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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R,5S)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one —— C13H16O2S
    (3R,5S)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one
    —— 3-(2-chlorophenyl)sulfanyl-N-[2-(1-methylpyrazol-4-yl)ethyl]propanamide —— C15H18ClN3OS
    3-(2-chlorophenyl)sulfanyl-N-[2-(1-methylpyrazol-4-yl)ethyl]propanamide
    —— N-[(5E)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazol-2-yl]acetamide —— C13H12N2O2S2
    N-[(5E)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazol-2-yl]acetamide
    —— N-[2-(1-methylpyrazol-4-yl)ethyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C14H15F3N4OS
    N-[2-(1-methylpyrazol-4-yl)ethyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[2-(1-methylpyrazol-4-yl)ethyl]propanamide —— C15H18ClN3OS
    3-(4-chlorophenyl)sulfanyl-N-[2-(1-methylpyrazol-4-yl)ethyl]propanamide
    —— Cambridge id 5958582 —— C10H15ClN2O4S
    Cambridge id 5958582
    —— 3-(2-hydroxyphenyl)-N'-{[5-(8-quinolinylthio)-2-furyl]methylene}propanohydrazide —— C23H19N3O3S
    3-(2-hydroxyphenyl)-N'-{[5-(8-quinolinylthio)-2-furyl]methylene}propanohydrazide
    —— 3-fluoro-N-[(E)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide —— C21H14FN3O2S
    3-fluoro-N-[(E)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— 2-{[(4-Chlorophenyl)methyl]sulfanyl}-N'-[(E)-[5-(quinolin-8-ylsulfanyl)furan-2-YL]methylidene]acetohydrazide —— C23H18ClN3O2S2
    2-{[(4-Chlorophenyl)methyl]sulfanyl}-N'-[(E)-[5-(quinolin-8-ylsulfanyl)furan-2-YL]methylidene]acetohydrazide
    —— 2-[(4-bromophenyl)methylsulfanyl]-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide —— C19H16BrN3O2S2
    2-[(4-bromophenyl)methylsulfanyl]-N-[(E)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— 5-[(2-methyl-1,3-thiazol-5-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C12H16N4OS3
    5-[(2-methyl-1,3-thiazol-5-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— [(Z)-(3-oxo-1-benzothiophen-2-ylidene)amino] acetate —— C10H7NO3S
    [(Z)-(3-oxo-1-benzothiophen-2-ylidene)amino] acetate
    —— (2S)-3-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide —— C17H23N5OS
    (2S)-3-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide
    —— 5-[(2-methyl-1,3-thiazol-5-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C12H16N4OS3
    5-[(2-methyl-1,3-thiazol-5-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— (2Z)-2-[(pyridin-4-ylmethylamino)methylidene]-1-benzothiophen-3-one —— C15H12N2OS
    (2Z)-2-[(pyridin-4-ylmethylamino)methylidene]-1-benzothiophen-3-one
    —— (2R)-3-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide —— C17H23N5OS
    (2R)-3-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide
    —— methyl (2R)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C15H24N4O3S
    methyl (2R)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— methyl (2S)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C15H24N4O3S
    methyl (2S)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— methyl (2R)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C15H24N4O3S
    methyl (2R)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— (3S)-3-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one —— C15H22N4O3S
    (3S)-3-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one
    —— (3R)-3-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one —— C15H22N4O3S
    (3R)-3-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one
    —— (3S)-3-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one —— C15H22N4O3S
    (3S)-3-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2R)-2-(4-methylpiperidin-1-yl)propyl]acetamide —— C17H28N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2R)-2-(4-methylpiperidin-1-yl)propyl]acetamide
    —— (3R)-3-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one —— C15H22N4O3S
    (3R)-3-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]oxolan-2-one
    —— N-[(2S)-1-methoxypropan-2-yl]-3-phenylsulfanylpropanamide —— C13H19NO2S
    N-[(2S)-1-methoxypropan-2-yl]-3-phenylsulfanylpropanamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3S)-1-propan-2-ylpyrrolidin-3-yl]methyl]acetamide —— C16H26N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3S)-1-propan-2-ylpyrrolidin-3-yl]methyl]acetamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3S)-1-propan-2-ylpiperidin-3-yl]methyl]acetamide —— C17H28N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3S)-1-propan-2-ylpiperidin-3-yl]methyl]acetamide
