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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]propanamide —— C24H29N7OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]propanamide
    —— N-[(Z)-(2-chlorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H23ClN6OS
    N-[(Z)-(2-chlorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]propanamide —— C24H29N7OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]propanamide
    —— [(E)-[2-(2,5-dimethoxyphenyl)sulfanylphenyl]methylideneamino]urea —— C16H17N3O3S
    [(E)-[2-(2,5-dimethoxyphenyl)sulfanylphenyl]methylideneamino]urea
    —— (4R,8E)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile —— C25H25N3OS2
    (4R,8E)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile
    —— 1-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-methylthiourea —— C15H13ClN4O2S2
    1-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-methylthiourea
    —— 1-benzyl-3-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]thiourea —— C19H17N3OS2
    1-benzyl-3-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]thiourea
    —— (6E)-2,4-dibromo-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-3-methoxycyclohexa-2,4-dien-1-one —— C19H17Br2N3O2S
    (6E)-2,4-dibromo-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-3-methoxycyclohexa-2,4-dien-1-one
    —— N-Hydroxy-thiobenzimidic acid phenyl ester —— C13H11NOS
    N-Hydroxy-thiobenzimidic acid phenyl ester
    —— (Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-phenylmethanimine —— C17H15BrN4S
    (Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-phenylmethanimine
    —— 2-((5-(Benzylthio)-1,3,4-thiadiazol-2-yl)thio)-N'-(1-phenylethylidene)acetohydrazide 315201-30-0 C19H18N4OS3
    2-((5-(Benzylthio)-1,3,4-thiadiazol-2-yl)thio)-N'-(1-phenylethylidene)acetohydrazide
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]acetamide —— C12H10BrN5O3S
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]acetamide
    —— (Z)-1-(3-bromophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15BrN4S
    (Z)-1-(3-bromophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(3-bromophenyl)methanimine —— C16H13BrN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(3-bromophenyl)methanimine
    —— 2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide —— C17H13ClN4OS2
    2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide
    —— (12S)-12-[2-oxo-2-[4-(2-pyrazol-1-ylethyl)piperazin-1-yl]ethyl]-10-thia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3(7),8-dien-2-one —— C20H26N6O2S
    (12S)-12-[2-oxo-2-[4-(2-pyrazol-1-ylethyl)piperazin-1-yl]ethyl]-10-thia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3(7),8-dien-2-one
    —— (12R)-12-[2-oxo-2-[4-(2-pyrazol-1-ylethyl)piperazin-1-yl]ethyl]-10-thia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3(7),8-dien-2-one —— C20H26N6O2S
    (12R)-12-[2-oxo-2-[4-(2-pyrazol-1-ylethyl)piperazin-1-yl]ethyl]-10-thia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3(7),8-dien-2-one
    —— 2-[4-Methyl-5-(2-methylpropylsulfanyl)-1,2,4-triazol-3-yl]ethanamine —— C9H18N4S
    2-[4-Methyl-5-(2-methylpropylsulfanyl)-1,2,4-triazol-3-yl]ethanamine
    —— 4-[5-[(2-fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]piperidine —— C15H19FN4S
    4-[5-[(2-fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]piperidine
    —— 4-[5-[(4-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]piperidine —— C15H19FN4S
    4-[5-[(4-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]piperidine
    —— 2-(4-Methyl-5-propylsulfanyl-1,2,4-triazol-3-yl)ethanamine —— C8H16N4S
    2-(4-Methyl-5-propylsulfanyl-1,2,4-triazol-3-yl)ethanamine
    —— 4-[4-methyl-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]piperidine —— C16H22N4S
    4-[4-methyl-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]piperidine
    —— 4-[4-Methyl-5-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]piperidine —— C16H22N4S
    4-[4-Methyl-5-[(3-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]piperidine
    —— 4-[4-methyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]piperidine —— C16H22N4S
    4-[4-methyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]piperidine
    —— 4-[5-[(3-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]piperidine —— C15H19FN4S
    4-[5-[(3-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]piperidine
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H12BrClN2OS
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C16H14Cl2N2OS
    N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-{[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl}-1-({[(1Z)-1-phenylethylidene]amino}oxy)ethanone —— C19H14F3N3O3S
    2-{[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl}-1-({[(1Z)-1-phenylethylidene]amino}oxy)ethanone
    —— 2,2,2-trifluoro-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C10H9F3N2OS
    2,2,2-trifluoro-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-[[4-[(2R)-2-methyl-3-pyrrolidin-1-ylpropyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H20N4O2S
    2-[[4-[(2R)-2-methyl-3-pyrrolidin-1-ylpropyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(2S)-2-methyl-3-pyrrolidin-1-ylpropyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H20N4O2S
    2-[[4-[(2S)-2-methyl-3-pyrrolidin-1-ylpropyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-N-[(Z)-(3-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H15BrN2OS
    (2S)-N-[(Z)-(3-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (2R)-N-[(Z)-(3-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H15BrN2OS
    (2R)-N-[(Z)-(3-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— N'-hydroxy-6-(oxan-4-ylsulfanyl)pyridine-3-carboximidamide —— C11H15N3O2S
    N'-hydroxy-6-(oxan-4-ylsulfanyl)pyridine-3-carboximidamide
    —— (1S)-N-methyl-1-[2-(oxan-4-ylsulfanyl)phenyl]ethanamine —— C14H21NOS
    (1S)-N-methyl-1-[2-(oxan-4-ylsulfanyl)phenyl]ethanamine
    —— (1R)-N-methyl-1-[2-(oxan-4-ylsulfanyl)phenyl]ethanamine —— C14H21NOS
    (1R)-N-methyl-1-[2-(oxan-4-ylsulfanyl)phenyl]ethanamine
    —— (1R)-N-ethyl-1-[4-(oxan-4-ylsulfanyl)phenyl]ethanamine —— C15H23NOS
    (1R)-N-ethyl-1-[4-(oxan-4-ylsulfanyl)phenyl]ethanamine
    —— (1R)-1-[3-bromo-4-(oxan-4-ylsulfanyl)phenyl]-N-methylethanamine —— C14H20BrNOS
    (1R)-1-[3-bromo-4-(oxan-4-ylsulfanyl)phenyl]-N-methylethanamine
    —— (1S)-N-ethyl-1-[3-fluoro-4-(oxan-4-ylsulfanyl)phenyl]ethanamine —— C15H22FNOS
    (1S)-N-ethyl-1-[3-fluoro-4-(oxan-4-ylsulfanyl)phenyl]ethanamine
    —— N'-hydroxy-3-methyl-4-(oxan-4-ylsulfanyl)benzenecarboximidamide —— C13H18N2O2S
    N'-hydroxy-3-methyl-4-(oxan-4-ylsulfanyl)benzenecarboximidamide
    —— (1S)-N-ethyl-1-[4-(oxan-4-ylsulfanyl)phenyl]ethanamine —— C15H23NOS
    (1S)-N-ethyl-1-[4-(oxan-4-ylsulfanyl)phenyl]ethanamine
    —— (1R)-N-ethyl-1-[3-fluoro-4-(oxan-4-ylsulfanyl)phenyl]ethanamine —— C15H22FNOS
    (1R)-N-ethyl-1-[3-fluoro-4-(oxan-4-ylsulfanyl)phenyl]ethanamine
    —— 5-chloro-N'-hydroxy-2-(oxan-4-ylsulfanyl)benzenecarboximidamide —— C12H15ClN2O2S
    5-chloro-N'-hydroxy-2-(oxan-4-ylsulfanyl)benzenecarboximidamide
    —— (1S)-1-[3-bromo-4-(oxan-4-ylsulfanyl)phenyl]-N-methylethanamine —— C14H20BrNOS
    (1S)-1-[3-bromo-4-(oxan-4-ylsulfanyl)phenyl]-N-methylethanamine
    —— (1S)-N-[(6-methylpyridin-3-yl)methyl]-1-(4-methylsulfanylphenyl)ethanamine —— C16H20N2S
    (1S)-N-[(6-methylpyridin-3-yl)methyl]-1-(4-methylsulfanylphenyl)ethanamine
    —— (1R)-N-[(6-methylpyridin-3-yl)methyl]-1-(4-methylsulfanylphenyl)ethanamine —— C16H20N2S
    (1R)-N-[(6-methylpyridin-3-yl)methyl]-1-(4-methylsulfanylphenyl)ethanamine
    —— (4S,8E)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile —— C25H25N3OS2
    (4S,8E)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile
    —— methyl (4Z)-1-(furan-2-ylmethyl)-2-methyl-4-[(4-methylsulfanylphenyl)methylidene]-5-oxopyrrole-3-carboxylate —— C20H19NO4S
    methyl (4Z)-1-(furan-2-ylmethyl)-2-methyl-4-[(4-methylsulfanylphenyl)methylidene]-5-oxopyrrole-3-carboxylate
    —— (6E)-4-bromo-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-ethoxycyclohexa-2,4-dien-1-one —— C20H20BrN3O2S
    (6E)-4-bromo-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-ethoxycyclohexa-2,4-dien-1-one
    —— 2-[(4-hydroxy-6-oxo-5-propyl-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C17H21N3O3S
    2-[(4-hydroxy-6-oxo-5-propyl-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide