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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-4-(4-chlorophenylthio)-3-nitrobenzaldehyde oxime —— C13H9ClN2O3S
    (E)-4-(4-chlorophenylthio)-3-nitrobenzaldehyde oxime
    —— (5Z)-2-hydroxyimino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C11H10N2O2S2
    (5Z)-2-hydroxyimino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (E)-3-nitro-4-(p-tolylthio)benzaldehyde O-3,4-dichlorobenzyl oxime —— C21H16Cl2N2O3S
    (E)-3-nitro-4-(p-tolylthio)benzaldehyde O-3,4-dichlorobenzyl oxime
    —— 4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-(2,4-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-(2,4-dichlorobenzyl)oxime
    —— 3-Nitro-4-(phenylsulfanyl)benzenecarbaldehydeo-methyloxime —— C14H12N2O3S
    3-Nitro-4-(phenylsulfanyl)benzenecarbaldehydeo-methyloxime
    —— 4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-(2,6-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-(2,6-dichlorobenzyl)oxime
    —— 3-Nitro-4-((3-(trifluoromethyl)phenyl)sulfanyl)benzenecarbaldehydeo-methyloxime —— C15H11F3N2O3S
    3-Nitro-4-((3-(trifluoromethyl)phenyl)sulfanyl)benzenecarbaldehydeo-methyloxime
    —— (E)-3-nitro-4-(p-tolylthio)benzaldehyde O-methyl oxime —— C15H14N2O3S
    (E)-3-nitro-4-(p-tolylthio)benzaldehyde O-methyl oxime
    —— 4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-methyloxime —— C14H11ClN2O3S
    4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-methyloxime
    —— (E)-3-nitro-4-(p-tolylthio)benzaldehyde O-2,4-dichlorobenzyl oxime —— C21H16Cl2N2O3S
    (E)-3-nitro-4-(p-tolylthio)benzaldehyde O-2,4-dichlorobenzyl oxime
    —— 2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-7-styryl[1,2,4]triazolo[1,5-a]pyrimidine —— C19H11ClF3N5S
    2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-7-styryl[1,2,4]triazolo[1,5-a]pyrimidine
    —— 2-[1-[(E)-4-[4-[(Z)-hydroxyiminomethyl]pyridin-1-ium-1-yl]but-2-enyl]pyridin-1-ium-4-yl]sulfanylacetic acid —— C17H19N3O3S+2
    2-[1-[(E)-4-[4-[(Z)-hydroxyiminomethyl]pyridin-1-ium-1-yl]but-2-enyl]pyridin-1-ium-4-yl]sulfanylacetic acid
    —— N-[(E)-2-(3-methyl-4-nitro-1,2-oxazol-5-yl)ethenyl]-3-(methylsulfanyl)aniline —— C13H13N3O3S
    N-[(E)-2-(3-methyl-4-nitro-1,2-oxazol-5-yl)ethenyl]-3-(methylsulfanyl)aniline
    —— (E)-[(2-chlorophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide —— C9H7ClN2S2
    (E)-[(2-chlorophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide
    —— (5E)-5-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C15H9N3O3S3
    (5E)-5-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5Z)-5-[[2-(4-methylphenyl)sulfanyl-5-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C17H12N2O3S3
    (5Z)-5-[[2-(4-methylphenyl)sulfanyl-5-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[[3-nitro-4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C16H8F3N3O3S3
    (5E)-5-[[3-nitro-4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 5-({2-[4-(3-Methylpyridin-4-yl)-1,4-diazepan-1-yl]-2-oxoethyl}thio)-1,3,4-thiadiazol-2-amine —— C15H20N6OS2
    5-({2-[4-(3-Methylpyridin-4-yl)-1,4-diazepan-1-yl]-2-oxoethyl}thio)-1,3,4-thiadiazol-2-amine
    —— (5E)-3-benzyl-5-[[4-(4-bromophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H15BrN2O3S3
    (5E)-3-benzyl-5-[[4-(4-bromophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (E)-4-chloro-N-(1-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)dithiazol-5-imine —— C6H6ClN5S3
    (E)-4-chloro-N-(1-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)dithiazol-5-imine
    —— N-[3-(4-methyl-1,3-thiazol-5-yl)propyl]-2-(pyrimidin-2-ylthio)acetamide —— C13H16N4OS2
    N-[3-(4-methyl-1,3-thiazol-5-yl)propyl]-2-(pyrimidin-2-ylthio)acetamide
    —— N-[cis-4-(2-amino-2-oxoethoxy)tetrahydro-2H-pyran-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide —— C13H19N3O4S2
    N-[cis-4-(2-amino-2-oxoethoxy)tetrahydro-2H-pyran-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide
    —— (5E)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C17H12N2O3S3
    (5E)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— [(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino] benzoate —— C20H12ClF3N2O2S
    [(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino] benzoate
    —— (5Z)-5-[[5-nitro-2-[[5-(trifluoromethyl)-2-pyridyl]sulfanyl]phenyl]methylene]-2-thioxo-thiazolidin-4-one —— C16H8F3N3O3S3
    (5Z)-5-[[5-nitro-2-[[5-(trifluoromethyl)-2-pyridyl]sulfanyl]phenyl]methylene]-2-thioxo-thiazolidin-4-one
    —— 5-(4-((4-Chlorophenyl)thio)-3-nitrobenzylidene)-2-thioxo-1,3-thiazolidin-4-one —— C16H9ClN2O3S3
    5-(4-((4-Chlorophenyl)thio)-3-nitrobenzylidene)-2-thioxo-1,3-thiazolidin-4-one
    —— N-[2-(2-oxopyrrolidin-1-yl)ethyl]-2-(pyridin-4-ylthio)acetamide —— C13H17N3O2S
    N-[2-(2-oxopyrrolidin-1-yl)ethyl]-2-(pyridin-4-ylthio)acetamide
    —— 1-(4-chlorophenyl)-3-[(Z)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea —— C19H13Cl2N5S3
    1-(4-chlorophenyl)-3-[(Z)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea
    —— 1-[(Z)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]-3-methylthiourea —— C14H12ClN5S3
    1-[(Z)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]-3-methylthiourea
    —— N-[(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]benzenesulfonamide —— C19H13ClF3N3O2S2
    N-[(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]benzenesulfonamide
    —— 1-(4-chlorophenyl)-3-[(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C20H13Cl2F3N4S2
    1-(4-chlorophenyl)-3-[(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— (2Z)-3-(4-chlorophenyl)sulfanyl-2-(nitrosomethylidene)-5-(trifluoromethyl)-1H-pyridine —— C13H8ClF3N2OS
    (2Z)-3-(4-chlorophenyl)sulfanyl-2-(nitrosomethylidene)-5-(trifluoromethyl)-1H-pyridine
    —— 2-methyl-N-{2-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]ethyl}-3-(1H-1,2,4-triazol-1-yl)propanamide —— C11H17N7OS
    2-methyl-N-{2-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]ethyl}-3-(1H-1,2,4-triazol-1-yl)propanamide
    —— [(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino] thiophene-2-carboxylate —— C18H10ClF3N2O2S2
    [(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino] thiophene-2-carboxylate
    —— 1-tert-butyl-3-[(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C18H18ClF3N4S2
    1-tert-butyl-3-[(Z)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— 1-tert-butyl-3-[(Z)-[2-[(4-chlorophenyl)methylsulfanyl]pyrimidin-4-yl]methylideneamino]thiourea —— C17H20ClN5S2
    1-tert-butyl-3-[(Z)-[2-[(4-chlorophenyl)methylsulfanyl]pyrimidin-4-yl]methylideneamino]thiourea
    —— 1-(3-chlorophenyl)-5-(4-chlorophenyl)sulfanyl-N-[(Z)-dimethylaminomethylideneamino]-4-oxopyridazine-3-carboxamide —— C20H17Cl2N5O2S
    1-(3-chlorophenyl)-5-(4-chlorophenyl)sulfanyl-N-[(Z)-dimethylaminomethylideneamino]-4-oxopyridazine-3-carboxamide
    —— N-[(1R*,2S*)-2-(methoxymethyl)cyclopentyl]-2-[(4-methyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio]acetamide —— C14H21N3O3S
    N-[(1R*,2S*)-2-(methoxymethyl)cyclopentyl]-2-[(4-methyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio]acetamide
    —— (5-{[5-(cyclohexylthio)-2-furyl]methyl}-5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-yl)methanol —— C19H27N3O2S
    (5-{[5-(cyclohexylthio)-2-furyl]methyl}-5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-yl)methanol
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)thio]-N-[3-(1H-1,2,3-triazol-1-yl)propyl]acetamide —— C9H13N7OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)thio]-N-[3-(1H-1,2,3-triazol-1-yl)propyl]acetamide
    —— (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]cyclohexa-2,4-dien-1-one —— C24H18N2OS2
    (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]cyclohexa-2,4-dien-1-one
    —— 4-Methyl-2-({2-oxo-2-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]ethyl}thio)-1,3-thiazole —— C13H15N3OS3
    4-Methyl-2-({2-oxo-2-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]ethyl}thio)-1,3-thiazole
    —— (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-4-bromo-2-methoxycyclohexa-2,4-dien-1-one —— C25H19BrN2O2S2
    (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-4-bromo-2-methoxycyclohexa-2,4-dien-1-one
    —— (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-2,4-dibromocyclohexa-2,4-dien-1-one —— C24H16Br2N2OS2
    (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-2,4-dibromocyclohexa-2,4-dien-1-one
    —— 2-[(4-methyl-1,3-thiazol-2-yl)thio]-N-[1-methyl-2-(1H-1,2,4-triazol-1-yl)ethyl]acetamide —— C11H15N5OS2
    2-[(4-methyl-1,3-thiazol-2-yl)thio]-N-[1-methyl-2-(1H-1,2,4-triazol-1-yl)ethyl]acetamide
    —— (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-4-chlorocyclohexa-2,4-dien-1-one —— C24H17ClN2OS2
    (6E)-6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-4-chlorocyclohexa-2,4-dien-1-one
    —— [(Z)-1-(4-phenylsulfanylphenyl)ethylideneamino] 4-chlorobenzoate —— C21H16ClNO2S
    [(Z)-1-(4-phenylsulfanylphenyl)ethylideneamino] 4-chlorobenzoate
    —— (NZ)-N-[1-(4-phenylsulfanylphenyl)ethylidene]hydroxylamine —— C14H13NOS
    (NZ)-N-[1-(4-phenylsulfanylphenyl)ethylidene]hydroxylamine
    —— methyl (E)-2-cyano-3-(5-methylsulfanylthiophen-2-yl)prop-2-enoate —— C10H9NO2S2
    methyl (E)-2-cyano-3-(5-methylsulfanylthiophen-2-yl)prop-2-enoate
    —— (Z)-2-(furan-2-carbonyl)-3-(2-methylsulfanylthiophen-3-yl)prop-2-enenitrile —— C13H9NO2S2
    (Z)-2-(furan-2-carbonyl)-3-(2-methylsulfanylthiophen-3-yl)prop-2-enenitrile