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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide —— C17H15ClN4OS4
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]acetamide —— C20H20ClN5OS3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]acetamide
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide —— C22H25N5OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide
    —— Tributyl-[8-ethoxy-8-oxo-5,5-bis(phenylsulfanyl)octyl]phosphanium —— C34H54O2PS2+
    Tributyl-[8-ethoxy-8-oxo-5,5-bis(phenylsulfanyl)octyl]phosphanium
    —— N-[(Z)-(2-bromophenyl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H17BrN4OS3
    N-[(Z)-(2-bromophenyl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(Z)-[5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]methylideneamino]-2-hydroxybenzamide —— C21H17N3O4S2
    N-[(Z)-[5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]methylideneamino]-2-hydroxybenzamide
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(5-methylthiophen-2-yl)methylideneamino]acetamide —— C18H18N4OS4
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(5-methylthiophen-2-yl)methylideneamino]acetamide
    —— 3-[(Z)-[[2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-4-ium-2-yl]sulfanyl]acetyl]hydrazinylidene]methyl]phenolate —— C18H15ClN4O2S3
    3-[(Z)-[[2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-4-ium-2-yl]sulfanyl]acetyl]hydrazinylidene]methyl]phenolate
    —— (2Z,5E)-5-[1-(4-chloro-2-methylphenyl)sulfanylbut-2-ynylidene]-3-ethyl-2-(1,3-thiazol-2-ylmethylidene)-1,3-thiazolidin-4-one —— C20H17ClN2OS3
    (2Z,5E)-5-[1-(4-chloro-2-methylphenyl)sulfanylbut-2-ynylidene]-3-ethyl-2-(1,3-thiazol-2-ylmethylidene)-1,3-thiazolidin-4-one
    —— N-[(Z)-(5-bromothiophen-2-yl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H15BrN4OS4
    N-[(Z)-(5-bromothiophen-2-yl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-[(Z)-(4-bromophenyl)methylidene]-2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C18H14BrClN4OS3
    N'-[(Z)-(4-bromophenyl)methylidene]-2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— [(2-bromo-4,5-difluorophenyl)thio]acetonitrile —— C8H4BrF2NS
    [(2-bromo-4,5-difluorophenyl)thio]acetonitrile
    —— C18H13Cl2FN4OS3 —— C18H13Cl2FN4OS3
    C18H13Cl2FN4OS3
    —— 3-(Aminodiazenyl)propane-1-thiol —— C3H9N3S
    3-(Aminodiazenyl)propane-1-thiol
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide —— C16H13ClN4O2S3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide
    —— N-[(Z)-[(E)-3-(furan-2-yl)prop-2-enylidene]amino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H18N4O2S3
    N-[(Z)-[(E)-3-(furan-2-yl)prop-2-enylidene]amino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide —— C18H17N5OS3
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide
    —— N,N'-difluoroethanedithioamide —— C2H2F2N2S2
    N,N'-difluoroethanedithioamide
    —— (4R,8Z)-2-amino-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-6-propyl-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile —— C27H29N3OS2
    (4R,8Z)-2-amino-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-6-propyl-5,7-dihydro-4H-pyrano[3,2-c]pyridine-3-carbonitrile
    —— 2,3,5,6-Tetrafluoro-4-(2,3,5,6-tetrafluoro-4-sulfanylphenyl)sulfanylbenzenethiol —— C12H2F8S3
    2,3,5,6-Tetrafluoro-4-(2,3,5,6-tetrafluoro-4-sulfanylphenyl)sulfanylbenzenethiol
    —— N,N,N',N'-tetrachloroethanedithioamide —— C2Cl4N2S2
    N,N,N',N'-tetrachloroethanedithioamide
    —— N-[(Z)-1-aminoprop-1-en-2-yl]ethanethioamide —— C5H10N2S
    N-[(Z)-1-aminoprop-1-en-2-yl]ethanethioamide
    —— N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H14Cl2N4OS3
    N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 4-[3-[2-(1-Adamantyl)propan-2-yloxy]-3-oxopropyl]sulfanylbenzenesulfinic acid —— C22H30O4S2
    4-[3-[2-(1-Adamantyl)propan-2-yloxy]-3-oxopropyl]sulfanylbenzenesulfinic acid
    —— 1,1-Bis(trifluoromethylsulfonyl)pentan-3-yl 2-(trifluoromethyl)prop-2-enoate —— C11H11F9O6S2
    1,1-Bis(trifluoromethylsulfonyl)pentan-3-yl 2-(trifluoromethyl)prop-2-enoate
    —— [4-Methyl-1,1-bis(trifluoromethylsulfonyl)pentan-3-yl] 2-(trifluoromethyl)prop-2-enoate —— C12H13F9O6S2
