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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Cambridge id 5732161 —— C11H11N3S
    Cambridge id 5732161
    —— (2R)-2-phenyl-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetic acid —— C17H13N3O2S
    (2R)-2-phenyl-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetic acid
    —— (2S)-2-phenyl-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetic acid —— C17H13N3O2S
    (2S)-2-phenyl-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetic acid
    —— phenyl (1E)-N-hydroxy-2-oxobutanimidothioate —— C10H11NO2S
    phenyl (1E)-N-hydroxy-2-oxobutanimidothioate
    —— phenyl (1E)-N-hydroxy-2-oxopropanimidothioate —— C9H9NO2S
    phenyl (1E)-N-hydroxy-2-oxopropanimidothioate
    —— 3-[(2-Chlorobenzyl)sulfanyl]-5,6-di(furan-2-yl)-1,2,4-triazine —— C18H12ClN3O2S
    3-[(2-Chlorobenzyl)sulfanyl]-5,6-di(furan-2-yl)-1,2,4-triazine
    —— (1E)-1-hydroxyimino-1-methylsulfinylpropan-2-one —— C4H7NO3S
    (1E)-1-hydroxyimino-1-methylsulfinylpropan-2-one
    —— 1-hydroxyimino-3-methylsulfonylpropan-2-one —— C4H7NO4S
    1-hydroxyimino-3-methylsulfonylpropan-2-one
    —— (2Z)-2-hydroxyimino-1-benzothiophen-3-one —— C8H5NO2S
    (2Z)-2-hydroxyimino-1-benzothiophen-3-one
    —— (2R)-N-[2-(diethylamino)ethyl]-2-phenylsulfanylpropanamide —— C15H24N2OS
    (2R)-N-[2-(diethylamino)ethyl]-2-phenylsulfanylpropanamide
    —— (2R)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-phenylsulfanylpropan-1-one —— C15H21NO2S
    (2R)-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-phenylsulfanylpropan-1-one
    —— Methionine phosphinate —— C4H11NO2PS+
    Methionine phosphinate
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-[(1R,3S)-3-(trifluoromethyl)cyclohexyl]propanamide —— C17H22F3NOS
    (2R)-2-(4-methylphenyl)sulfanyl-N-[(1R,3S)-3-(trifluoromethyl)cyclohexyl]propanamide
    —— (2R)-6-methyl-N-[(1S,3S)-3-(trifluoromethyl)cyclohexyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C17H20F3NOS
    (2R)-6-methyl-N-[(1S,3S)-3-(trifluoromethyl)cyclohexyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-[(1S,3S)-3-(trifluoromethyl)cyclohexyl]propanamide —— C17H22F3NOS
    (2S)-2-(4-methylphenyl)sulfanyl-N-[(1S,3S)-3-(trifluoromethyl)cyclohexyl]propanamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-[(1S,3S)-3-(trifluoromethyl)cyclohexyl]propanamide —— C17H22F3NOS
    (2R)-2-(4-methylphenyl)sulfanyl-N-[(1S,3S)-3-(trifluoromethyl)cyclohexyl]propanamide
    —— 5,6,14,15-bisbenzo-8,12-diaza-1,4-dithia-cyclopentadecane 760124-58-1 C19H24N2S2
    5,6,14,15-bisbenzo-8,12-diaza-1,4-dithia-cyclopentadecane
    —— (2R)-6-methyl-N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]-2,3-dihydro-1-benzothiophene-2-carboxamide —— C19H28N2O2S
    (2R)-6-methyl-N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— Aminomethanedithiolate;diethylamino(sulfanyl)methanethiolate;platinum;tricyclohexylphosphanium —— C24H49N2PPtS4-2
    Aminomethanedithiolate;diethylamino(sulfanyl)methanethiolate;platinum;tricyclohexylphosphanium
    —— (2-Aminocyclopropyl)-(3-aminopropyl)-propylphosphanium;nickel(2+);sulfanylmethylazanide;tris(3-aminopropyl)phosphanium —— C20H55N7NiP2S2+2
    (2-Aminocyclopropyl)-(3-aminopropyl)-propylphosphanium;nickel(2+);sulfanylmethylazanide;tris(3-aminopropyl)phosphanium
    —— 2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;nickel(2+);2-phenylsulfanylbenzenethiolate —— C26H42NiP2S2+2
    2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;nickel(2+);2-phenylsulfanylbenzenethiolate
    —— 3,3-dimethylbutoxymethanedithioic acid —— C7H14OS2
    3,3-dimethylbutoxymethanedithioic acid
    —— 7233-52-5 (Name error) 7233-52-5 C20H56Cd2Cu2I4N4O6S2+2
    7233-52-5 (Name error)
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-phenylsulfanylpyridine-3-carboxamide —— C17H18N2O2S
    N-[[(2S)-oxolan-2-yl]methyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[4-(dimethylamino)phenyl]-1-[3-(2-ethoxy-2-oxo-1-phenylsulfanylethyl)-4-methoxy-6-oxopyran-2-yl]methanimine oxide —— C25H26N2O6S
    N-[4-(dimethylamino)phenyl]-1-[3-(2-ethoxy-2-oxo-1-phenylsulfanylethyl)-4-methoxy-6-oxopyran-2-yl]methanimine oxide
    —— trimethyl-[(E)-3-phenylsulfanylprop-2-enyl]azanium —— C12H18NS+
    trimethyl-[(E)-3-phenylsulfanylprop-2-enyl]azanium
    —— 5-methyl-3-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,2,4-triazole-3,4-diamine —— C11H14N6S
