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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(hydroxymethyl)-2-methyl-3-methylsulfanylpropanal —— C6H12O2S
    (2S)-2-(hydroxymethyl)-2-methyl-3-methylsulfanylpropanal
    —— (2R)-2-sulfanylpropanal —— C3H6OS
    (2R)-2-sulfanylpropanal
    —— 3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-(propan-2-yl)-5H-[1,2,4]triazino[5,6-b]indole —— C18H13N7O2S2
    3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-(propan-2-yl)-5H-[1,2,4]triazino[5,6-b]indole
    —— 3-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-1,2,4-triazole-3,4-diamine —— C10H12N6S
    3-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-1,2,4-triazole-3,4-diamine
    —— [(Z)-4-(5-fluoro-2-hydroxyphenyl)sulfanylbut-1-enyl]phosphonic acid —— C10H12FO4PS
    [(Z)-4-(5-fluoro-2-hydroxyphenyl)sulfanylbut-1-enyl]phosphonic acid
    —— (4Z)-4-[[6-methoxy-2-(4-methylphenyl)sulfanylquinolin-3-yl]methylidene]-2-(4-methoxyphenyl)-1,3-oxazol-5-one —— C28H22N2O4S
    (4Z)-4-[[6-methoxy-2-(4-methylphenyl)sulfanylquinolin-3-yl]methylidene]-2-(4-methoxyphenyl)-1,3-oxazol-5-one
    —— (1R,3R)-N,3-dimethyl-N-[(1Z)-3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]cyclohexan-1-amine —— C18H21Cl3N2O2S
    (1R,3R)-N,3-dimethyl-N-[(1Z)-3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]cyclohexan-1-amine
    —— 4-methyl-3-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazole —— C8H13N3OS
    4-methyl-3-[[(2S)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazole
    —— 3-[methyl-[(2R)-2-(5-nitropyridin-2-yl)sulfanylpropanoyl]amino]propanoic acid —— C12H15N3O5S
    3-[methyl-[(2R)-2-(5-nitropyridin-2-yl)sulfanylpropanoyl]amino]propanoic acid
    —— (4S)-4,8,8-trimethylnonane-4-thiol —— C12H26S
    (4S)-4,8,8-trimethylnonane-4-thiol
    —— (4R)-4,8,8-trimethylnonane-4-thiol —— C12H26S
    (4R)-4,8,8-trimethylnonane-4-thiol
    —— (Z,4R)-4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-1-(dimethylamino)pent-1-en-3-one —— C13H14ClF3N2OS
    (Z,4R)-4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-1-(dimethylamino)pent-1-en-3-one
    —— 1-[(3R,3aR,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C24H20N4O5S
    1-[(3R,3aR,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 4-hydroxy-2-[(Z)-2-[4-(4-methylphenyl)sulfanylphenyl]ethenyl]-5-nitro-1H-pyrimidin-6-one —— C19H15N3O4S
    4-hydroxy-2-[(Z)-2-[4-(4-methylphenyl)sulfanylphenyl]ethenyl]-5-nitro-1H-pyrimidin-6-one
    —— (5Z)-2-[(2S)-2-(2-hydroxyethyl)piperidin-1-yl]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one —— C18H22N2O2S2
    (5Z)-2-[(2S)-2-(2-hydroxyethyl)piperidin-1-yl]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one
    —— (5Z)-2-[(2R)-2-(2-hydroxyethyl)piperidin-1-yl]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one —— C18H22N2O2S2
    (5Z)-2-[(2R)-2-(2-hydroxyethyl)piperidin-1-yl]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one
    —— 3-[(5-Thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-amine —— C9H11N3OS2
    3-[(5-Thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-amine
    —— 3-[(5-Pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-amine —— C10H12N4OS
    3-[(5-Pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-amine
    —— 3-[(5-Pyridin-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-amine —— C10H12N4OS
    3-[(5-Pyridin-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-amine
    —— 3-[[5-(Furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propan-1-amine —— C10H14N4OS
    3-[[5-(Furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propan-1-amine
    —— 1-[(3R,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C21H21N5O3S
    1-[(3R,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (Z)-2-(1H-benzimidazol-2-yl)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]prop-2-enenitrile —— C20H12ClN3OS
    (Z)-2-(1H-benzimidazol-2-yl)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]prop-2-enenitrile
    —— 1-(3-bromophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C20H20BrN3S
    1-(3-bromophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— dizinc;(2Z)-2-[(4-ethyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-4-[5-[(Z)-(4-ethyl-3,5-dimethylpyrrol-2-ylidene)methyl]-2,4-dimethylpyrrol-1-id-3-yl]sulfanyl-3,5-dimethylpyrrole —— C60H72N8S2Zn2
    dizinc;(2Z)-2-[(4-ethyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-4-[5-[(Z)-(4-ethyl-3,5-dimethylpyrrol-2-ylidene)methyl]-2,4-dimethylpyrrol-1-id-3-yl]sulfanyl-3,5-dimethylpyrrole
    —— ethyl 4-(6'-amino-4'-oxo-2'-pyrimidinethio)-3-aminocrotonate 78974-61-5 C10H14N4O3S
    ethyl 4-(6'-amino-4'-oxo-2'-pyrimidinethio)-3-aminocrotonate
    —— (2S)-2-(2,5-dimethylphenyl)sulfanyl-3-methylbutanoyl chloride —— C13H17ClOS
    (2S)-2-(2,5-dimethylphenyl)sulfanyl-3-methylbutanoyl chloride
    —— propan-2-yl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H26N2O3S3
    propan-2-yl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (5Z)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(4-nitrophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C20H11ClN2O4S3
    (5Z)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(4-nitrophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (2R)-2-(2,5-dimethylphenyl)sulfanyl-3-methylbutanoyl chloride —— C13H17ClOS
    (2R)-2-(2,5-dimethylphenyl)sulfanyl-3-methylbutanoyl chloride
    —— (2R)-2-(2,4-dimethylphenyl)sulfanyl-3-methylbutanamide —— C13H19NOS
    (2R)-2-(2,4-dimethylphenyl)sulfanyl-3-methylbutanamide
    —— (2R)-2-(3,5-dimethylphenyl)sulfanylpropanoyl chloride —— C11H13ClOS
    (2R)-2-(3,5-dimethylphenyl)sulfanylpropanoyl chloride
    —— (2S)-3-methyl-2-phenylsulfanylbutanoyl chloride —— C11H13ClOS
    (2S)-3-methyl-2-phenylsulfanylbutanoyl chloride
    —— (2R)-3-methyl-2-phenylsulfanylbutanoyl chloride —— C11H13ClOS
    (2R)-3-methyl-2-phenylsulfanylbutanoyl chloride
    —— (2R)-3-methyl-2-(2-methylphenyl)sulfanylbutanoyl chloride —— C12H15ClOS
    (2R)-3-methyl-2-(2-methylphenyl)sulfanylbutanoyl chloride
    —— (2S)-2-phenylsulfanylpropanoyl chloride —— C9H9ClOS
    (2S)-2-phenylsulfanylpropanoyl chloride
    —— (2S)-2-(2,4-dimethylphenyl)sulfanylpropanoyl chloride —— C11H13ClOS
    (2S)-2-(2,4-dimethylphenyl)sulfanylpropanoyl chloride
    —— (2R)-2-(3-chlorophenyl)sulfanylpropanamide —— C9H10ClNOS
    (2R)-2-(3-chlorophenyl)sulfanylpropanamide
    —— (2S)-3-methyl-2-(3-methylphenyl)sulfanylbutanoyl chloride —— C12H15ClOS
    (2S)-3-methyl-2-(3-methylphenyl)sulfanylbutanoyl chloride
    —— (2R)-3-methyl-2-phenylsulfanylbutanamide —— C11H15NOS
    (2R)-3-methyl-2-phenylsulfanylbutanamide
    —— (2R)-2-phenylsulfanylpropanoyl chloride —— C9H9ClOS
    (2R)-2-phenylsulfanylpropanoyl chloride
    —— (2S)-3-methyl-2-(2-methylphenyl)sulfanylbutanamide —— C12H17NOS
    (2S)-3-methyl-2-(2-methylphenyl)sulfanylbutanamide
    —— [(E)-1-(4-phenylsulfanylphenyl)ethylideneamino] 4-chlorobenzoate —— C21H16ClNO2S
    [(E)-1-(4-phenylsulfanylphenyl)ethylideneamino] 4-chlorobenzoate
    —— (2R)-2-(2-methylphenyl)sulfanylpropanoyl chloride —— C10H11ClOS
    (2R)-2-(2-methylphenyl)sulfanylpropanoyl chloride
    —— ethyl (2Z)-2-[(5-bromothiophen-2-yl)methylidene]-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C22H19BrN2O3S3
    ethyl (2Z)-2-[(5-bromothiophen-2-yl)methylidene]-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(Z)-(3-bromophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C15H15BrN4OS
    N-[(Z)-(3-bromophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-[(4,6-Dimethylpyrimidin-2-YL)sulfanyl]-N'-[(Z)-(2-fluorophenyl)methylidene]acetohydrazide —— C15H15FN4OS
    2-[(4,6-Dimethylpyrimidin-2-YL)sulfanyl]-N'-[(Z)-(2-fluorophenyl)methylidene]acetohydrazide
    —— 3-{[(2-methyl-1,3-thiazol-4-yl)methyl]sulfanyl}-5-[(E)-2-(phenylamino)ethenyl]-1,2-thiazole-4-carbonitrile —— C17H14N4S3
    3-{[(2-methyl-1,3-thiazol-4-yl)methyl]sulfanyl}-5-[(E)-2-(phenylamino)ethenyl]-1,2-thiazole-4-carbonitrile
    —— (2S)-N-[(E)-(4-bromo-5-methylfuran-2-yl)methylideneamino]-2-phenylsulfanylpropanamide —— C15H15BrN2O2S
    (2S)-N-[(E)-(4-bromo-5-methylfuran-2-yl)methylideneamino]-2-phenylsulfanylpropanamide
    —— (Z)-2-(benzenesulfonyl)-3-[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]prop-2-enenitrile —— C21H13ClN2O4S2
    (Z)-2-(benzenesulfonyl)-3-[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]prop-2-enenitrile
    —— [(Z)-(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylideneamino]thiourea —— C17H13N5O2S2
    [(Z)-(3-nitro-4-quinolin-8-ylsulfanylphenyl)methylideneamino]thiourea