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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Chloro-3-[(3,5-difluorophenyl)sulfanylmethyl]benzene —— C13H9ClF2S
    1-Chloro-3-[(3,5-difluorophenyl)sulfanylmethyl]benzene
    —— Magnesium;pentylsulfanylbenzene;bromide —— C11H15BrMgS
    Magnesium;pentylsulfanylbenzene;bromide
    —— 1-Allylsulfanyl-4-chloro-3-methylbenzene —— C10H11ClS
    1-Allylsulfanyl-4-chloro-3-methylbenzene
    —— 2-(4-((Trifluoromethyl)thio)phenyl)ethane-1-thiol —— C9H9F3S2
    2-(4-((Trifluoromethyl)thio)phenyl)ethane-1-thiol
    —— 1-Fluoro-2-[(3-chloro-4-fluorophenyl)sulfanylmethyl]benzene —— C13H9ClF2S
    1-Fluoro-2-[(3-chloro-4-fluorophenyl)sulfanylmethyl]benzene
    —— magnesium;hexylsulfanylbenzene;bromide —— C12H17BrMgS
    magnesium;hexylsulfanylbenzene;bromide
    —— Magnesium;pentylsulfanylbenzene;bromide —— C11H15BrMgS
    Magnesium;pentylsulfanylbenzene;bromide
    —— 1-Allylsulfanyl-3-methylsulfanylbenzene —— C10H12S2
    1-Allylsulfanyl-3-methylsulfanylbenzene
    —— Magnesium;cyclopentylsulfanylbenzene;bromide —— C11H13BrMgS
    Magnesium;cyclopentylsulfanylbenzene;bromide
    —— Magnesium;heptylsulfanylbenzene;bromide —— C13H19BrMgS
    Magnesium;heptylsulfanylbenzene;bromide
    —— 1,4-Difluoro-2-[(3,4-difluorophenyl)sulfanylmethyl]benzene —— C13H8F4S
    1,4-Difluoro-2-[(3,4-difluorophenyl)sulfanylmethyl]benzene
    —— 1-Chloro-3-fluoro-2-[(3-chloro-5-fluorophenyl)sulfanylmethyl]benzene —— C13H8Cl2F2S
    1-Chloro-3-fluoro-2-[(3-chloro-5-fluorophenyl)sulfanylmethyl]benzene
    —— 4-Ethylthiophenyl-(3-thienyl)methanol —— C13H14OS2
    4-Ethylthiophenyl-(3-thienyl)methanol
    —— (4-(Trifluoromethylthio)phenyl)magnesium bromide —— C7H4BrF3MgS
    (4-(Trifluoromethylthio)phenyl)magnesium bromide
    —— (E)-3-[5-(3-chloro-4-methylphenyl)furan-2-yl]-N-[(3-methyl-5-methylsulfanyl-1,2,4-triazol-4-yl)carbamothioyl]prop-2-enamide —— C19H18ClN5O2S2
    (E)-3-[5-(3-chloro-4-methylphenyl)furan-2-yl]-N-[(3-methyl-5-methylsulfanyl-1,2,4-triazol-4-yl)carbamothioyl]prop-2-enamide
    —— 1-Allylsulfanyl-4-fluoro-3-methylbenzene —— C10H11FS
    1-Allylsulfanyl-4-fluoro-3-methylbenzene
    —— 1-Chloro-4-[(3-chloro-4-fluorophenyl)sulfanylmethyl]benzene —— C13H9Cl2FS
    1-Chloro-4-[(3-chloro-4-fluorophenyl)sulfanylmethyl]benzene
    —— N-[(1E,3Z)-4-bromo-3,4-dichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]aniline —— C16H11BrCl2N2O2S
    N-[(1E,3Z)-4-bromo-3,4-dichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]aniline
    —— 2,3,3-Trifluoro-2-(trifluoromethyl)thietane 1,1-dioxide —— C4H2F6O2S
    2,3,3-Trifluoro-2-(trifluoromethyl)thietane 1,1-dioxide
    —— 4-[4-(3-Bromophenyl)sulfanylbutyl]morpholine —— C14H20BrNOS
    4-[4-(3-Bromophenyl)sulfanylbutyl]morpholine
    —— 3-[(3,4-dimethoxypyridin-2-yl)methylsulfanyl]-4-methyl-1H-1,2,4-triazol-5-one —— C11H14N4O3S
    3-[(3,4-dimethoxypyridin-2-yl)methylsulfanyl]-4-methyl-1H-1,2,4-triazol-5-one
    —— ethyl 4-[[5-(hydroxymethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butanoate —— C9H15N3O3S
    ethyl 4-[[5-(hydroxymethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butanoate