    5-methyl-3-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,2,4-triazole-3,4-diamine
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(E)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide 292052-45-0 C15H15N5O3S
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(E)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide
    —— ethyl (2E)-2-(2-phenylsulfanylpropanoylhydrazinylidene)cyclopentane-1-carboxylate —— C17H22N2O3S
    ethyl (2E)-2-(2-phenylsulfanylpropanoylhydrazinylidene)cyclopentane-1-carboxylate
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide —— C18H18N4OS4
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]triazole-4-carboxamide —— C18H15ClN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]triazole-4-carboxamide
    —— (6E)-5-imino-6-[4-(methylsulfanyl)benzylidene]-2-(pentan-3-yl)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C18H20N4OS2
    (6E)-5-imino-6-[4-(methylsulfanyl)benzylidene]-2-(pentan-3-yl)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— N-[(Z)-hex-5-en-2-ylideneamino]-2-[[5-[2-[(2Z)-2-hex-5-en-2-ylidenehydrazinyl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H26N6O2S3
    N-[(Z)-hex-5-en-2-ylideneamino]-2-[[5-[2-[(2Z)-2-hex-5-en-2-ylidenehydrazinyl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (7E)-5-ethylsulfanyl-7-(furan-2-ylmethylidene)imidazo[5,1-c][1,2,4]triazole —— C11H10N4OS
    (7E)-5-ethylsulfanyl-7-(furan-2-ylmethylidene)imidazo[5,1-c][1,2,4]triazole
    —— 2-[[5-[2-oxo-2-[(2Z)-2-(1-phenylethylidene)hydrazinyl]ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]acetamide —— C22H22N6O2S3
    2-[[5-[2-oxo-2-[(2Z)-2-(1-phenylethylidene)hydrazinyl]ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]acetamide
    —— N-[(Z)-1-(4-aminophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H19N5OS
    N-[(Z)-1-(4-aminophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 7-methyl-3-[(Z)-(3-octyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C27H29N3O2S3
    7-methyl-3-[(Z)-(3-octyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— amino N-cyclohexylcarbamodithioate —— C7H14N2S2
    amino N-cyclohexylcarbamodithioate
    —— ethyl (5Z)-2-(4-methoxyanilino)-4-oxo-5-[(5-phenylsulfanylfuran-2-yl)methylidene]thiophene-3-carboxylate —— C25H21NO5S2
    ethyl (5Z)-2-(4-methoxyanilino)-4-oxo-5-[(5-phenylsulfanylfuran-2-yl)methylidene]thiophene-3-carboxylate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-thiophen-2-ylethylideneamino]triazole-4-carboxamide —— C18H15ClN8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-thiophen-2-ylethylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C23H22N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C16H17FN4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]triazole-4-carboxamide —— C18H15ClN8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(5-chlorothiophen-2-yl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C18H15ClN8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(5-chlorothiophen-2-yl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— ethyl (3Z)-3-[(4-cyano-3-methylsulfanyl-1,2-thiazol-5-yl)hydrazinylidene]-4,4-difluorobutanoate —— C11H12F2N4O2S2
    ethyl (3Z)-3-[(4-cyano-3-methylsulfanyl-1,2-thiazol-5-yl)hydrazinylidene]-4,4-difluorobutanoate
    —— (7Z)-3-(difluoromethyl)-6-methyl-7-[(1-methylpyrazol-3-yl)methylidene]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H10F2N6S
    (7Z)-3-(difluoromethyl)-6-methyl-7-[(1-methylpyrazol-3-yl)methylidene]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (E)-[(4-bromophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide —— C9H7BrN2S2
    (E)-[(4-bromophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide
    —— (E)-[(3-chloro-1,2,4-thiadiazol-5-yl)sulfanylmethylsulfanyl-methylsulfanylmethylidene]cyanamide —— C6H5ClN4S4
    (E)-[(3-chloro-1,2,4-thiadiazol-5-yl)sulfanylmethylsulfanyl-methylsulfanylmethylidene]cyanamide
    —— (Z)-3-Amino-2-[2-[[5-[(2,6-dimethylphenyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile 1146248-00-1 C16H17N5OS2
    (Z)-3-Amino-2-[2-[[5-[(2,6-dimethylphenyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— (E)-[(4-fluorophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide —— C9H7FN2S2
    (E)-[(4-fluorophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide