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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[4-(1-Ethyl-3-methylpyrazol-4-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylacetate —— C13H12F3N4O2S-
    2-[4-(1-Ethyl-3-methylpyrazol-4-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylacetate
    —— 2-{[5-(1,5-Dimethyl-1H-pyrazol-3-YL)-4-ethyl-4H-1,2,4-triazol-3-YL]thio}acetohydrazide —— C11H17N7OS
    2-{[5-(1,5-Dimethyl-1H-pyrazol-3-YL)-4-ethyl-4H-1,2,4-triazol-3-YL]thio}acetohydrazide
    —— 5-({4-[(4-Bromophenyl)sulfanyl]-3-nitrophenyl}methylene)-2-thioxo-1,3-thiazolan-4-one —— C16H9BrN2O3S3
    5-({4-[(4-Bromophenyl)sulfanyl]-3-nitrophenyl}methylene)-2-thioxo-1,3-thiazolan-4-one
    —— 5-({2-[(4-Methylphenyl)sulfanyl]-5-nitrophenyl}methylene)-2-thioxo-1,3-thiazolan-4-one —— C17H12N2O3S3
    5-({2-[(4-Methylphenyl)sulfanyl]-5-nitrophenyl}methylene)-2-thioxo-1,3-thiazolan-4-one
    —— S-[2-[(hydroxymethylsulfanylmethylsulfanylmethylsulfanylcarbonylamino)methylsulfanyl]ethylsulfanylmethyliminomethylsulfinylmethylsulfanylmethyl] N-[2-[(methylsulfanylmethylsulfanylmethylsulfinylmethylideneamino)methylsulfanyl]ethylsulfanylmethyl]carbamothioate —— C20H38N4O5S13
    S-[2-[(hydroxymethylsulfanylmethylsulfanylmethylsulfanylcarbonylamino)methylsulfanyl]ethylsulfanylmethyliminomethylsulfinylmethylsulfanylmethyl] N-[2-[(methylsulfanylmethylsulfanylmethylsulfinylmethylideneamino)methylsulfanyl]ethylsulfanylmethyl]carbamothioate
    —— 2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate —— C6H6N3O3S-
    2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetate
    —— [3-[3-[Butylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C29H34N2O3S
    [3-[3-[Butylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— (4R)-1-(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-3-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione —— C18H19N3O2S3
    (4R)-1-(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-3-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione
    —— prop-2-enyl (6R)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate —— C19H20N2O3S2
    prop-2-enyl (6R)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate
    —— 2-methoxyethyl (6R)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate —— C19H22N2O4S2
    2-methoxyethyl (6R)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate
    —— prop-2-enyl (6S)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate —— C19H20N2O3S2
    prop-2-enyl (6S)-8-methyl-6-(4-methylsulfanylphenyl)-4-oxo-3,6-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-7-carboxylate
    —— 5-cycloprop-2-en-1-ylidene-N-(2-phenylsulfanylphenyl)-7-(trifluoromethyl)-1H-pyrazolo[1,5-a]pyrimidine-3-carboxamide —— C23H15F3N4OS
    5-cycloprop-2-en-1-ylidene-N-(2-phenylsulfanylphenyl)-7-(trifluoromethyl)-1H-pyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— (2R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-3-ethoxypropan-2-ol —— C11H18N2O2S
    (2R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-3-ethoxypropan-2-ol
    —— 3-(Dideuteriomethylsulfonylmethyl)-2,2,4,4-tetramethylpentane —— C11H24O2S
    3-(Dideuteriomethylsulfonylmethyl)-2,2,4,4-tetramethylpentane
    —— 5-ethyl-4-hydroxy-3-phenyl-2-propylsulfanyl-1H-pyrimidin-3-ium-6-one —— C15H19N2O2S+
    5-ethyl-4-hydroxy-3-phenyl-2-propylsulfanyl-1H-pyrimidin-3-ium-6-one
    —— (4S)-1-(5-prop-2-enylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-2-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione —— C18H17N3O2S3
    (4S)-1-(5-prop-2-enylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-2-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione
    —— (4R)-1-(5-prop-2-enylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-2-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione —— C18H17N3O2S3
    (4R)-1-(5-prop-2-enylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-2-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione
    —— (4S)-1-(5-prop-2-enylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-3-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione —— C18H17N3O2S3
    (4S)-1-(5-prop-2-enylsulfanyl-1,3,4-thiadiazol-2-yl)-4-thiophen-3-yl-4,6,7,8-tetrahydro-3H-quinoline-2,5-dione
    —— 2-(4-chlorophenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)acetamide —— C15H22ClN2O2S+
    2-(4-chlorophenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N'-(1-thiophen-2-ylethenyl)triazole-4-carbohydrazide —— C18H16N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N'-(1-thiophen-2-ylethenyl)triazole-4-carbohydrazide
    —— (2R)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide —— C6H11N5OS
    (2R)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]butanamide
    —— (2R)-2-bromo-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]butanamide —— C13H18BrNOS
    (2R)-2-bromo-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]butanamide
    —— (1R)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol —— C10H12N2OS3
    (1R)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol
    —— (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)-N-prop-2-enylpropanamide —— C17H22N4OS
    (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)-N-prop-2-enylpropanamide
    —— (2R)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide —— C16H24N6OS
    (2R)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide
    —— (1R)-3-pyrimidin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol —— C11H12N2OS2
    (1R)-3-pyrimidin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol
    —— 4-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C11H16N4OS2
    4-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— 2-(Ethylamino)-6-{[(4-methylphenyl)thio]methyl}pyrimidin-4-ol —— C14H17N3OS
    2-(Ethylamino)-6-{[(4-methylphenyl)thio]methyl}pyrimidin-4-ol
    —— (2S)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C18H24N4OS
    (2S)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (2R)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C18H24N4OS
    (2R)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— 2-Methylsulfonylethylazanium —— C3H10NO2S+
    2-Methylsulfonylethylazanium
    —— (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide —— C16H24N6OS
    (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide —— C15H21NO3S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide —— C15H21NO3S2
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H25N5OS
    (2S)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-(1-ethyl-4-oxopyrimidin-2-yl)sulfanyl-N-[(1S)-1-phenylethyl]acetamide —— C16H19N3O2S
    2-(1-ethyl-4-oxopyrimidin-2-yl)sulfanyl-N-[(1S)-1-phenylethyl]acetamide
    —— N-[(2R)-2-cyanopropyl]-2-(3,4-difluorophenyl)sulfanyl-N-ethylacetamide —— C14H16F2N2OS
    N-[(2R)-2-cyanopropyl]-2-(3,4-difluorophenyl)sulfanyl-N-ethylacetamide
    —— (2R)-N-[(3-hydroxyphenyl)methyl]-N-methyl-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H17NO3S
    (2R)-N-[(3-hydroxyphenyl)methyl]-N-methyl-2,3-dihydro-1,4-benzoxathiine-2-carboxamide
    —— (2R)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2R)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— 2-(1-ethyl-4-oxopyrimidin-2-yl)sulfanyl-N-[(1R)-1-phenylethyl]acetamide —— C16H19N3O2S
    2-(1-ethyl-4-oxopyrimidin-2-yl)sulfanyl-N-[(1R)-1-phenylethyl]acetamide
    —— (2R)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H25N5OS
    (2R)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H25N5OS
    (2R)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(2S)-2-cyanopropyl]-2-(3,4-difluorophenyl)sulfanyl-N-ethylacetamide —— C14H16F2N2OS
    N-[(2S)-2-cyanopropyl]-2-(3,4-difluorophenyl)sulfanyl-N-ethylacetamide
    —— (2S)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2S)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide —— C15H21NO3S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide
    —— 3-Methylsulfonylsulfanylpropylazanium —— C4H12NO2S2+
    3-Methylsulfonylsulfanylpropylazanium
    —— N-[(2R)-2-cyanopropyl]-N-ethyl-3-phenylsulfanylpropanamide —— C15H20N2OS
    N-[(2R)-2-cyanopropyl]-N-ethyl-3-phenylsulfanylpropanamide
    —— N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-3-(1-methyltetrazol-5-yl)sulfanylpropanamide —— C16H24N6OS
    N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-3-(1-methyltetrazol-5-yl)sulfanylpropanamide
    —— N-[(Z)-benzylideneamino]-2-[2-[2-(2-benzylidenehydrazinyl)-2-oxoethyl]sulfanyl-6-methylpyrimidin-4-yl]oxyacetamide —— C23H22N6O3S
    N-[(Z)-benzylideneamino]-2-[2-[2-(2-benzylidenehydrazinyl)-2-oxoethyl]sulfanyl-6-methylpyrimidin-4-yl]oxyacetamide
    —— 2-[2-(4-Methylpiperazin-4-ium-1-yl)-2-oxoethyl]sulfanyl-6-thiophen-2-ylpyridine-3-carbonitrile —— C17H19N4OS2+
    2-[2-(4-Methylpiperazin-4-ium-1-yl)-2-oxoethyl]sulfanyl-6-thiophen-2-ylpyridine-3-carbonitrile