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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(3,4-dimethylphenyl)-1-[5-[[5-(naphthalen-1-ylmethyl)-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]furan-2-yl]methanimine —— C32H26N4OS
    N-(3,4-dimethylphenyl)-1-[5-[[5-(naphthalen-1-ylmethyl)-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]furan-2-yl]methanimine
    —— N-(2-benzylsulfanyl-1,3-benzothiazol-6-yl)-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C26H18N4O2S3
    N-(2-benzylsulfanyl-1,3-benzothiazol-6-yl)-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— 1-(4-fluorophenyl)-N-(2-methylsulfanylphenyl)methanimine —— C14H12FNS
    1-(4-fluorophenyl)-N-(2-methylsulfanylphenyl)methanimine
    —— (1Z)-1-methylsulfanyl-N-(pentafluoro-lambda6-sulfanyl)methanimidoyl chloride —— C2H3ClF5NS2
    (1Z)-1-methylsulfanyl-N-(pentafluoro-lambda6-sulfanyl)methanimidoyl chloride
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]propanamide —— C23H26N6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]propanamide
    —— N-(4-methylphenyl)-1-[5-[[5-(naphthalen-1-ylmethyl)-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]furan-2-yl]methanimine —— C31H24N4OS
    N-(4-methylphenyl)-1-[5-[[5-(naphthalen-1-ylmethyl)-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]furan-2-yl]methanimine
    —— N-(2-ethylsulfanyl-1,3-benzothiazol-6-yl)-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C21H16N4O2S3
    N-(2-ethylsulfanyl-1,3-benzothiazol-6-yl)-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]propanamide —— C23H26N6OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]propanamide
    —— Propanoic acid, 2,2-dimethyl-, 5-(phenylthio)-3-methyl-3-pentenyl ester —— C17H24O2S
    Propanoic acid, 2,2-dimethyl-, 5-(phenylthio)-3-methyl-3-pentenyl ester
    —— (2S)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]propanamide —— C21H22ClN7OS
    (2S)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]propanamide
    —— (2R)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]propanamide —— C21H22ClN7OS
    (2R)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]propanamide
    —— (1R,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-one —— C12H12F2N2O3S
    (1R,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-one
    —— (3Z,19E)-28,31-dithia-2,10,13,21-tetrazapentacyclo[30.4.0.04,9.014,19.022,27]hexatriaconta-1(36),3,5,7,9,13,15,17,19,22,24,26,32,34-tetradecaene —— C30H28N4S2
    (3Z,19E)-28,31-dithia-2,10,13,21-tetrazapentacyclo[30.4.0.04,9.014,19.022,27]hexatriaconta-1(36),3,5,7,9,13,15,17,19,22,24,26,32,34-tetradecaene
    —— N-benzyl-N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]propanediamide —— C18H19N3O2S
    N-benzyl-N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]propanediamide
    —— 2-hydroxy-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C10H12N2O2S
    2-hydroxy-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N-prop-2-enylpropanediamide —— C14H17N3O2S
    N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N-prop-2-enylpropanediamide
    —— N-cyclohexyl-N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]propanediamide —— C17H23N3O2S
    N-cyclohexyl-N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]propanediamide
    —— (2S)-2-hydroxy-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C11H14N2O2S
    (2S)-2-hydroxy-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— (2R)-2-hydroxy-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C11H14N2O2S
    (2R)-2-hydroxy-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N-(2-phenylethyl)propanediamide —— C19H21N3O2S
    N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N-(2-phenylethyl)propanediamide
    —— Phenyl N-hydroxybenzenecarbimidothioate —— C13H11NOS
    Phenyl N-hydroxybenzenecarbimidothioate
    —— 4-Methylene-3a,4,5,6,7,9a-hexahydrocycloocta[1,3]dioxole-2-thione —— C10H12O2S
    4-Methylene-3a,4,5,6,7,9a-hexahydrocycloocta[1,3]dioxole-2-thione
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-4-phenylbutanamide —— C18H20N2OS
