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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (NZ)-N-[[4-[(Z)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine —— C8H10N2O2S3
    (NZ)-N-[[4-[(Z)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-[2-(2,6-dichlorophenyl)ethyl]-7H-purin-3-ium-6-amine —— C20H15BrCl2N5O2S+
    8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-[2-(2,6-dichlorophenyl)ethyl]-7H-purin-3-ium-6-amine
    —— 3-[3-(Diethylamino)propylsulfonyl]-4-(2,5-dimethylphenyl)sulfanylbenzonitrile —— C22H28N2O2S2
    3-[3-(Diethylamino)propylsulfonyl]-4-(2,5-dimethylphenyl)sulfanylbenzonitrile
    —— 6-(4-methylpiperazin-1-yl)-5-(nitrosomethylidene)-6H-pyrrolo[2,1-b][1,3]benzothiazepine —— C18H20N4OS
    6-(4-methylpiperazin-1-yl)-5-(nitrosomethylidene)-6H-pyrrolo[2,1-b][1,3]benzothiazepine
    —— (E)-3-(4-chlorophenyl)sulfanyl-1-thiophen-2-ylprop-2-en-1-one —— C13H9ClOS2
    (E)-3-(4-chlorophenyl)sulfanyl-1-thiophen-2-ylprop-2-en-1-one
    —— 1-Prop-2-ynyl-4-(4-prop-2-ynylphenyl)sulfanylbenzene —— C18H14S
    1-Prop-2-ynyl-4-(4-prop-2-ynylphenyl)sulfanylbenzene
    —— [1-(Tert-butylamino)-3-[[4-[1-hydroxy-2,2,5,5-tetramethyl-4-(nitrooxymethyl)pyrrolidin-3-yl]sulfanyl-1,2,5-thiadiazol-3-yl]oxy]propan-2-yl] nitrate —— C18H32N6O8S2
    [1-(Tert-butylamino)-3-[[4-[1-hydroxy-2,2,5,5-tetramethyl-4-(nitrooxymethyl)pyrrolidin-3-yl]sulfanyl-1,2,5-thiadiazol-3-yl]oxy]propan-2-yl] nitrate
    —— 6-(3-Methylbutan-2-ylsulfonyl)hexane-2-sulfinic acid —— C11H24O4S2
    6-(3-Methylbutan-2-ylsulfonyl)hexane-2-sulfinic acid
    —— (4Z)-4-[(4-chlorophenyl)methylidene]-3-(phenylsulfanylmethyl)-1,2-oxazol-5-one —— C17H12ClNO2S
    (4Z)-4-[(4-chlorophenyl)methylidene]-3-(phenylsulfanylmethyl)-1,2-oxazol-5-one
    —— 4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]-2-(3-nitropyridin-2-yl)sulfanylpyrimidine —— C16H12N4O2S2
    4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]-2-(3-nitropyridin-2-yl)sulfanylpyrimidine
    —— 2,2,4-Trimethylpentane-1,5-dithiol —— C8H18S2
    2,2,4-Trimethylpentane-1,5-dithiol
    —— (4Z)-4-benzylidene-3-(phenylsulfanylmethyl)-1,2-oxazol-5-one —— C17H13NO2S
    (4Z)-4-benzylidene-3-(phenylsulfanylmethyl)-1,2-oxazol-5-one
    —— 2-[4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]pyrimidin-2-yl]sulfanyl-5-nitro-1,3-thiazole —— C14H10N4O2S3
    2-[4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]pyrimidin-2-yl]sulfanyl-5-nitro-1,3-thiazole
    —— 2-(2,4-dinitrophenyl)sulfanyl-4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]pyrimidine —— C17H12N4O4S2
    2-(2,4-dinitrophenyl)sulfanyl-4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]pyrimidine
    —— 2-[(3-chlorophenyl)methylsulfanyl]-4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]pyrimidine —— C18H15ClN2S2
    2-[(3-chlorophenyl)methylsulfanyl]-4-[(E)-2-(3-methylthiophen-2-yl)ethenyl]pyrimidine
    —— 1-(3-chlorophenyl)-5-heptyl-6-hydroxy-2-methylsulfanylpyrimidin-4-one —— C18H23ClN2O2S
    1-(3-chlorophenyl)-5-heptyl-6-hydroxy-2-methylsulfanylpyrimidin-4-one
    —— 4-(4-chlorophenyl)-5-[(E)-3-(dimethylamino)prop-2-enoyl]-2-methylsulfanylthiophene-3-carbonitrile —— C17H15ClN2OS2
