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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]-2-piperidin-1-ylpropan-1-amine —— C17H28N2S
    (2R)-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]-2-piperidin-1-ylpropan-1-amine
    —— 2-[(2R)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]acetic acid —— C16H23NO2S
    2-[(2R)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]acetic acid
    —— 2-[(2S)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]acetic acid —— C16H23NO2S
    2-[(2S)-1-[2-(4-methylphenyl)sulfanylethyl]piperidin-2-yl]acetic acid
    —— 2-[(2R)-1-[2-(2-fluorophenyl)sulfanylethyl]piperidin-2-yl]acetic acid —— C15H20FNO2S
    2-[(2R)-1-[2-(2-fluorophenyl)sulfanylethyl]piperidin-2-yl]acetic acid
    —— 2-(3,3-dimethyl-2-oxobutyl)sulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C11H13N3O3S2
    2-(3,3-dimethyl-2-oxobutyl)sulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[(2R)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidin-2-yl]acetic acid —— C15H20FNO2S
    2-[(2R)-1-[2-(4-fluorophenyl)sulfanylethyl]piperidin-2-yl]acetic acid
    —— 2-[(2-fluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidine-5,7(4H,6H)-dione —— C12H8FN3O2S2
    2-[(2-fluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidine-5,7(4H,6H)-dione
    —— 2-[(4-chlorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C12H8ClN3O2S2
    2-[(4-chlorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[(3-methylphenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C13H11N3O2S2
    2-[(3-methylphenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[(2-chlorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C12H8ClN3O2S2
    2-[(2-chlorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[(3-fluorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C12H8FN3O2S2
    2-[(3-fluorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— methyl 3-[[(2S)-2-(4-chlorophenyl)sulfanylpropanoyl]-ethylamino]propanoate —— C15H20ClNO3S
    methyl 3-[[(2S)-2-(4-chlorophenyl)sulfanylpropanoyl]-ethylamino]propanoate
    —— 2-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}-N-(4-phenylbutan-2-yl)acetamide —— C15H19N3OS3
    2-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}-N-(4-phenylbutan-2-yl)acetamide
    —— methyl 3-[[(2R)-2-(4-chlorophenyl)sulfanylpropanoyl]-ethylamino]propanoate —— C15H20ClNO3S
    methyl 3-[[(2R)-2-(4-chlorophenyl)sulfanylpropanoyl]-ethylamino]propanoate
    —— methyl 3-[[(2R)-2,3-dihydro-1-benzothiophene-2-carbonyl]-ethylamino]propanoate —— C15H19NO3S
    methyl 3-[[(2R)-2,3-dihydro-1-benzothiophene-2-carbonyl]-ethylamino]propanoate
    —— N-(4-phenylbutan-2-yl)-2-(1H-1,2,3-triazol-5-ylsulfanyl)acetamide —— C14H18N4OS
    N-(4-phenylbutan-2-yl)-2-(1H-1,2,3-triazol-5-ylsulfanyl)acetamide
    —— 2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C10H14N2O3S
    2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— 2-(2-piperidin-1-ylethylsulfanyl)-4-propan-2-yl-1H-pyrimidin-6-one —— C14H23N3OS
    2-(2-piperidin-1-ylethylsulfanyl)-4-propan-2-yl-1H-pyrimidin-6-one
    —— N-[[5-(4-fluorophenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine —— C18H18FN3OS
    N-[[5-(4-fluorophenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine
    —— 2-((4-Ethyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid —— C9H12N2O3S
    2-((4-Ethyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid
    —— 3-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid —— C9H12N2O3S
    3-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid
    —— N-[[5-(3-chloro-2-methylphenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine —— C19H20ClN3OS
    N-[[5-(3-chloro-2-methylphenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine
    —— N-[(1-methyl-1H-pyrrol-2-yl)methyl]-3-(pyrimidin-2-ylsulfanyl)propan-1-amine —— C13H18N4S
    N-[(1-methyl-1H-pyrrol-2-yl)methyl]-3-(pyrimidin-2-ylsulfanyl)propan-1-amine
    —— N-[[5-(3-chloro-4-fluorophenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine —— C18H17ClFN3OS
    N-[[5-(3-chloro-4-fluorophenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine
    —— N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine —— C18H18ClN3OS
    N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-3-pyrimidin-2-ylsulfanylpropan-1-amine
    —— [3-(Pyrimidin-2-ylsulfanyl)-propyl]-thiophen-2-ylmethyl-amine —— C12H15N3S2
    [3-(Pyrimidin-2-ylsulfanyl)-propyl]-thiophen-2-ylmethyl-amine
    —— 1-(5-phenyl-4,5-dihydro-1H-pyrazol-1-yl)-2-{[5-(prop-2-en-1-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl}ethanone —— C16H17N5OS2
    1-(5-phenyl-4,5-dihydro-1H-pyrazol-1-yl)-2-{[5-(prop-2-en-1-ylamino)-1,3,4-thiadiazol-2-yl]sulfanyl}ethanone
    —— 2-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-1-(5-phenyl-4,5-dihydro-1H-pyrazol-1-yl)ethanone —— C15H16N4OS
    2-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-1-(5-phenyl-4,5-dihydro-1H-pyrazol-1-yl)ethanone
    —— 2-{[5-(furan-2-yl)-4-methyl-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide —— C19H24N4O2S
    2-{[5-(furan-2-yl)-4-methyl-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide
    —— 2-{[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide —— C21H25N3O2S
    2-{[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide
    —— (1R)-1-(5-bromothiophen-2-yl)-N-(2-phenylsulfanylethyl)ethanamine —— C14H16BrNS2
    (1R)-1-(5-bromothiophen-2-yl)-N-(2-phenylsulfanylethyl)ethanamine
    —— (1S)-1-(5-bromothiophen-2-yl)-N-(2-phenylsulfanylethyl)ethanamine —— C14H16BrNS2
    (1S)-1-(5-bromothiophen-2-yl)-N-(2-phenylsulfanylethyl)ethanamine
    —— (1R)-N-[(1R)-1-(5-bromothiophen-2-yl)ethyl]-1-(4-methylsulfanylphenyl)ethanamine —— C15H18BrNS2
    (1R)-N-[(1R)-1-(5-bromothiophen-2-yl)ethyl]-1-(4-methylsulfanylphenyl)ethanamine
    —— 2-{[5-(furan-2-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide —— C21H26N4O2S
    2-{[5-(furan-2-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide
    —— N-[(1R)-1-(5-bromothiophen-2-yl)ethyl]-4-(difluoromethylsulfanyl)aniline —— C13H12BrF2NS2
    N-[(1R)-1-(5-bromothiophen-2-yl)ethyl]-4-(difluoromethylsulfanyl)aniline
    —— N-[(1R)-1-(5-bromothiophen-2-yl)ethyl]-4-methylsulfanylaniline —— C13H14BrNS2
    N-[(1R)-1-(5-bromothiophen-2-yl)ethyl]-4-methylsulfanylaniline
    —— N-[(1S)-1-(5-bromothiophen-2-yl)ethyl]-4-methylsulfanylaniline —— C13H14BrNS2
    N-[(1S)-1-(5-bromothiophen-2-yl)ethyl]-4-methylsulfanylaniline
    —— N-[(1S)-1-(5-bromothiophen-2-yl)ethyl]-2-(difluoromethylsulfanyl)aniline —— C13H12BrF2NS2
    N-[(1S)-1-(5-bromothiophen-2-yl)ethyl]-2-(difluoromethylsulfanyl)aniline
    —— 4-(difluoromethylsulfanyl)-N-[(1R)-1-(1H-pyrazol-5-yl)ethyl]aniline —— C12H13F2N3S
    4-(difluoromethylsulfanyl)-N-[(1R)-1-(1H-pyrazol-5-yl)ethyl]aniline
    —— 2-[(R)-difluoromethylsulfinyl]acetic acid —— C3H4F2O3S
    2-[(R)-difluoromethylsulfinyl]acetic acid
    —— 5-[(3-Phenylpropyl)thio]-1,3,4-thiadiazol-2-amine —— C11H13N3S2
    5-[(3-Phenylpropyl)thio]-1,3,4-thiadiazol-2-amine
    —— 3-{5-[(4-chlorobenzyl)sulfanyl]-1H-tetrazol-1-yl}pyridine —— C13H10ClN5S
    3-{5-[(4-chlorobenzyl)sulfanyl]-1H-tetrazol-1-yl}pyridine
    —— 2-Benzyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C15H16N4O2S
    2-Benzyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-[(4-bromophenyl)methylsulfanyl]-4-propan-2-yl-1H-pyrimidin-6-one —— C14H15BrN2OS
    2-[(4-bromophenyl)methylsulfanyl]-4-propan-2-yl-1H-pyrimidin-6-one
    —— 2-[(5-Benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole —— C15H17N5OS
    2-[(5-Benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole
    —— 3-{5-[(2-chlorobenzyl)sulfanyl]-1H-tetrazol-1-yl}pyridine —— C13H10ClN5S
    3-{5-[(2-chlorobenzyl)sulfanyl]-1H-tetrazol-1-yl}pyridine
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-(4-hydroxyphenyl)sulfanylacetamide —— C16H16BrNO2S
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-(4-hydroxyphenyl)sulfanylacetamide
    —— 2-(4-hydroxyphenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide —— C13H19NO2S
    2-(4-hydroxyphenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-(4-hydroxyphenyl)sulfanylacetamide —— C16H16BrNO2S
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-(4-hydroxyphenyl)sulfanylacetamide
    —— N-[(2S)-heptan-2-yl]-2-(4-hydroxyphenyl)sulfanylacetamide —— C15H23NO2S
    N-[(2S)-heptan-2-yl]-2-(4-hydroxyphenyl)sulfanylacetamide