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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1R)-N-ethyl-1-(5-fluoro-2-thiophen-2-ylsulfanylphenyl)ethanamine —— C14H16FNS2
    (1R)-N-ethyl-1-(5-fluoro-2-thiophen-2-ylsulfanylphenyl)ethanamine
    —— N-[(1R)-1-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]ethyl]propan-1-amine —— C15H20N2S2
    N-[(1R)-1-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]ethyl]propan-1-amine
    —— (1R)-N-ethyl-1-(4-pyrimidin-2-ylsulfanylphenyl)ethanamine —— C14H17N3S
    (1R)-N-ethyl-1-(4-pyrimidin-2-ylsulfanylphenyl)ethanamine
    —— (1S)-1-[4-(4-bromophenyl)sulfanyl-3-fluorophenyl]-N-methylethanamine —— C15H15BrFNS
    (1S)-1-[4-(4-bromophenyl)sulfanyl-3-fluorophenyl]-N-methylethanamine
    —— 2-[4-[(1S)-1-(ethylamino)ethyl]phenyl]sulfanyl-1H-pyrimidin-6-one —— C14H17N3OS
    2-[4-[(1S)-1-(ethylamino)ethyl]phenyl]sulfanyl-1H-pyrimidin-6-one
    —— (1S)-N-ethyl-1-[3-fluoro-4-(2-methylpropylsulfanyl)phenyl]ethanamine —— C14H22FNS
    (1S)-N-ethyl-1-[3-fluoro-4-(2-methylpropylsulfanyl)phenyl]ethanamine
    —— (1R)-1-(3-fluoro-4-pyrimidin-2-ylsulfanylphenyl)-N-methylethanamine —— C13H14FN3S
    (1R)-1-(3-fluoro-4-pyrimidin-2-ylsulfanylphenyl)-N-methylethanamine
    —— N-[(1S)-1-[5-fluoro-2-(2-methylpropylsulfanyl)phenyl]ethyl]propan-1-amine —— C15H24FNS
    N-[(1S)-1-[5-fluoro-2-(2-methylpropylsulfanyl)phenyl]ethyl]propan-1-amine
    —— (1R)-1-[5-fluoro-2-(4-fluorophenyl)sulfanylphenyl]-N-methylethanamine —— C15H15F2NS
    (1R)-1-[5-fluoro-2-(4-fluorophenyl)sulfanylphenyl]-N-methylethanamine
    —— (1S)-1-[3-fluoro-4-(1-methylimidazol-2-yl)sulfanylphenyl]-N-methylethanamine —— C13H16FN3S
    (1S)-1-[3-fluoro-4-(1-methylimidazol-2-yl)sulfanylphenyl]-N-methylethanamine
    —— (1R)-N-ethyl-1-(5-fluoro-2-phenylsulfanylphenyl)ethanamine —— C16H18FNS
    (1R)-N-ethyl-1-(5-fluoro-2-phenylsulfanylphenyl)ethanamine
    —— (1S)-1-(2-tert-butylsulfanyl-6-fluorophenyl)-N-ethylethanamine —— C14H22FNS
    (1S)-1-(2-tert-butylsulfanyl-6-fluorophenyl)-N-ethylethanamine
    —— (1S)-1-(4-ethylsulfanyl-3-fluorophenyl)-N-methylethanamine —— C11H16FNS
    (1S)-1-(4-ethylsulfanyl-3-fluorophenyl)-N-methylethanamine
    —— (1S)-1-[2-(2,5-dichlorophenyl)sulfanylphenyl]-N-methylethanamine —— C15H15Cl2NS
    (1S)-1-[2-(2,5-dichlorophenyl)sulfanylphenyl]-N-methylethanamine
    —— (1S)-N-ethyl-1-[3-fluoro-4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]ethanamine —— C12H15FN4S
    (1S)-N-ethyl-1-[3-fluoro-4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]ethanamine
    —— (1S)-1-[2-(4-chlorophenyl)sulfanyl-6-fluorophenyl]-N-methylethanamine —— C15H15ClFNS
    (1S)-1-[2-(4-chlorophenyl)sulfanyl-6-fluorophenyl]-N-methylethanamine
    —— (1R)-1-(2-benzylsulfanyl-5-fluorophenyl)-N-methylethanamine —— C16H18FNS
    (1R)-1-(2-benzylsulfanyl-5-fluorophenyl)-N-methylethanamine
    —— (1R)-1-[2-fluoro-6-(1-methylimidazol-2-yl)sulfanylphenyl]-N-methylethanamine —— C13H16FN3S
    (1R)-1-[2-fluoro-6-(1-methylimidazol-2-yl)sulfanylphenyl]-N-methylethanamine
    —— (2R,3S,6S)-N,N,2-trimethyl-6-pyrimidin-2-ylsulfanyloxan-3-amine —— C12H19N3OS
    (2R,3S,6S)-N,N,2-trimethyl-6-pyrimidin-2-ylsulfanyloxan-3-amine
    —— (3R)-3-methyl-3-(methylsulfanylmethoxy)cyclohexene-1-carbonitrile —— C10H15NOS
    (3R)-3-methyl-3-(methylsulfanylmethoxy)cyclohexene-1-carbonitrile
    —— (3S)-3-methyl-3-(methylsulfanylmethoxy)cyclohexene-1-carbonitrile —— C10H15NOS
    (3S)-3-methyl-3-(methylsulfanylmethoxy)cyclohexene-1-carbonitrile
    —— (3S)-3-[(1R)-1-phenylsulfanylprop-2-enyl]cyclohexan-1-one —— C15H18OS
    (3S)-3-[(1R)-1-phenylsulfanylprop-2-enyl]cyclohexan-1-one
    —— ethyl (2R)-2-ethoxycarbothioylsulfanyl-2-fluoroacetate —— C7H11FO3S2
    ethyl (2R)-2-ethoxycarbothioylsulfanyl-2-fluoroacetate
    —— (2S)-5-aminospiro[1-benzothiophene-2,3'-oxolane]-2',3-dione —— C11H9NO3S
    (2S)-5-aminospiro[1-benzothiophene-2,3'-oxolane]-2',3-dione
    —— (2R)-2-(phenylsulfanylmethyl)cyclohexan-1-one —— C13H16OS
    (2R)-2-(phenylsulfanylmethyl)cyclohexan-1-one
    —— (5S)-5-(phenylsulfanylmethyl)oxolan-2-one —— C11H12O2S
    (5S)-5-(phenylsulfanylmethyl)oxolan-2-one
    —— (2S)-2-(phenylsulfanylmethyl)cyclohexan-1-one —— C13H16OS
    (2S)-2-(phenylsulfanylmethyl)cyclohexan-1-one
    —— 2-[[4-(1-Oxidopyridin-1-ium-2-yl)sulfanyl-6-(1-oxopiperidin-1-ium-2-yl)sulfanyl-1,3,5-triazinan-2-yl]sulfanyl]piperidin-1-ium 1-oxide —— C18H28N6O3S3+2
    2-[[4-(1-Oxidopyridin-1-ium-2-yl)sulfanyl-6-(1-oxopiperidin-1-ium-2-yl)sulfanyl-1,3,5-triazinan-2-yl]sulfanyl]piperidin-1-ium 1-oxide
    —— (3R)-3-chloro-4-phenylsulfanylbutanoic acid —— C10H11ClO2S
    (3R)-3-chloro-4-phenylsulfanylbutanoic acid
    —— Imino-[4-[4-(iminoazaniumylideneamino)phenyl]sulfanylphenyl]iminoazanium —— C12H10N6S+2
    Imino-[4-[4-(iminoazaniumylideneamino)phenyl]sulfanylphenyl]iminoazanium
    —— 2-methylsulfanyl-1-oxopurin-1-ium-6-amine —— C6H6N5OS+
    2-methylsulfanyl-1-oxopurin-1-ium-6-amine
    —— (E)-3-[5-(4-chlorophenyl)sulfanylthiophen-2-yl]-2-phenylprop-2-enenitrile —— C19H12ClNS2
    (E)-3-[5-(4-chlorophenyl)sulfanylthiophen-2-yl]-2-phenylprop-2-enenitrile
    —— 2-methyl-1-[[(2R)-1-methylpyrrolidin-2-yl]methyl]-3-phenylsulfanylindole —— C21H24N2S
    2-methyl-1-[[(2R)-1-methylpyrrolidin-2-yl]methyl]-3-phenylsulfanylindole
    —— 2-[(R)-tert-butylsulfinyl]acetic acid —— C6H12O3S
    2-[(R)-tert-butylsulfinyl]acetic acid
    —— (3R)-3-thiophen-3-ylsulfanylbutanoic acid —— C8H10O2S2
    (3R)-3-thiophen-3-ylsulfanylbutanoic acid
    —— (3S)-2,4-dimethyl-2-methylsulfanylpentan-3-amine —— C8H19NS
    (3S)-2,4-dimethyl-2-methylsulfanylpentan-3-amine
    —— Dihydroxy(oxo)azanium;2-(4-methylsulfanylphenyl)guanidine —— C8H13N4O3S+
    Dihydroxy(oxo)azanium;2-(4-methylsulfanylphenyl)guanidine
    —— (2S)-2-cyclohexylsulfanylpropanal —— C9H16OS
    (2S)-2-cyclohexylsulfanylpropanal
    —— methyl (2R)-2-cyano-2-(5-cyano-2-methyl-6-methylsulfanylpyrimidin-4-yl)acetate —— C11H10N4O2S
    methyl (2R)-2-cyano-2-(5-cyano-2-methyl-6-methylsulfanylpyrimidin-4-yl)acetate
    —— (3R)-3-phenylsulfanylpent-4-en-1-ol —— C11H14OS
    (3R)-3-phenylsulfanylpent-4-en-1-ol
    —— (Z)-2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N,N-dimethylethenamine —— C15H18N4S
    (Z)-2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N,N-dimethylethenamine
    —— (3S)-3-phenylsulfanylpent-4-en-1-ol —— C11H14OS
    (3S)-3-phenylsulfanylpent-4-en-1-ol
    —— (4-carbamoyl-3-methylsulfanyl-1H-pyrazol-5-yl)imino-iminoazanium —— C5H7N6OS+
    (4-carbamoyl-3-methylsulfanyl-1H-pyrazol-5-yl)imino-iminoazanium
    —— (2S)-2-hydroxy-2-methyl-3-phenylsulfanylpropanoic acid —— C10H12O3S
    (2S)-2-hydroxy-2-methyl-3-phenylsulfanylpropanoic acid
    —— (2S)-2-hydroxy-2-(2-methylsulfanylphenyl)acetic acid —— C9H10O3S
    (2S)-2-hydroxy-2-(2-methylsulfanylphenyl)acetic acid
    —— (2S,3R)-3-hydroxy-2-phenylsulfanylpentanoic acid —— C11H14O3S
    (2S,3R)-3-hydroxy-2-phenylsulfanylpentanoic acid
    —— (2S)-1-(2-aminophenyl)sulfanylpropan-2-ol —— C9H13NOS
    (2S)-1-(2-aminophenyl)sulfanylpropan-2-ol
    —— methyl (2S)-2-cyano-2-(5-cyano-2-methyl-6-methylsulfanylpyrimidin-4-yl)acetate —— C11H10N4O2S
    methyl (2S)-2-cyano-2-(5-cyano-2-methyl-6-methylsulfanylpyrimidin-4-yl)acetate
    —— (2R)-2-hydroxy-2-(2-methylsulfanylphenyl)acetic acid —— C9H10O3S
    (2R)-2-hydroxy-2-(2-methylsulfanylphenyl)acetic acid
    —— 2-chloro-6-[[(3S)-piperidin-3-yl]methylsulfanyl]pyridine —— C11H15ClN2S
    2-chloro-6-[[(3S)-piperidin-3-yl]methylsulfanyl]pyridine