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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(1-Propylimidazol-2-yl)sulfanylethanol —— C8H14N2OS
    2-(1-Propylimidazol-2-yl)sulfanylethanol
    —— N-[(2R)-1-amino-3-methyl-1-sulfanylidenebutan-2-yl]propanamide —— C8H16N2OS
    N-[(2R)-1-amino-3-methyl-1-sulfanylidenebutan-2-yl]propanamide
    —— N-[(2S)-1-amino-3-methyl-1-sulfanylidenebutan-2-yl]propanamide —— C8H16N2OS
    N-[(2S)-1-amino-3-methyl-1-sulfanylidenebutan-2-yl]propanamide
    —— 2-(1-Prop-2-enylimidazol-2-yl)sulfanylethanol —— C8H12N2OS
    2-(1-Prop-2-enylimidazol-2-yl)sulfanylethanol
    —— N'-(2-furylmethylene)-2-[(4-methylphenyl)thio]acetohydrazide —— C14H14N2O2S
    N'-(2-furylmethylene)-2-[(4-methylphenyl)thio]acetohydrazide
    —— 2-(1-Prop-2-enylimidazol-2-yl)sulfanylethanamine —— C8H13N3S
    2-(1-Prop-2-enylimidazol-2-yl)sulfanylethanamine
    —— (2Z)-2-(1H-benzimidazol-2-yl)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]prop-2-enenitrile —— C21H13N5OS
    (2Z)-2-(1H-benzimidazol-2-yl)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]prop-2-enenitrile
    —— ethyl (2Z)-7-methyl-5-[4-(methylsulfanyl)phenyl]-2-{[5-(morpholin-4-yl)furan-2-yl]methylidene}-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H27N3O5S2
    ethyl (2Z)-7-methyl-5-[4-(methylsulfanyl)phenyl]-2-{[5-(morpholin-4-yl)furan-2-yl]methylidene}-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(2R)-1-amino-3-methyl-1-sulfanylidenebutan-2-yl]acetamide —— C7H14N2OS
    N-[(2R)-1-amino-3-methyl-1-sulfanylidenebutan-2-yl]acetamide
    —— ethyl (2Z)-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2-(thiophen-2-ylmethylidene)-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C22H20N2O3S3
    ethyl (2Z)-7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2-(thiophen-2-ylmethylidene)-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2-(cyclohexylmethylsulfonyl)-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C17H31NO3S
    2-(cyclohexylmethylsulfonyl)-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— 5-[2-(2-chlorophenyl)ethylsulfanyl]-1-[[(2S)-oxolan-2-yl]methyl]tetrazole —— C14H17ClN4OS
    5-[2-(2-chlorophenyl)ethylsulfanyl]-1-[[(2S)-oxolan-2-yl]methyl]tetrazole
    —— N-(2-adamantyl)-N-ethyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C19H26N2O2S
    N-(2-adamantyl)-N-ethyl-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 2-[5-[2-(2-chlorophenyl)ethylsulfanyl]tetrazol-1-yl]-N,N-dimethylethanamine —— C13H18ClN5S
    2-[5-[2-(2-chlorophenyl)ethylsulfanyl]tetrazol-1-yl]-N,N-dimethylethanamine
    —— 1-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-3-(6-ethylsulfanylpyridin-3-yl)urea —— C16H22N4OS2
    1-[(2R)-2-(dimethylamino)-2-thiophen-2-ylethyl]-3-(6-ethylsulfanylpyridin-3-yl)urea
    —— (2S)-N-(2-morpholin-4-ylethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide —— C15H20N2O2S
    (2S)-N-(2-morpholin-4-ylethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[[(2S)-oxolan-2-yl]methyl]urea —— C13H19N3O2S
    1-(6-ethylsulfanylpyridin-3-yl)-3-[[(2S)-oxolan-2-yl]methyl]urea
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(2R)-1-imidazol-1-ylpropan-2-yl]urea —— C14H19N5OS
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(2R)-1-imidazol-1-ylpropan-2-yl]urea
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(1S)-1-phenylethyl]urea —— C16H19N3OS
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(1S)-1-phenylethyl]urea
    —— 1-[(2S)-butan-2-yl]-3-(6-ethylsulfanylpyridin-3-yl)urea —— C12H19N3OS
    1-[(2S)-butan-2-yl]-3-(6-ethylsulfanylpyridin-3-yl)urea
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(2R)-2-morpholin-4-ylpropyl]urea —— C15H24N4O2S
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(2R)-2-morpholin-4-ylpropyl]urea
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(4S)-1-methyl-4,5,6,7-tetrahydroindazol-4-yl]urea —— C16H21N5OS
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(4S)-1-methyl-4,5,6,7-tetrahydroindazol-4-yl]urea
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(1S)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]urea —— C13H18N6OS
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(1S)-1-(4-methyl-1,2,4-triazol-3-yl)ethyl]urea
    —— (2R)-N-(2-morpholin-4-ylethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide —— C15H20N2O2S
    (2R)-N-(2-morpholin-4-ylethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(2R)-1-morpholin-4-ylpropan-2-yl]urea —— C15H24N4O2S
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(2R)-1-morpholin-4-ylpropan-2-yl]urea