    [4-Methyl-1,1-bis(trifluoromethylsulfonyl)pentan-3-yl] 2-(trifluoromethyl)prop-2-enoate
    —— [2-Methyl-6,6-bis(trifluoromethylsulfonyl)hexan-3-yl] 2-(trifluoromethyl)prop-2-enoate —— C13H15F9O6S2
    [2-Methyl-6,6-bis(trifluoromethylsulfonyl)hexan-3-yl] 2-(trifluoromethyl)prop-2-enoate
    —— (NE,S)-N-[(3-chloro-5-methylsulfanylpyrazin-2-yl)methylidene]-2-methylpropane-2-sulfinamide —— C10H14ClN3OS2
    (NE,S)-N-[(3-chloro-5-methylsulfanylpyrazin-2-yl)methylidene]-2-methylpropane-2-sulfinamide
    —— (2S)-2-(3-chloro-5-methylsulfanylpyrazin-2-yl)-2-(3,5-difluorophenyl)ethanamine —— C13H12ClF2N3S
    (2S)-2-(3-chloro-5-methylsulfanylpyrazin-2-yl)-2-(3,5-difluorophenyl)ethanamine
    —— 5-cycloprop-2-en-1-ylidene-7-(difluoromethyl)-N-(2-phenylsulfanylphenyl)-1H-pyrazolo[1,5-a]pyrimidine-3-carboxamide —— C23H16F2N4OS
    5-cycloprop-2-en-1-ylidene-7-(difluoromethyl)-N-(2-phenylsulfanylphenyl)-1H-pyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide —— C18H17N5OS3
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide
    —— 1-Methylsulfanylcarbonyloxyethyl 4-(aminomethyl)cyclohexane-1-carboxylate —— C12H21NO4S
    1-Methylsulfanylcarbonyloxyethyl 4-(aminomethyl)cyclohexane-1-carboxylate
    —— N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H18N6O2S
    N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-2-[(5-pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-(1,1,2,2-Tetrafluoropropylsulfanyl)phenol —— C9H8F4OS
    2-(1,1,2,2-Tetrafluoropropylsulfanyl)phenol
    —— 5-[(4-chlorophenyl)sulfanylmethyl]-4-(diaminomethylidene)-2-phenylpyrazol-3-one —— C17H15ClN4OS
    5-[(4-chlorophenyl)sulfanylmethyl]-4-(diaminomethylidene)-2-phenylpyrazol-3-one
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(2-methylphenyl)methylideneamino]acetamide —— C19H17ClN4OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(2-methylphenyl)methylideneamino]acetamide
    —— 6-Methyl-1lambda6-thia-6-azaspiro[3.3]heptane 1,1-dioxide —— C6H11NO2S
    6-Methyl-1lambda6-thia-6-azaspiro[3.3]heptane 1,1-dioxide
    —— 1,3-Dichloro-5-thionitroso-2-[2-(trifluoromethyl)phenyl]sulfanylbenzene —— C13H6Cl2F3NS2
    1,3-Dichloro-5-thionitroso-2-[2-(trifluoromethyl)phenyl]sulfanylbenzene
    —— 6-Methyl-2-(2-methylsulfonylethyl)-2-azaspiro[3.3]heptane —— C10H19NO2S
    6-Methyl-2-(2-methylsulfonylethyl)-2-azaspiro[3.3]heptane
    —— 1,3-Dichloro-5-methyl-2-[4-(trifluoromethyl)phenyl]sulfanylbenzene —— C14H9Cl2F3S
    1,3-Dichloro-5-methyl-2-[4-(trifluoromethyl)phenyl]sulfanylbenzene
    —— 1,3-Dichloro-2-(4-methoxyphenyl)sulfanyl-5-methylbenzene —— C14H12Cl2OS
    1,3-Dichloro-2-(4-methoxyphenyl)sulfanyl-5-methylbenzene
    —— N-[(Z)-[2-(4-chlorophenyl)sulfanyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylideneamino]-4-methylbenzenesulfonamide —— C22H17ClN4O3S2
    N-[(Z)-[2-(4-chlorophenyl)sulfanyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylideneamino]-4-methylbenzenesulfonamide
    —— (2Z)-2-[(3-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    (2Z)-2-[(3-methylanilino)methylidene]-1-benzothiophen-3-one
    —— 1-(3-Methylsulfonylpropylsulfonimidoyl)propan-2-ol —— C7H17NO4S2
    1-(3-Methylsulfonylpropylsulfonimidoyl)propan-2-ol
    —— (2Z)-2-[(2-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    (2Z)-2-[(2-methylanilino)methylidene]-1-benzothiophen-3-one
    —— ethyl (5S)-5-methyl-1-phenylsulfanylcyclohex-3-ene-1-carboxylate —— C16H20O2S
    ethyl (5S)-5-methyl-1-phenylsulfanylcyclohex-3-ene-1-carboxylate
    —— (2Z)-2-[(3,4-dimethylanilino)methylidene]-1-benzothiophen-3-one —— C17H15NOS
    (2Z)-2-[(3,4-dimethylanilino)methylidene]-1-benzothiophen-3-one
    —— 1-phenyl-3-[(2-pyridin-3-yl-1H-imidazol-5-yl)sulfanyl]propan-2-one —— C17H15N3OS
    1-phenyl-3-[(2-pyridin-3-yl-1H-imidazol-5-yl)sulfanyl]propan-2-one
    —— (2Z)-2-[(4-bromoanilino)methylidene]-1-benzothiophene-3-thione —— C15H10BrNS2
    (2Z)-2-[(4-bromoanilino)methylidene]-1-benzothiophene-3-thione
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-methylphenyl)methylideneamino]acetamide —— C19H18N4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-methylphenyl)methylideneamino]acetamide