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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(Phenylsulfanylmethyl)piperidin-1-ium —— C12H18NS+
    1-(Phenylsulfanylmethyl)piperidin-1-ium
    —— (2S)-1-(diethylamino)-3-thiophen-2-ylsulfanylpropan-2-ol —— C11H19NOS2
    (2S)-1-(diethylamino)-3-thiophen-2-ylsulfanylpropan-2-ol
    —— (2S)-1-pyrrolidin-1-ium-1-yl-3-thiophen-2-ylsulfanylpropan-2-ol —— C11H18NOS2+
    (2S)-1-pyrrolidin-1-ium-1-yl-3-thiophen-2-ylsulfanylpropan-2-ol
    —— (2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetate —— C12H10NO2S2-
    (2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetate
    —— (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetate —— C12H10NO2S2-
    (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetate
    —— [(4-Methyl-1,3-thiazol-2-yl)sulfanyl]acetate —— C6H6NO2S2-
    [(4-Methyl-1,3-thiazol-2-yl)sulfanyl]acetate
    —— (2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetic acid —— C12H11NO2S2
    (2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetic acid
    —— (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetic acid —— C12H11NO2S2
    (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-2-phenylacetic acid
    —— 2-[(5-Phenyl-1,2,4-triazin-3-yl)sulfanyl]acetate —— C11H8N3O2S-
    2-[(5-Phenyl-1,2,4-triazin-3-yl)sulfanyl]acetate
    —— 3-[(2-ethylphenyl)methylsulfanyl]-4-[(1R)-1-phenylethyl]-1H-1,2,4-triazol-5-one —— C19H21N3OS
    3-[(2-ethylphenyl)methylsulfanyl]-4-[(1R)-1-phenylethyl]-1H-1,2,4-triazol-5-one
    —— 3-[(2-ethylphenyl)methylsulfanyl]-4-[(1S)-1-phenylethyl]-1H-1,2,4-triazol-5-one —— C19H21N3OS
    3-[(2-ethylphenyl)methylsulfanyl]-4-[(1S)-1-phenylethyl]-1H-1,2,4-triazol-5-one
    —— (2S)-2-phenyl-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetate —— C17H12N3O2S-
    (2S)-2-phenyl-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetate
    —— (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylacetic acid —— C11H10N2O2S2
    (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylacetic acid
    —— [(4,6-Dimethylpyrimidin-2-yl)sulfanyl](phenyl)acetate 87125-95-9 C14H13N2O2S-
    [(4,6-Dimethylpyrimidin-2-yl)sulfanyl](phenyl)acetate
    —— (2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-phenylacetate —— C14H13N2O2S-
    (2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-phenylacetate
    —— (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylacetate —— C11H9N2O2S2-
    (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylacetate
    —— 3-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-4-[(1S)-1-phenylethyl]-1H-1,2,4-triazol-5-one —— C16H20N4O3S
    3-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-4-[(1S)-1-phenylethyl]-1H-1,2,4-triazol-5-one
    —— 2-(4-Methylpyrimidin-2-yl)sulfanylacetate —— C7H7N2O2S-
    2-(4-Methylpyrimidin-2-yl)sulfanylacetate
    —— 3-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-4-[(1R)-1-phenylethyl]-1H-1,2,4-triazol-5-one —— C16H20N4O3S
    3-(2-morpholin-4-yl-2-oxoethyl)sulfanyl-4-[(1R)-1-phenylethyl]-1H-1,2,4-triazol-5-one
    —— (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid —— C11H11N3O2S
    (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid
    —— (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-2-phenylacetic acid —— C10H10N4O2S
    (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-2-phenylacetic acid
    —— (2S)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylacetate —— C11H9N2O2S2-
    (2S)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-2-phenylacetate
    —— (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetate —— C11H10N3O2S-
    (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetate
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid —— C11H11N3O2S
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetic acid
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetate —— C11H10N3O2S-
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylacetate
    —— (7S)-7-methyl-4-phenylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C17H16N2S2
    (7S)-7-methyl-4-phenylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 5-Methyl-2,3-dihydropyrrolo[2,1-b][1,3]thiazole-6,7-dicarboxylate —— C9H7NO4S-2
    5-Methyl-2,3-dihydropyrrolo[2,1-b][1,3]thiazole-6,7-dicarboxylate
    —— 2-[5-[2-(4-Methylphenyl)sulfanylacetyl]thiophen-2-yl]acetate —— C15H13O3S2-
    2-[5-[2-(4-Methylphenyl)sulfanylacetyl]thiophen-2-yl]acetate
    —— 3-[[5-(2,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C13H15N3O2S2
    3-[[5-(2,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-[[5-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C9H15N3O3S3
    2-[[5-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 1,3-Dimethyl-4-(4-methylphenyl)sulfanylpyrazolo[3,4-b]pyridine-5-carboxylate —— C16H14N3O2S-
    1,3-Dimethyl-4-(4-methylphenyl)sulfanylpyrazolo[3,4-b]pyridine-5-carboxylate
    —— 2-[[5-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C9H15N3O3S3
    2-[[5-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 3-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C13H15N3O2S2
    3-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 5-(2-aminoethylsulfanyl)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-1,3,4-thiadiazol-2-amine —— C9H16N4O2S3
    5-(2-aminoethylsulfanyl)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— 5-(2-aminoethylsulfanyl)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-1,3,4-thiadiazol-2-amine —— C9H16N4O2S3
    5-(2-aminoethylsulfanyl)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— 2-[5-(2-Phenylsulfanylacetyl)thiophen-2-yl]acetate —— C14H11O3S2-
    2-[5-(2-Phenylsulfanylacetyl)thiophen-2-yl]acetate
    —— 5-(2-aminoethylsulfanyl)-N-(2,6-diethylphenyl)-1,3,4-thiadiazol-2-amine —— C14H20N4S2
    5-(2-aminoethylsulfanyl)-N-(2,6-diethylphenyl)-1,3,4-thiadiazol-2-amine
    —— (5S)-3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-5-phenylcyclohex-2-en-1-one —— C15H14N2OS3
    (5S)-3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-5-phenylcyclohex-2-en-1-one
    —— [2-[1-(3-methoxypropyl)-2,5-dimethylpyrrol-3-yl]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C21H27NO4S
    [2-[1-(3-methoxypropyl)-2,5-dimethylpyrrol-3-yl]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— (2S)-2-[2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1-methylpiperidine —— C15H22N4OS
    (2S)-2-[2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1-methylpiperidine
    —— [(2S)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropyl]-dimethylazanium —— C11H20N3S+
    [(2S)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropyl]-dimethylazanium
    —— 2-[2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium —— C17H17ClFN2S+
    2-[2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium
    —— (3S)-3-(2-aminophenyl)sulfanyl-1,3-dithiophen-2-ylpropan-1-one —— C17H15NOS3
    (3S)-3-(2-aminophenyl)sulfanyl-1,3-dithiophen-2-ylpropan-1-one
    —— 2-Amino-6-methylsulfanylpyridin-1-ium-3,5-dicarbonitrile —— C8H7N4S+
    2-Amino-6-methylsulfanylpyridin-1-ium-3,5-dicarbonitrile
    —— 2-[2-[(2,6-Difluorophenyl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium —— C17H17F2N2S+
    2-[2-[(2,6-Difluorophenyl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium
    —— methyl (2R)-2-cyano-3-oxobutanimidothioate —— C6H8N2OS
    methyl (2R)-2-cyano-3-oxobutanimidothioate
    —— 2-[2-[(2-Fluoro-3-methylphenyl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium —— C18H20FN2S+
    2-[2-[(2-Fluoro-3-methylphenyl)methylsulfanyl]phenyl]-1,4,5,6-tetrahydropyrimidin-3-ium
    —— 2-(3-Chloro-2-methylphenyl)sulfanylacetate —— C9H8ClO2S-
    2-(3-Chloro-2-methylphenyl)sulfanylacetate
    —— 4,6-Dimethyl-2-(2-piperidin-1-ium-1-ylethylsulfanyl)pyridine-3-carbonitrile —— C15H22N3S+
    4,6-Dimethyl-2-(2-piperidin-1-ium-1-ylethylsulfanyl)pyridine-3-carbonitrile
    —— 2-[(4-Methylphenyl)sulfanyl]pyridine-3-carboxylate 955-53-3 C13H10NO2S-
    2-[(4-Methylphenyl)sulfanyl]pyridine-3-carboxylate