    4-(4-chlorophenyl)-5-[(E)-3-(dimethylamino)prop-2-enoyl]-2-methylsulfanylthiophene-3-carbonitrile
    —— (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-(thiophene-2-carbonyl)prop-2-enenitrile —— C18H10ClNOS3
    (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-(thiophene-2-carbonyl)prop-2-enenitrile
    —— (Z)-[3-(4-chlorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine —— C11H9ClN4OS
    (Z)-[3-(4-chlorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine
    —— (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfonylprop-2-enenitrile —— C19H10ClF3N2O2S3
    (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfonylprop-2-enenitrile
    —— (NE)-N-(1-bromo-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)hydroxylamine —— C11H14BrNOS2
    (NE)-N-(1-bromo-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)hydroxylamine
    —— (4E)-4-hydroxyimino-3-methylsulfanyl-6,7-dihydro-5H-2-benzothiophene-1-carbonitrile —— C10H10N2OS2
    (4E)-4-hydroxyimino-3-methylsulfanyl-6,7-dihydro-5H-2-benzothiophene-1-carbonitrile
    —— (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-(4-chlorophenyl)sulfonylprop-2-enenitrile —— C19H11Cl2NO2S3
    (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-(4-chlorophenyl)sulfonylprop-2-enenitrile
    —— [(Z)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-(4-chlorophenyl)carbamate —— C18H19ClN2O2S2
    [(Z)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-(4-chlorophenyl)carbamate
    —— 3-[(4-chlorophenyl)methylsulfanyl]-1-[(E)-3-(dimethylamino)prop-2-enoyl]-6,6-dimethyl-5,7-dihydro-2-benzothiophen-4-one —— C22H24ClNO2S2
    3-[(4-chlorophenyl)methylsulfanyl]-1-[(E)-3-(dimethylamino)prop-2-enoyl]-6,6-dimethyl-5,7-dihydro-2-benzothiophen-4-one
    —— [(Z)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-phenylcarbamate —— C18H20N2O2S2
    [(Z)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-phenylcarbamate
    —— [(Z)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-methylcarbamate —— C13H18N2O2S2
    [(Z)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-methylcarbamate
    —— 5-[(E)-3-(dimethylamino)prop-2-enoyl]-2-methylsulfanyl-4-phenylthiophene-3-carbonitrile —— C17H16N2OS2
    5-[(E)-3-(dimethylamino)prop-2-enoyl]-2-methylsulfanyl-4-phenylthiophene-3-carbonitrile
    —— (NE)-N-[1-[(4E)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-1-yl]ethylidene]hydroxylamine —— C13H18N2O2S2
    (NE)-N-[1-[(4E)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-1-yl]ethylidene]hydroxylamine
    —— 2-Methylsulfanylhex-3-yne —— C7H12S
    2-Methylsulfanylhex-3-yne
    —— (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-methylsulfonylprop-2-enenitrile —— C14H10ClNO2S3
    (E)-3-[2-(4-chlorophenyl)sulfanylthiophen-3-yl]-2-methylsulfonylprop-2-enenitrile
    —— (E)-2-tert-butylsulfonyl-3-[(2Z)-2-(2,2-dimethylpropylidene)hydrazinyl]prop-2-enenitrile —— C12H21N3O2S
    (E)-2-tert-butylsulfonyl-3-[(2Z)-2-(2,2-dimethylpropylidene)hydrazinyl]prop-2-enenitrile
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-cyano-5-methylsulfanyl-3-thiophen-2-ylpyrazol-1-yl)acetamide —— C18H13ClFN5OS2
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-cyano-5-methylsulfanyl-3-thiophen-2-ylpyrazol-1-yl)acetamide
    —— (E)-3-[2-(4-chlorophenyl)sulfanylphenyl]-2-pyridin-2-ylsulfonylprop-2-enenitrile —— C20H13ClN2O2S2
    (E)-3-[2-(4-chlorophenyl)sulfanylphenyl]-2-pyridin-2-ylsulfonylprop-2-enenitrile
    —— (2E)-2-[(4-chlorophenyl)methylidene]-1-benzothiophen-3-one —— C15H9ClOS
    (2E)-2-[(4-chlorophenyl)methylidene]-1-benzothiophen-3-one
    —— (E)-3-[2-(4-chlorophenyl)sulfanylphenyl]-2-(3-methylimidazol-4-yl)sulfonylprop-2-enenitrile —— C19H14ClN3O2S2
    (E)-3-[2-(4-chlorophenyl)sulfanylphenyl]-2-(3-methylimidazol-4-yl)sulfonylprop-2-enenitrile
    —— (Z)-N-[(4-bromophenyl)methoxy]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)ethanimine —— C20H16BrN3O3S
    (Z)-N-[(4-bromophenyl)methoxy]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)ethanimine
    —— (3Z)-3-[[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylidene]-1H-indol-2-one —— C20H12ClN3OS2
    (3Z)-3-[[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylidene]-1H-indol-2-one
    —— 6-amino-3-benzyl-2-(benzylthio)pyrimidin-4(3H)-one 1620909-86-5 C18H17N3OS
    6-amino-3-benzyl-2-(benzylthio)pyrimidin-4(3H)-one
    —— 6-(benzyloxy)-2-(benzylthio)pyrimidin-4-amine 1620909-73-0 C18H17N3OS
    6-(benzyloxy)-2-(benzylthio)pyrimidin-4-amine
    —— S-(4-chlorophenyl) N-[(E)-2-thiophen-3-ylethenyl]carbamothioate —— C13H10ClNOS2
    S-(4-chlorophenyl) N-[(E)-2-thiophen-3-ylethenyl]carbamothioate
    —— S-(4-chloro-2,5-dimethylphenyl) N-[(E)-2-(furan-2-yl)ethenyl]carbamothioate —— C15H14ClNO2S
    S-(4-chloro-2,5-dimethylphenyl) N-[(E)-2-(furan-2-yl)ethenyl]carbamothioate
    —— S-(4-methylphenyl) N-[(E)-2-thiophen-3-ylethenyl]carbamothioate —— C14H13NOS2
    S-(4-methylphenyl) N-[(E)-2-thiophen-3-ylethenyl]carbamothioate
    —— (Z)-4-oxo-4-[2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylanilino]but-2-enoic acid —— C15H10F3N3O3S
    (Z)-4-oxo-4-[2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylanilino]but-2-enoic acid
    —— N'-[2-[2-(12-aminododecylamino)ethyldisulfanyl]ethyl]dodecane-1,12-diamine;hydrochloride —— C28H63ClN4S2
    N'-[2-[2-(12-aminododecylamino)ethyldisulfanyl]ethyl]dodecane-1,12-diamine;hydrochloride
    —— N'-[2-[2-(9-aminononylamino)ethyldisulfanyl]ethyl]nonane-1,9-diamine;hydrochloride —— C22H51ClN4S2
    N'-[2-[2-(9-aminononylamino)ethyldisulfanyl]ethyl]nonane-1,9-diamine;hydrochloride
    —— N'-[2-[2-(10-aminodecylamino)ethyldisulfanyl]ethyl]decane-1,10-diamine;hydrochloride —— C24H55ClN4S2
    N'-[2-[2-(10-aminodecylamino)ethyldisulfanyl]ethyl]decane-1,10-diamine;hydrochloride
    —— (2E)-6-chloro-2-[(2-hydroxyphenyl)methylidene]-4-methyl-1-benzothiophen-3-one —— C16H11ClO2S
    (2E)-6-chloro-2-[(2-hydroxyphenyl)methylidene]-4-methyl-1-benzothiophen-3-one
    —— (2E)-6-chloro-4-methyl-2-(pyridin-3-ylmethylidene)-1-benzothiophen-3-one —— C15H10ClNOS
    (2E)-6-chloro-4-methyl-2-(pyridin-3-ylmethylidene)-1-benzothiophen-3-one
    —— (4Z)-2-[2-(4-methylphenyl)sulfanylpyridin-3-yl]-4-[[4-(trifluoromethyl)phenyl]methylidene]-1,3-oxazol-5-one —— C23H15F3N2O2S
    (4Z)-2-[2-(4-methylphenyl)sulfanylpyridin-3-yl]-4-[[4-(trifluoromethyl)phenyl]methylidene]-1,3-oxazol-5-one