    —— methyl (2S)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C15H24N4O3S
    methyl (2S)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3R)-1-propan-2-ylpyrrolidin-3-yl]methyl]acetamide —— C16H26N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3R)-1-propan-2-ylpyrrolidin-3-yl]methyl]acetamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-2-(4-methylpiperidin-1-yl)propyl]acetamide —— C17H28N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-2-(4-methylpiperidin-1-yl)propyl]acetamide
    —— 3-methyl-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-1H-pyrazole-5-carbohydrazide —— C13H14N4OS
    3-methyl-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-1H-pyrazole-5-carbohydrazide
    —— ethyl (2Z)-2-[(5-bromo-2-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21BrN2O4S2
    ethyl (2Z)-2-[(5-bromo-2-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-3-cyanothiolan-3-yl]propanamide —— C14H15ClN2OS2
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-3-cyanothiolan-3-yl]propanamide
    —— ethyl (2Z)-2-[[5-(4-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C28H23ClN2O4S2
    ethyl (2Z)-2-[[5-(4-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5-phenyl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H22N2O3S2
    ethyl (2Z)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5-phenyl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C25H24N2O3S2
    ethyl (2Z)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— Ethyl (2Z)-2-{[3-bromo-4-(dimethylamino)phenyl]methylidene}-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2H,3H,5H-[1,3]thiazolo[3,2-A]pyrimidine-6-carboxylate —— C26H26BrN3O3S2
    Ethyl (2Z)-2-{[3-bromo-4-(dimethylamino)phenyl]methylidene}-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2H,3H,5H-[1,3]thiazolo[3,2-A]pyrimidine-6-carboxylate
    —— ethyl (2Z)-5-(4-chlorophenyl)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21ClN2O3S2
    ethyl (2Z)-5-(4-chlorophenyl)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3R)-1-propan-2-ylpiperidin-3-yl]methyl]acetamide —— C17H28N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[[(3R)-1-propan-2-ylpiperidin-3-yl]methyl]acetamide
    —— ethyl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-(pyridin-3-ylmethylidene)-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C23H21N3O3S2
    ethyl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-(pyridin-3-ylmethylidene)-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-2-(4-bromobenzylidene)-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21BrN2O3S2
    ethyl (2Z)-2-(4-bromobenzylidene)-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-2-[4-(diethylamino)benzylidene]-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C28H31N3O3S2
    ethyl (2Z)-2-[4-(diethylamino)benzylidene]-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-3-cyanothiolan-3-yl]propanamide —— C14H15ClN2OS2
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-3-cyanothiolan-3-yl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-3-cyanothiolan-3-yl]propanamide —— C14H15ClN2OS2
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3R)-3-cyanothiolan-3-yl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-3-cyanothiolan-3-yl]propanamide —— C14H15ClN2OS2
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(3S)-3-cyanothiolan-3-yl]propanamide
    —— ethyl (2Z)-2-[(2-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H22N2O4S2
    ethyl (2Z)-2-[(2-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 3-(benzylsulfanyl)-N-{(E)-[4-(dimethylamino)phenyl]methylidene}-4H-1,2,4-triazol-4-amine —— C18H19N5S
    3-(benzylsulfanyl)-N-{(E)-[4-(dimethylamino)phenyl]methylidene}-4H-1,2,4-triazol-4-amine
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(furan-2-yl)methanimine —— C14H12N4OS
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(furan-2-yl)methanimine
    —— N-(3,5-dimethyl-4H-1,2,4-triazol-4-yl)-N-{(E)-[4-(methylthio)phenyl]methylidene}amine —— C12H14N4S
    N-(3,5-dimethyl-4H-1,2,4-triazol-4-yl)-N-{(E)-[4-(methylthio)phenyl]methylidene}amine
    —— N-[(2R)-2-cyanopropyl]-3-(2-fluorophenyl)sulfanyl-N-methylpropanamide —— C14H17FN2OS
    N-[(2R)-2-cyanopropyl]-3-(2-fluorophenyl)sulfanyl-N-methylpropanamide