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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Bis(trifluoromethylsulfonyl)azanide;2,5-dimethyl-4-[(4-methylphenyl)methylsulfanyl]benzenediazonium —— C18H17F6N3O4S3
    Bis(trifluoromethylsulfonyl)azanide;2,5-dimethyl-4-[(4-methylphenyl)methylsulfanyl]benzenediazonium
    —— 3-(2-chlorophenyl)-7-methyl-1-phenyl-4H-pyrimido[4,5-d]pyrimidin-2-one;3-(2-chlorophenyl)-7-methylsulfanyl-1-phenyl-4H-pyrimido[4,5-d]pyrimidin-2-one —— C38H30Cl2N8O2S
    3-(2-chlorophenyl)-7-methyl-1-phenyl-4H-pyrimido[4,5-d]pyrimidin-2-one;3-(2-chlorophenyl)-7-methylsulfanyl-1-phenyl-4H-pyrimido[4,5-d]pyrimidin-2-one
    —— (5Z)-5-({4-[(4-chlorophenyl)sulfanyl]-3-nitrophenyl}methylidene)-2-sulfanylidene-1,3-thiazolidin-4-one —— C16H9ClN2O3S3
    (5Z)-5-({4-[(4-chlorophenyl)sulfanyl]-3-nitrophenyl}methylidene)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— ethyl (2Z)-2-[(2-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21ClN2O3S2
    ethyl (2Z)-2-[(2-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 1-Hexyl-3-methylsulfanylpyrrole-2,5-diol —— C11H19NO2S
    1-Hexyl-3-methylsulfanylpyrrole-2,5-diol
    —— 4-Hydroxyhexane-3-thione —— C6H12OS
    4-Hydroxyhexane-3-thione
    —— 1-Ethyl-4-methylidene-2-methylsulfanylcyclohexane —— C10H18S
    1-Ethyl-4-methylidene-2-methylsulfanylcyclohexane
    —— 2-Amino-1-pyridin-2-ylsulfanylethanethiol —— C7H10N2S2
    2-Amino-1-pyridin-2-ylsulfanylethanethiol
    —— Ethane;2-(2-methylbutylsulfanyl)pyridine —— C12H21NS
    Ethane;2-(2-methylbutylsulfanyl)pyridine
    —— 6-Methyl-2-methylsulfanyloct-4-yne —— C10H18S
    6-Methyl-2-methylsulfanyloct-4-yne
    —— 2,4-dimethylpentane-3-thiol —— C7H15S-
    2,4-dimethylpentane-3-thiol
    —— Cyclohexylsulfanylbenzene;dimethoxymethane;methanamine —— C29H50N2O2S2
    Cyclohexylsulfanylbenzene;dimethoxymethane;methanamine
    —— 11-Hydroxyundecyl hexadec-7-enylsulfanylformate —— C28H54O3S
    11-Hydroxyundecyl hexadec-7-enylsulfanylformate
    —— 3-Benzylsulfanyl-6,7-dihydro-2-benzothiophene-1-carbaldehyde —— C16H14OS2
    3-Benzylsulfanyl-6,7-dihydro-2-benzothiophene-1-carbaldehyde
    —— 2-(4-Methyl-2-methylsulfanyl-2,3-dihydro-1-benzothiophene-5-carbonyl)cyclohexane-1,3-dione —— C17H18O3S2
    2-(4-Methyl-2-methylsulfanyl-2,3-dihydro-1-benzothiophene-5-carbonyl)cyclohexane-1,3-dione
    —— 3-(2-ethylphenyl)sulfanyl-7-methyl-1H-indole —— C17H17NS
    3-(2-ethylphenyl)sulfanyl-7-methyl-1H-indole
    —— 1,3-Bis(pentadecylsulfanyl)benzene —— C36H66S2
    1,3-Bis(pentadecylsulfanyl)benzene
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)-2-hydroxyphenyl]methylideneamino]acetamide —— C22H24ClN5O2S3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)-2-hydroxyphenyl]methylideneamino]acetamide
    —— (2Z,5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(2,4-dimethylphenyl)imino]-1,3-thiazolidin-4-one —— C22H17ClN2O2S2
    (2Z,5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(2,4-dimethylphenyl)imino]-1,3-thiazolidin-4-one
    —— (7Z)-2-[(4-chlorophenyl)methylsulfanyl]-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C25H17ClN2S3
    (7Z)-2-[(4-chlorophenyl)methylsulfanyl]-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— (4-methylphenyl) (Z)-N-(2,2-dichloro-1-diphenylphosphorylethenyl)benzenecarboximidothioate —— C28H22Cl2NOPS
    (4-methylphenyl) (Z)-N-(2,2-dichloro-1-diphenylphosphorylethenyl)benzenecarboximidothioate
    —— 1-(3,4-dimethylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C22H25N3S
    1-(3,4-dimethylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-furan-3-ylmethylideneamino]triazole-4-carboxamide —— C17H13ClN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-furan-3-ylmethylideneamino]triazole-4-carboxamide
    —— (E)-2-(p-tolylthio)nicotinaldehyde O-4-methylbenzyl oxime —— C21H20N2OS
    (E)-2-(p-tolylthio)nicotinaldehyde O-4-methylbenzyl oxime
    —— N'-[(Z)-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]-1-benzofuran-2-carbohydrazide —— C21H16N2O3S
    N'-[(Z)-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]-1-benzofuran-2-carbohydrazide
    —— Ethane;4-(2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-amine —— C12H20N4S2
    Ethane;4-(2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-amine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-1-pyridin-3-ylethylideneamino]triazole-4-carboxamide —— C19H17N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-1-pyridin-3-ylethylideneamino]triazole-4-carboxamide
    —— 4-[(5-Ethylsulfanyl-1,3,4-thiadiazol-2-yl)hydrazinylidene]-2,6-bis(2-methoxyethyl)-1,1-dioxo-1,2,6-thiadiazinane-3,5-dione —— C13H20N6O6S3
    4-[(5-Ethylsulfanyl-1,3,4-thiadiazol-2-yl)hydrazinylidene]-2,6-bis(2-methoxyethyl)-1,1-dioxo-1,2,6-thiadiazinane-3,5-dione
    —— N-(2-methylpropyl)-4-methylsulfonyl-N-propylhexan-1-amine —— C14H31NO2S
    N-(2-methylpropyl)-4-methylsulfonyl-N-propylhexan-1-amine
    —— [6-[[6-(4-fluorophenyl)-7,8-dihydro-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulfanyl]-1H-benzimidazol-2-yl] carbamate —— C19H14FN7O2S
    [6-[[6-(4-fluorophenyl)-7,8-dihydro-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulfanyl]-1H-benzimidazol-2-yl] carbamate
    —— 4-[5-[(5,6-dichloro-1H-benzimidazol-2-yl)sulfanyl]furan-2-yl]-1,4,4a,6,7,8-hexahydropyrazolo[3,4-b][1,7]naphthyridin-5-one —— C20H14Cl2N6O2S
    4-[5-[(5,6-dichloro-1H-benzimidazol-2-yl)sulfanyl]furan-2-yl]-1,4,4a,6,7,8-hexahydropyrazolo[3,4-b][1,7]naphthyridin-5-one
    —— 1-[(4S,5aR,9aR)-3-hydroxy-4-(3-methylsulfanylthiophen-2-yl)-4,5a,6,7,8,9,9a,10-octahydro-2H-pyrrolo[3,4-c][1,5]benzodiazepin-5-yl]-2-hydroxyethanone —— C18H23N3O3S2
    1-[(4S,5aR,9aR)-3-hydroxy-4-(3-methylsulfanylthiophen-2-yl)-4,5a,6,7,8,9,9a,10-octahydro-2H-pyrrolo[3,4-c][1,5]benzodiazepin-5-yl]-2-hydroxyethanone
    —— 1-[(4-Chlorophenyl)methyl]-4-methylsulfanyl-2-(4-methylsulfanylphenyl)-6-oxopyrimidine-5-carboximidamide —— C20H19ClN4OS2
    1-[(4-Chlorophenyl)methyl]-4-methylsulfanyl-2-(4-methylsulfanylphenyl)-6-oxopyrimidine-5-carboximidamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-1-pyridin-3-ylethylideneamino]triazole-4-carboxamide —— C20H19N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-1-pyridin-3-ylethylideneamino]triazole-4-carboxamide
    —— 2-[[4-(Cyclohexylcarbamoyl)-5-(4-methylpentanoyl)-1,3,4-oxadiazol-4-ium-2-yl]sulfanyl]acetic acid —— C17H26N3O5S+
    2-[[4-(Cyclohexylcarbamoyl)-5-(4-methylpentanoyl)-1,3,4-oxadiazol-4-ium-2-yl]sulfanyl]acetic acid
    —— 4-(4-fluorophenyl)-2-[(E)-2-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)ethenyl]-1,3-thiazole —— C21H13FN4O2S2
    4-(4-fluorophenyl)-2-[(E)-2-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)ethenyl]-1,3-thiazole
    —— ethyl (2Z)-2-benzylidene-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H22N2O3S2
    ethyl (2Z)-2-benzylidene-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 3-Methylsulfanylprop-1-ynylcyclopropane —— C7H10S
    3-Methylsulfanylprop-1-ynylcyclopropane
    —— 3-[3-(cycloheptylmethylsulfanyl)phenyl]-N-ethylprop-2-yn-1-amine —— C19H27NS
    3-[3-(cycloheptylmethylsulfanyl)phenyl]-N-ethylprop-2-yn-1-amine
    —— Butylsulfonyl-[diethyl(2-oxoheptyl)-lambda4-sulfanyl]oxidanium —— C15H33O4S2+
    Butylsulfonyl-[diethyl(2-oxoheptyl)-lambda4-sulfanyl]oxidanium
    —— 2-pyridin-2-ylsulfanyl-N,N-bis(2-pyridin-2-ylsulfanylethyl)ethanamine —— C21H24N4S3
    2-pyridin-2-ylsulfanyl-N,N-bis(2-pyridin-2-ylsulfanylethyl)ethanamine
    —— [(E)-2-butylsulfonylethenyl] carbamimidothioate —— C7H14N2O2S2
    [(E)-2-butylsulfonylethenyl] carbamimidothioate
    —— Ethyl acetate;methylsulfanylethane —— C7H16O2S
    Ethyl acetate;methylsulfanylethane
    —— 8-(6-Sulfanylhexyl)-9-(8-sulfanyloctyl)-8-(1-sulfanyltridecan-6-yl)octadecane-1,9,18-trithiol —— C45H92S6
    8-(6-Sulfanylhexyl)-9-(8-sulfanyloctyl)-8-(1-sulfanyltridecan-6-yl)octadecane-1,9,18-trithiol
    —— 4-Methyl-6-methylsulfonylhex-5-en-2-one —— C8H14O3S
    4-Methyl-6-methylsulfonylhex-5-en-2-one
    —— 2-[3-chloro-2-[[5-(4-methylphenyl)sulfanylpyridin-2-yl]oxymethyl]phenyl]-2-methoxyimino-N-methylacetamide —— C23H22ClN3O3S
    2-[3-chloro-2-[[5-(4-methylphenyl)sulfanylpyridin-2-yl]oxymethyl]phenyl]-2-methoxyimino-N-methylacetamide
    —— 2-Methyl-1-methylsulfanylhexa-2,4-diene —— C8H14S
    2-Methyl-1-methylsulfanylhexa-2,4-diene
    —— 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one —— C18H17Cl2NOS2
    3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
    —— 8-(2,5-dimethoxyphenyl)sulfanyl-3-[2-(2-methoxyphenyl)ethyl]-7H-purin-3-ium-6-amine —— C22H24N5O3S+
    8-(2,5-dimethoxyphenyl)sulfanyl-3-[2-(2-methoxyphenyl)ethyl]-7H-purin-3-ium-6-amine
    —— 2-Methyl-4-phenylsulfanyl-1,3-thiazole —— C10H9NS2
    2-Methyl-4-phenylsulfanyl-1,3-thiazole