    —— 1-(6-ethylsulfanylpyridin-3-yl)-3-[(1S)-1-(1,3,5-trimethylpyrazol-4-yl)ethyl]urea —— C16H23N5OS
    1-(6-ethylsulfanylpyridin-3-yl)-3-[(1S)-1-(1,3,5-trimethylpyrazol-4-yl)ethyl]urea
    —— (Z)-2-(1H-benzimidazol-2-yl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enenitrile —— C20H13N3OS
    (Z)-2-(1H-benzimidazol-2-yl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enenitrile
    —— (Z)-2-cyano-N-(4-methoxyphenyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide —— C21H16N2O3S
    (Z)-2-cyano-N-(4-methoxyphenyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide
    —— N-methyl-3-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropane-1-sulfonamide —— C10H19N5O3S2
    N-methyl-3-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropane-1-sulfonamide
    —— N-methyl-3-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropane-1-sulfonamide —— C10H19N5O3S2
    N-methyl-3-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropane-1-sulfonamide
    —— (Z)-N-benzyl-2-cyano-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide —— C21H16N2O2S
    (Z)-N-benzyl-2-cyano-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide
    —— 3-(3-methylbutylsulfanyl)-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C12H21N3O2S
    3-(3-methylbutylsulfanyl)-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— Ethyl 4-[3-cyano-4-(dimethylamino)pyridin-2-yl]sulfanyl-3-oxobutanoate —— C14H17N3O3S
    Ethyl 4-[3-cyano-4-(dimethylamino)pyridin-2-yl]sulfanyl-3-oxobutanoate
    —— 2-(1-methyltetrazol-5-yl)sulfanyl-N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]acetamide —— C14H14N6OS2
    2-(1-methyltetrazol-5-yl)sulfanyl-N-[(R)-phenyl(1,3-thiazol-2-yl)methyl]acetamide
    —— 2-(1-methyltetrazol-5-yl)sulfanyl-N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]acetamide —— C14H14N6OS2
    2-(1-methyltetrazol-5-yl)sulfanyl-N-[(S)-phenyl(1,3-thiazol-2-yl)methyl]acetamide
    —— 2-[(3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)sulfanyl]-N'-[(1E,2Z)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide —— C15H15N5O3S
    2-[(3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)sulfanyl]-N'-[(1E,2Z)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide
    —— 3-(3-methylbutylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C12H21N3O2S
    3-(3-methylbutylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— N'-benzylidene-2-[(3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)thio]acetohydrazide —— C12H11N5O3S
    N'-benzylidene-2-[(3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)thio]acetohydrazide
    —— (2S)-2-[[5-(methylsulfanylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C10H14N2O2S2
    (2S)-2-[[5-(methylsulfanylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2R)-2-[[5-(methylsulfanylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C10H14N2O2S2
    (2R)-2-[[5-(methylsulfanylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— 2-(1-methylimidazol-2-yl)sulfanyl-N-[2-[(2R)-oxolan-2-yl]ethyl]acetamide —— C12H19N3O2S
    2-(1-methylimidazol-2-yl)sulfanyl-N-[2-[(2R)-oxolan-2-yl]ethyl]acetamide
    —— 2-(1-methylimidazol-2-yl)sulfanyl-N-[2-[(2S)-oxolan-2-yl]ethyl]acetamide —— C12H19N3O2S
    2-(1-methylimidazol-2-yl)sulfanyl-N-[2-[(2S)-oxolan-2-yl]ethyl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide —— C13H17NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide —— C13H17NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide
    —— (3S,5R)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one —— C13H16O2S
    (3S,5R)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one
    —— (3R,5R)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one —— C13H16O2S
    (3R,5R)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(3-nitropyridin-2-yl)sulfanylpropan-1-one —— C16H17N3O4S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(3-nitropyridin-2-yl)sulfanylpropan-1-one
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(3-nitropyridin-2-yl)sulfanylpropan-1-one —— C16H17N3O4S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(3-nitropyridin-2-yl)sulfanylpropan-1-one
    —— (3S,5S)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one —— C13H16O2S
    (3S,5S)-3-(3,4-dimethylphenyl)sulfanyl-5-methyloxolan-2-one
    —— ethyl (2Z)-7-methyl-2-[(5-methylfuran-2-yl)methylidene]-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C23H22N2O4S2
    ethyl (2Z)-7-methyl-2-[(5-methylfuran-2-yl)methylidene]-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate