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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-cyclohexyl-N-methyl-2-methylsulfanyl-5-[[[(2R)-4-phenylbutan-2-yl]amino]methyl]pyrimidin-4-amine —— C23H34N4S
    N-cyclohexyl-N-methyl-2-methylsulfanyl-5-[[[(2R)-4-phenylbutan-2-yl]amino]methyl]pyrimidin-4-amine
    —— (2S)-2-[[4-amino-5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N-(cyclohexylmethyl)propanamide —— C18H32N6O2S2
    (2S)-2-[[4-amino-5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N-(cyclohexylmethyl)propanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-1-(2-propan-2-yliminopyridin-1-yl)propan-1-one —— C17H19ClN2OS
    (2S)-2-(4-chlorophenyl)sulfanyl-1-(2-propan-2-yliminopyridin-1-yl)propan-1-one
    —— (Z)-2-hexylsulfanylhex-2-en-4-yne-1,6-diol —— C12H20O2S
    (Z)-2-hexylsulfanylhex-2-en-4-yne-1,6-diol
    —— 2-ethyl-7-[[5-(4-methylpiperidin-1-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C21H29N7O2S2
    2-ethyl-7-[[5-(4-methylpiperidin-1-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— 2-(3,5-dimethylphenyl)-5-[(2-thiophen-2-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole —— C18H15N3OS3
    2-(3,5-dimethylphenyl)-5-[(2-thiophen-2-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2R)-N-benzyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H20N4O2S
    (2R)-N-benzyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H20N4O2S
    (2S)-N-benzyl-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N-[(Z)-[5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]methylideneamino]-3-nitrobenzamide —— C21H16N4O5S2
    N-[(Z)-[5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]methylideneamino]-3-nitrobenzamide
    —— 1-(2-chlorophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C20H20ClN3S
    1-(2-chlorophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— 1-[(1R)-1-(4-methylsulfanylphenyl)ethyl]piperazine —— C13H20N2S
    1-[(1R)-1-(4-methylsulfanylphenyl)ethyl]piperazine
    —— 1-[(S)-(4-methylsulfanylphenyl)-pyridin-2-ylmethyl]piperazine —— C17H21N3S
    1-[(S)-(4-methylsulfanylphenyl)-pyridin-2-ylmethyl]piperazine
    —— (2S)-N-cyclohexyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H21N3OS3
    (2S)-N-cyclohexyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 1-[(S)-furan-2-yl-(4-methylsulfanylphenyl)methyl]piperazine —— C16H20N2OS
    1-[(S)-furan-2-yl-(4-methylsulfanylphenyl)methyl]piperazine
    —— (2R)-N-cyclohexyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H21N3OS3
    (2R)-N-cyclohexyl-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]-N-methylacetamide —— C23H27FN4O2S
    2-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]-N-methylacetamide
    —— 2-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]-N-methylacetamide —— C23H27FN4O2S
    2-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]-N-methylacetamide
    —— [2-(6-amino-1-benzyl-3-ethyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C24H25N3O5S
    [2-(6-amino-1-benzyl-3-ethyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (1S)-1-(4-methylsulfanylphenyl)-2-piperazin-1-ylethanol —— C13H20N2OS
    (1S)-1-(4-methylsulfanylphenyl)-2-piperazin-1-ylethanol
    —— (1R)-1-(2-ethylsulfanyl-5-methylphenyl)-2-piperazin-1-ylethanol —— C15H24N2OS
    (1R)-1-(2-ethylsulfanyl-5-methylphenyl)-2-piperazin-1-ylethanol
    —— (1S)-1-(5-chloro-2-methylsulfanylphenyl)-2-piperazin-1-ylethanol —— C13H19ClN2OS
    (1S)-1-(5-chloro-2-methylsulfanylphenyl)-2-piperazin-1-ylethanol
    —— (1R)-1-(5-chloro-2-methylsulfanylphenyl)-2-piperazin-1-ylethanol —— C13H19ClN2OS
    (1R)-1-(5-chloro-2-methylsulfanylphenyl)-2-piperazin-1-ylethanol
    —— (1R)-1-(5-chloro-2-ethylsulfanylphenyl)-2-piperazin-1-ylethanol —— C14H21ClN2OS
    (1R)-1-(5-chloro-2-ethylsulfanylphenyl)-2-piperazin-1-ylethanol
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C21H22BrN3O2S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— (2R)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C25H25FN4O2S
    (2R)-2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C21H23N3OS3
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C15H18FN5OS
    (2R)-2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— [2-[(6-amino-1-benzyl-2,4-dioxopyrimidin-5-yl)-ethylamino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C24H26N4O5S
    [2-[(6-amino-1-benzyl-2,4-dioxopyrimidin-5-yl)-ethylamino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— ethyl (2Z)-5-(2-methoxynaphthalen-1-yl)-7-methyl-3-oxo-2-[(5-pyrimidin-2-ylsulfanylfuran-2-yl)methylidene]-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C30H24N4O5S2
    ethyl (2Z)-5-(2-methoxynaphthalen-1-yl)-7-methyl-3-oxo-2-[(5-pyrimidin-2-ylsulfanylfuran-2-yl)methylidene]-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(4-methylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H15ClN2O3S3
    (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(4-methylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (2Z)-2-[(E)-3-anilinoprop-2-enylidene]-1-benzothiophen-3-one —— C17H13NOS
    (2Z)-2-[(E)-3-anilinoprop-2-enylidene]-1-benzothiophen-3-one
    —— (E)-3-(2,4-dimethoxypyrimidin-5-yl)-1-[2-[[6-(methoxymethyl)-2-methylsulfanylpyrimidin-4-yl]oxymethyl]morpholin-4-yl]prop-2-en-1-one —— C21H27N5O6S
    (E)-3-(2,4-dimethoxypyrimidin-5-yl)-1-[2-[[6-(methoxymethyl)-2-methylsulfanylpyrimidin-4-yl]oxymethyl]morpholin-4-yl]prop-2-en-1-one
    —— 2-[(E)-1,2-dichloro-2-pyridin-2-ylsulfanylethenyl]sulfanylpyridine —— C12H8Cl2N2S2
    2-[(E)-1,2-dichloro-2-pyridin-2-ylsulfanylethenyl]sulfanylpyridine
    —— (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-(tetrahydrofuran-2-ylmethyl)prop-2-enamide —— C19H17ClN2O3S
    (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-(tetrahydrofuran-2-ylmethyl)prop-2-enamide
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2-(2-nitrophenyl)acetamide —— C19H13BrClN3O4S
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2-(2-nitrophenyl)acetamide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]pyridine-4-carboxamide —— C18H12N4O2S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]pyridine-4-carboxamide
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-(4-methoxyphenyl)imino-1,3-thiazolidin-4-one —— C23H16ClN3O4S2
    (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-(4-methoxyphenyl)imino-1,3-thiazolidin-4-one
    —— (5E)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-3-propyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C20H18N2O3S3
    (5E)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-3-propyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanylphenyl]methylidene]-2-(4-ethoxyphenyl)imino-1,3-thiazolidin-4-one —— C24H19ClN2O2S2
    (5E)-5-[[4-(4-chlorophenyl)sulfanylphenyl]methylidene]-2-(4-ethoxyphenyl)imino-1,3-thiazolidin-4-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(2,5-difluorophenyl)methylideneamino]triazole-4-carboxamide —— C19H13ClF2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(2,5-difluorophenyl)methylideneamino]triazole-4-carboxamide
    —— N-[(2S)-butan-2-yl]-2-(2-ethylsulfanyl-5-oxopyrimido[4,5-d]pyrimidin-6-yl)acetamide —— C14H19N5O2S
    N-[(2S)-butan-2-yl]-2-(2-ethylsulfanyl-5-oxopyrimido[4,5-d]pyrimidin-6-yl)acetamide
    —— 3-nitro-N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide —— C21H12N6O7S2
    3-nitro-N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide
    —— (6Z)-5-imino-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-propyl-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C20H18N4O2S2
    (6Z)-5-imino-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-propyl-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (6Z)-6-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-5-imino-2-(2-morpholin-4-yl-2-oxoethyl)-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C22H18ClN5O4S2
    (6Z)-6-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-5-imino-2-(2-morpholin-4-yl-2-oxoethyl)-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— 2-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-N-phenyl-6-piperidin-1-yl-1,3,5-triazine-2,4-diamine —— C27H25ClN8O2S
    2-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-N-phenyl-6-piperidin-1-yl-1,3,5-triazine-2,4-diamine
    —— methyl (4Z)-2-methyl-4-[(4-methylsulfanylphenyl)methylidene]-5-oxo-1-(pyridin-3-ylmethyl)pyrrole-3-carboxylate —— C21H20N2O3S
    methyl (4Z)-2-methyl-4-[(4-methylsulfanylphenyl)methylidene]-5-oxo-1-(pyridin-3-ylmethyl)pyrrole-3-carboxylate
    —— (5E)-3-[(2-chloro-6-fluorophenyl)methyl]-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidine-2,4-dione —— C23H13Cl2FN2O4S2
    (5E)-3-[(2-chloro-6-fluorophenyl)methyl]-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidine-2,4-dione
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-3-ylmethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-3-ylmethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— [(2Z)-2-benzylidenehydrazinyl] 2-[2-[[(Z)-benzylideneamino]carbamoyloxymethylsulfanyl]-6-methylpyrimidin-4-yl]oxyacetate —— C23H22N6O5S
    [(2Z)-2-benzylidenehydrazinyl] 2-[2-[[(Z)-benzylideneamino]carbamoyloxymethylsulfanyl]-6-methylpyrimidin-4-yl]oxyacetate
    —— (5Z)-3-[(6-chloro-1,3-benzodioxol-5-yl)methyl]-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidine-2,4-dione —— C25H17ClN2O6S2
    (5Z)-3-[(6-chloro-1,3-benzodioxol-5-yl)methyl]-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidine-2,4-dione