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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-2-amino-3-[[2-(4-chlorophenyl)sulfanylphenyl]methylamino]but-2-enedinitrile —— C17H13ClN4S
    (Z)-2-amino-3-[[2-(4-chlorophenyl)sulfanylphenyl]methylamino]but-2-enedinitrile
    —— (3Z,7E,11E,15Z)-1,2,5,6,9,10,13,14-octathiacyclohexadeca-3,7,11,15-tetraene —— C8H8S8
    (3Z,7E,11E,15Z)-1,2,5,6,9,10,13,14-octathiacyclohexadeca-3,7,11,15-tetraene
    —— 4-Hydroxy-5-[3-(4-phenylmethoxyphenyl)sulfanylfuran-2-yl]-1,3-dihydroimidazol-2-one —— C20H16N2O4S
    4-Hydroxy-5-[3-(4-phenylmethoxyphenyl)sulfanylfuran-2-yl]-1,3-dihydroimidazol-2-one
    —— 1-Butylsulfanyl-5-methylsulfanylpentane —— C10H22S2
    1-Butylsulfanyl-5-methylsulfanylpentane
    —— N-[(4-bromothiophen-2-yl)methyl]-4-(4-fluorophenyl)sulfanylpentanamide —— C16H17BrFNOS2
    N-[(4-bromothiophen-2-yl)methyl]-4-(4-fluorophenyl)sulfanylpentanamide
    —— Butylsulfonyl-[diethyl(2-oxobutyl)-lambda4-sulfanyl]oxidanium —— C12H27O4S2+
    Butylsulfonyl-[diethyl(2-oxobutyl)-lambda4-sulfanyl]oxidanium
    —— (5E)-5-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(3-methoxypropyl)-1,3-thiazolidine-2,4-dione —— C18H15BrClNO4S2
    (5E)-5-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(3-methoxypropyl)-1,3-thiazolidine-2,4-dione
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-[3-cyano-4-(methoxymethyl)-6-methyl-2-oxopyridin-1-yl]acetamide —— C24H20ClN5O5S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-[3-cyano-4-(methoxymethyl)-6-methyl-2-oxopyridin-1-yl]acetamide
    —— 2-(Methylsulfinylmethyl)thiirane —— C4H8OS2
    2-(Methylsulfinylmethyl)thiirane
    —— (E)-3-(2-methylsulfanylthiophen-3-yl)-2-(thiophene-2-carbonyl)prop-2-enenitrile —— C13H9NOS3
    (E)-3-(2-methylsulfanylthiophen-3-yl)-2-(thiophene-2-carbonyl)prop-2-enenitrile
    —— 1-Amino-4-(1-aminoethylamino)butane-1-thiol —— C6H17N3S
    1-Amino-4-(1-aminoethylamino)butane-1-thiol
    —— [4-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidin-1-yl]-[1-(trifluoromethyl)cyclopropyl]methanone —— C24H25BrF3N6O3S+
    [4-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidin-1-yl]-[1-(trifluoromethyl)cyclopropyl]methanone
    —— 3-Fluoro-2-(2-methylbutan-2-yl)-6-methylsulfanylpyridine —— C11H16FNS
    3-Fluoro-2-(2-methylbutan-2-yl)-6-methylsulfanylpyridine
    —— 4-[3-(3-Ethylsulfanyl-4-methylphenyl)-1,2,4-triazol-3-yl]pyridine —— C16H16N4S
    4-[3-(3-Ethylsulfanyl-4-methylphenyl)-1,2,4-triazol-3-yl]pyridine
    —— N-[(2-chloro-6-fluorophenyl)methyl]-4-(4-hydroxyphenyl)sulfanylpentanamide —— C18H19ClFNO2S
    N-[(2-chloro-6-fluorophenyl)methyl]-4-(4-hydroxyphenyl)sulfanylpentanamide
    —— (2E)-2-(1H-benzimidazol-2-yl)-3-{5-[(4-chlorophenyl)sulfanyl]thiophen-2-yl}prop-2-enenitrile —— C20H12ClN3S2
    (2E)-2-(1H-benzimidazol-2-yl)-3-{5-[(4-chlorophenyl)sulfanyl]thiophen-2-yl}prop-2-enenitrile
    —— 3-[5-[2-(Azepan-2-yl)ethylsulfanyl]-1,3-thiazol-2-yl]-1,1-dicyclohexylurea —— C24H40N4OS2
    3-[5-[2-(Azepan-2-yl)ethylsulfanyl]-1,3-thiazol-2-yl]-1,1-dicyclohexylurea
    —— N-chloro-4-phenylsulfanylaniline —— C12H10ClNS
    N-chloro-4-phenylsulfanylaniline
    —— 1-Methylsulfanylpentadec-1-ene —— C16H32S
    1-Methylsulfanylpentadec-1-ene
    —— 2-Fluoro-1-(2-fluorobut-1-enyldisulfanyl)but-1-ene —— C8H12F2S2
    2-Fluoro-1-(2-fluorobut-1-enyldisulfanyl)but-1-ene
    —— (6S,9R)-6-methyl-9-(4-methylsulfanylphenyl)-5-(2-phenylethynyl)-8-oxatetracyclo[8.8.0.02,6.011,16]octadeca-4,10,16-trien-14-one —— C33H32O2S
    (6S,9R)-6-methyl-9-(4-methylsulfanylphenyl)-5-(2-phenylethynyl)-8-oxatetracyclo[8.8.0.02,6.011,16]octadeca-4,10,16-trien-14-one
    —— 8-(4-chlorophenyl)sulfanyl-3-(2-phenylethyl)-7H-purin-3-ium-6-amine —— C19H17ClN5S+
    8-(4-chlorophenyl)sulfanyl-3-(2-phenylethyl)-7H-purin-3-ium-6-amine
    —— 5-Sulfanylpentanethial —— C5H10S2
    5-Sulfanylpentanethial
    —— [(Z)-[5-(2-methoxycarbonylphenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylideneamino] 2,4-dichlorobenzoate —— C21H14Cl2F3N3O4S
    [(Z)-[5-(2-methoxycarbonylphenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylideneamino] 2,4-dichlorobenzoate
    —— 2-methyl-1-methylsulfanylpropane —— C5H11S-
    2-methyl-1-methylsulfanylpropane
    —— Butylsulfonyl-[diethyl(2-oxohexyl)-lambda4-sulfanyl]oxidanium —— C14H31O4S2+
    Butylsulfonyl-[diethyl(2-oxohexyl)-lambda4-sulfanyl]oxidanium
    —— 1-acetyl-N-[4-[4-methyl-2-[(7-methyl-1,8-naphthyridin-4-yl)amino]phenyl]sulfanylphenyl]piperidine-4-carboxamide —— C30H31N5O2S
    1-acetyl-N-[4-[4-methyl-2-[(7-methyl-1,8-naphthyridin-4-yl)amino]phenyl]sulfanylphenyl]piperidine-4-carboxamide
    —— 2-Ethyl-4-methyl-6-(methylsulfanylmethylsulfanyl)pyrimidine —— C9H14N2S2
    2-Ethyl-4-methyl-6-(methylsulfanylmethylsulfanyl)pyrimidine
    —— 2-(4-methylpiperazin-1-yl)-6-phenylsulfanyl-N-(5-pyridin-2-yl-1H-pyrazol-3-yl)-1,4-dihydro-1,3,5-triazin-4-amine —— C22H25N9S
    2-(4-methylpiperazin-1-yl)-6-phenylsulfanyl-N-(5-pyridin-2-yl-1H-pyrazol-3-yl)-1,4-dihydro-1,3,5-triazin-4-amine
    —— Methyl 2-[[4-chloro-5-(2,6-dioxocyclohexanecarbonyl)-2,3-dihydro-1-benzothiophen-2-yl]sulfanyl]acetate —— C18H17ClO5S2
    Methyl 2-[[4-chloro-5-(2,6-dioxocyclohexanecarbonyl)-2,3-dihydro-1-benzothiophen-2-yl]sulfanyl]acetate
    —— Ethane;3-methyl-6-phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazine —— C14H16N4S
    Ethane;3-methyl-6-phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— 2,2-Bis(methylsulfanyl)oct-3-yne —— C10H18S2
    2,2-Bis(methylsulfanyl)oct-3-yne
    —— N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-3-(trifluoromethyl)benzamide —— C19H12ClF3N2O2S
    N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-3-(trifluoromethyl)benzamide
    —— N-ethoxy-2-fluoro-6-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide —— C23H19FN4O2S
    N-ethoxy-2-fluoro-6-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide
    —— 3-(2-propan-2-ylphenyl)sulfanyl-1H-indol-4-ol —— C17H17NOS
    3-(2-propan-2-ylphenyl)sulfanyl-1H-indol-4-ol
    —— 3-[2-(2,4-dichlorophenyl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine —— C21H20Cl2N5O2S+
    3-[2-(2,4-dichlorophenyl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine
    —— 4-Hydroxy-4-phenylsulfanylbutanoic acid —— C10H12O3S
    4-Hydroxy-4-phenylsulfanylbutanoic acid
    —— methyl 2-[4-[(Z)-(2,4-dichlorophenyl)methoxyiminomethyl]-2-methyl-5-(trifluoromethyl)pyrazol-3-yl]sulfanylbenzoate —— C21H16Cl2F3N3O3S
    methyl 2-[4-[(Z)-(2,4-dichlorophenyl)methoxyiminomethyl]-2-methyl-5-(trifluoromethyl)pyrazol-3-yl]sulfanylbenzoate
    —— (2E)-3-{4-bromo-5-[(4-methylphenyl)sulfanyl]furan-2-yl}-2-cyano-N-(2,4-dimethylphenyl)prop-2-enamide —— C23H19BrN2O2S
    (2E)-3-{4-bromo-5-[(4-methylphenyl)sulfanyl]furan-2-yl}-2-cyano-N-(2,4-dimethylphenyl)prop-2-enamide
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-pyridin-3-ylethylideneamino]acetamide —— C19H19N5OS3
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-pyridin-3-ylethylideneamino]acetamide
    —— 5-[[4-Chloro-2-(3-methylphenyl)sulfanyl-1,3-thiazol-5-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione —— C18H14ClN3O2S3
    5-[[4-Chloro-2-(3-methylphenyl)sulfanyl-1,3-thiazol-5-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 1-hydroxypropan-2-yl N'-methylcarbamimidothioate —— C5H12N2OS
    1-hydroxypropan-2-yl N'-methylcarbamimidothioate
    —— N-[4-[(Z)-[5-(4-bromophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methoxyiminomethyl]phenyl]acetamide —— C21H18BrF3N4O2S
    N-[4-[(Z)-[5-(4-bromophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methoxyiminomethyl]phenyl]acetamide
    —— 3-butyl-5,5-dimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-1,3-thiazolidine-2-thione —— C17H24N2OS3
    3-butyl-5,5-dimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-1,3-thiazolidine-2-thione
    —— ethyl (2Z)-2-benzylidene-7-methyl-5-(4-methylsulfanylphenyl)-3,5-dihydro-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H24N2O2S2
    ethyl (2Z)-2-benzylidene-7-methyl-5-(4-methylsulfanylphenyl)-3,5-dihydro-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(2-methoxypyridin-4-yl)methyl]-8H-pyrimido[5,4-b][1,4]thiazine-6-carboxamide —— C14H13N5O2S
    N-[(2-methoxypyridin-4-yl)methyl]-8H-pyrimido[5,4-b][1,4]thiazine-6-carboxamide
    —— 6-(2,6-dimethylmorpholin-4-yl)-2-N-(3-fluoro-4-pyridin-4-ylsulfanylphenyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidine-2,4-diamine —— C24H27FN6OS
    6-(2,6-dimethylmorpholin-4-yl)-2-N-(3-fluoro-4-pyridin-4-ylsulfanylphenyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidine-2,4-diamine
    —— [4-[3-[(4-Butoxyphenyl)carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C35H38N2O4S
    [4-[3-[(4-Butoxyphenyl)carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— O-[3-(dimethylamino)pentyl] carbamothioate —— C8H18N2OS
    O-[3-(dimethylamino)pentyl] carbamothioate
    —— 2-Methyl-3-(2-methylpyridin-3-yl)sulfanylpyridine —— C12H12N2S
    2-Methyl-3-(2-methylpyridin-3-yl)sulfanylpyridine