane-2-carboxamide —— C17H19FN2OS
    (2S,6S)-N-(cyanomethyl)-3-[(4-fluorophenyl)sulfanylmethyl]bicyclo[4.1.0]heptane-2-carboxamide
    —— 3-Octoxy-4-phenylsulfanylphenol —— C20H26O2S
    3-Octoxy-4-phenylsulfanylphenol
    —— 2-Dodecyl-3-sulfanylcyclopropane-1-thione —— C15H28S2
    2-Dodecyl-3-sulfanylcyclopropane-1-thione
    —— 1-Propoxyethanethiol —— C5H12OS
    1-Propoxyethanethiol
    —— Methanethiol;1-tritiobut-1-yne —— C5H10S
    Methanethiol;1-tritiobut-1-yne
    —— Tridecane-1,7-dithiol —— C13H28S2
    Tridecane-1,7-dithiol
    —— N,N-diethyl-2-[(Z)-[(5-ethyl-1,3-thiazol-2-yl)-[3-(trifluoromethylsulfanyl)phenyl]methylidene]amino]oxypropan-1-amine —— C20H26F3N3OS2
    N,N-diethyl-2-[(Z)-[(5-ethyl-1,3-thiazol-2-yl)-[3-(trifluoromethylsulfanyl)phenyl]methylidene]amino]oxypropan-1-amine
    —— methyl (1E)-N-[tert-butylsulfanylsulfinyl(methyl)carbamoyl]oxyethanimidothioate —— C9H18N2O3S3
    methyl (1E)-N-[tert-butylsulfanylsulfinyl(methyl)carbamoyl]oxyethanimidothioate
    —— Butan-2-yl-tert-butyl-dihydroxy-lambda4-sulfane —— C8H20O2S
    Butan-2-yl-tert-butyl-dihydroxy-lambda4-sulfane
    —— 4-methyl-2-[(5-methyl-4-prop-1-enylpyridin-3-yl)methylsulfanyl]-1H-pyrimidin-6-one —— C15H17N3OS
    4-methyl-2-[(5-methyl-4-prop-1-enylpyridin-3-yl)methylsulfanyl]-1H-pyrimidin-6-one
    —— 3,3,4,4-Tetramethylhept-6-ene-2-thiol —— C11H21S-
    3,3,4,4-Tetramethylhept-6-ene-2-thiol
    —— 3-(3-Amino-2-hydroperoxypropyl)sulfinyl-2-iminopropanoic acid —— C6H12N2O5S
    3-(3-Amino-2-hydroperoxypropyl)sulfinyl-2-iminopropanoic acid
    —— tert-butyl (4S)-4-[(2R)-2-(2-amino-5-cyanopyridin-4-yl)sulfanyl-2-phenylethyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate —— C24H30N4O3S
    tert-butyl (4S)-4-[(2R)-2-(2-amino-5-cyanopyridin-4-yl)sulfanyl-2-phenylethyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
    —— 3-Cyanopropyl ethanimidothioate —— C6H10N2S
    3-Cyanopropyl ethanimidothioate
    —— (2Z)-2-[amino(methoxy)methylidene]-1-benzothiophen-3-one —— C10H9NO2S
    (2Z)-2-[amino(methoxy)methylidene]-1-benzothiophen-3-one
    —— (2Z)-2-[amino-[2-(dimethylamino)ethylamino]methylidene]-1-benzothiophen-3-one —— C13H17N3OS
    (2Z)-2-[amino-[2-(dimethylamino)ethylamino]methylidene]-1-benzothiophen-3-one
    —— 2,3-Dimethyl-3-(3-methylphenyl)sulfanylbutan-2-ol;ethane —— C15H26OS
    2,3-Dimethyl-3-(3-methylphenyl)sulfanylbutan-2-ol;ethane
    —— 2-Tert-butyl-4-(5-tert-butyl-4-ethyl-2-methylphenyl)sulfanyl-5-methylphenol —— C24H34OS
    2-Tert-butyl-4-(5-tert-butyl-4-ethyl-2-methylphenyl)sulfanyl-5-methylphenol
    —— 2-ethylsulfanyl-N-(5-methyl-2-phenylsulfanylphenyl)pyrimido[4,5-d]pyrimidin-5-amine —— C21H19N5S2
    2-ethylsulfanyl-N-(5-methyl-2-phenylsulfanylphenyl)pyrimido[4,5-d]pyrimidin-5-amine
    —— (2Z)-2-[amino-[2-(diethylamino)ethylamino]methylidene]-1-benzothiophen-3-one —— C15H21N3OS
    (2Z)-2-[amino-[2-(diethylamino)ethylamino]methylidene]-1-benzothiophen-3-one
    —— 3-ethylsulfanylprop-1-ene —— C5H9S-
    3-ethylsulfanylprop-1-ene