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-4-phenylbutanamide
    —— (E)-[(3-bromo-1,2,4-thiadiazol-5-yl)sulfanylmethylsulfanyl-methylsulfanylmethylidene]cyanamide —— C6H5BrN4S4
    (E)-[(3-bromo-1,2,4-thiadiazol-5-yl)sulfanylmethylsulfanyl-methylsulfanylmethylidene]cyanamide
    —— 3a,4,5,6,7,9a-Hexahydrocycloocta-1,3-dioxole-2-thione —— C9H12O2S
    3a,4,5,6,7,9a-Hexahydrocycloocta-1,3-dioxole-2-thione
    —— r-Mercaptoethanol —— C2H6OS
    r-Mercaptoethanol
    —— (1S)-1-sulfanylethanol —— C2H6OS
    (1S)-1-sulfanylethanol
    —— 1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-naphthalen-2-ylmethanimine —— C21H16N4O2S
    1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-naphthalen-2-ylmethanimine
    —— 11-Thiabicyclo[4.4.3]trideca-3,8,0-triene,11,11-dioxide —— C12H16O2S
    11-Thiabicyclo[4.4.3]trideca-3,8,0-triene,11,11-dioxide
    —— N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]pentanamide —— C16H18N2O2S
    N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]pentanamide
    —— 1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-(4-pentoxyphenyl)methanimine —— C22H24N4O3S
    1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-(4-pentoxyphenyl)methanimine
    —— N-(4-pentoxyphenyl)-1-(5-phenylsulfanylfuran-2-yl)methanimine —— C22H23NO2S
    N-(4-pentoxyphenyl)-1-(5-phenylsulfanylfuran-2-yl)methanimine
    —— N-(4-methoxyphenyl)-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methanimine —— C18H16N4O3S
    N-(4-methoxyphenyl)-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methanimine
    —— (NZ)-N-(2-methyl-2-methylsulfinylpropylidene)hydroxylamine —— C5H11NO2S
    (NZ)-N-(2-methyl-2-methylsulfinylpropylidene)hydroxylamine
    —— 1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-phenylmethanimine —— C17H14N4O2S
    1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]-N-phenylmethanimine
    —— N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]benzamide —— C18H14N2O2S
    N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]furan-2-carboxamide —— C16H13N5O4S
    N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]furan-2-carboxamide
    —— 4-fluoro-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]benzamide —— C18H13FN2O2S
    4-fluoro-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— 1,2-Dithiin, 3,4-dihydro-4-methyl-3-(1-propenyl)- —— C8H12S2
    1,2-Dithiin, 3,4-dihydro-4-methyl-3-(1-propenyl)-
    —— N-(3,4-dimethylphenyl)-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methanimine —— C19H18N4O2S
    N-(3,4-dimethylphenyl)-1-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methanimine
    —— 2-methoxy-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide —— C14H14N2O3S
    2-methoxy-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— N-naphthalen-2-yl-1-(5-phenylsulfanylfuran-2-yl)methanimine —— C21H15NOS
    N-naphthalen-2-yl-1-(5-phenylsulfanylfuran-2-yl)methanimine
    —— 3-Bromo-2,6-dimethyl-8-phenylthiooct-6-en-2-ol —— C16H23BrOS
    3-Bromo-2,6-dimethyl-8-phenylthiooct-6-en-2-ol
    —— 3-Heptene, 7-(ethylthio)- —— C9H18S
    3-Heptene, 7-(ethylthio)-
    —— [(Z)-(2,4-dinitro-6-phenylsulfanylphenyl)methylideneamino]urea —— C14H11N5O5S
    [(Z)-(2,4-dinitro-6-phenylsulfanylphenyl)methylideneamino]urea
    —— 7-Methylene-3a,4,5,6,7,9-hexahydrocycloocta[1,3]dioxole-2-thione —— C10H12O2S
    7-Methylene-3a,4,5,6,7,9-hexahydrocycloocta[1,3]dioxole-2-thione
    —— (2S,4S)-4,6-dimethyl-2-(2-methylpropyl)-4H-1,3,5-dithiazine —— C9H17NS2
    (2S,4S)-4,6-dimethyl-2-(2-methylpropyl)-4H-1,3,5-dithiazine
    —— (2S,4R)-4,6-dimethyl-2-(2-methylpropyl)-4H-1,3,5-dithiazine —— C9H17NS2
    (2S,4R)-4,6-dimethyl-2-(2-methylpropyl)-4H-1,3,5-dithiazine
    —— (2S,4S)-2,4-dimethyl-6-(2-methylpropyl)-4H-1,3,5-dithiazine —— C9H17NS2
    (2S,4S)-2,4-dimethyl-6-(2-methylpropyl)-4H-1,3,5-dithiazine
    —— (2R,4R)-4,6-dimethyl-2-(2-methylpropyl)-4H-1,3,5-dithiazine —— C9H17NS2
    (2R,4R)-4,6-dimethyl-2-(2-methylpropyl)-4H-1,3,5-dithiazine