    —— N-[4-(2-chlorophenyl)sulfanylphenyl]-3-(1H-imidazol-5-yl)propanamide —— C18H16ClN3OS
    N-[4-(2-chlorophenyl)sulfanylphenyl]-3-(1H-imidazol-5-yl)propanamide
    —— 1-[(Z)-(4-oxo-2-pyridin-2-ylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylideneamino]-3-prop-2-enylthiourea —— C18H16N6OS2
    1-[(Z)-(4-oxo-2-pyridin-2-ylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylideneamino]-3-prop-2-enylthiourea
    —— 4-(4,4-Dimethylcyclohexyl)sulfinylbutanenitrile —— C12H21NOS
    4-(4,4-Dimethylcyclohexyl)sulfinylbutanenitrile
    —— 5-[(3-bromopyridin-2-yl)sulfanylmethyl]-3-(1H-1,2,4-triazol-5-yl)-1,2,4-oxadiazole —— C10H7BrN6OS
    5-[(3-bromopyridin-2-yl)sulfanylmethyl]-3-(1H-1,2,4-triazol-5-yl)-1,2,4-oxadiazole
    —— 2-[(3-ethyl-1H-1,2,4-triazol-5-yl)methylsulfanyl]pyrazine —— C9H11N5S
    2-[(3-ethyl-1H-1,2,4-triazol-5-yl)methylsulfanyl]pyrazine
    —— 3-[(2-Methylfuran-3-yl)sulfanylmethyl]-5-propyl-1,2,4-oxadiazole —— C11H14N2O2S
    3-[(2-Methylfuran-3-yl)sulfanylmethyl]-5-propyl-1,2,4-oxadiazole
    —— 1-[(4-Propan-2-ylsulfanylphenyl)methyl]triazole —— C12H15N3S
    1-[(4-Propan-2-ylsulfanylphenyl)methyl]triazole
    —— 3-(2-Chlorophenyl)-5-{[5-nitro-2-(phenylsulfanyl)phenyl]methylene}-2-thioxo-1,3-thiazolan-4-one —— C22H13ClN2O3S3
    3-(2-Chlorophenyl)-5-{[5-nitro-2-(phenylsulfanyl)phenyl]methylene}-2-thioxo-1,3-thiazolan-4-one
    —— 5-(2-Imidazol-1-ylethylsulfanyl)-1-methyl-1,2,4-triazole —— C8H11N5S
    5-(2-Imidazol-1-ylethylsulfanyl)-1-methyl-1,2,4-triazole
    —— N-[cyclohexyl(cyclopropyl)methyl]-1-methylsulfonylpropan-2-amine —— C14H27NO2S
    N-[cyclohexyl(cyclopropyl)methyl]-1-methylsulfonylpropan-2-amine
    —— 1-(Dimethylamino)-2-methyl-3-[(6-methylsulfanylpyrazin-2-yl)amino]propan-2-ol —— C11H20N4OS
    1-(Dimethylamino)-2-methyl-3-[(6-methylsulfanylpyrazin-2-yl)amino]propan-2-ol
    —— N-(2-benzamidoethyl)-2-(4-chlorophenyl)sulfanyl-6-fluorobenzamide —— C22H18ClFN2O2S
    N-(2-benzamidoethyl)-2-(4-chlorophenyl)sulfanyl-6-fluorobenzamide
    —— 2-(2-benzylsulfanyl-6-methylpyrimidin-4-yl)oxy-N-[(Z)-(3-bromophenyl)methylideneamino]acetamide —— C21H19BrN4O2S
    2-(2-benzylsulfanyl-6-methylpyrimidin-4-yl)oxy-N-[(Z)-(3-bromophenyl)methylideneamino]acetamide
    —— N-[cyclohexyl(cyclopropyl)methyl]-2-methylsulfinylpropan-1-amine —— C14H27NOS
    N-[cyclohexyl(cyclopropyl)methyl]-2-methylsulfinylpropan-1-amine
    —— 1,1-Dioxo-1lambda6-thiolan-3-yl 3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanoate —— C14H20N2O4S2
    1,1-Dioxo-1lambda6-thiolan-3-yl 3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanoate
    —— N-[(5-methyl-1,3-oxazol-2-yl)methyl]-2-methylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-amine —— C11H11N5OS2
    N-[(5-methyl-1,3-oxazol-2-yl)methyl]-2-methylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-amine
    —— 2,4-Dimethyl-6-[(5-oxo-1,4-dihydro-1,2,4-triazol-3-yl)methylsulfanyl]pyrimidine-5-carbonitrile —— C10H10N6OS
    2,4-Dimethyl-6-[(5-oxo-1,4-dihydro-1,2,4-triazol-3-yl)methylsulfanyl]pyrimidine-5-carbonitrile
    —— S-[3-[(4-methyl-1,2,4-triazol-3-yl)methylsulfanylmethyl]phenyl] N,N-dimethylcarbamothioate —— C14H18N4OS2
    S-[3-[(4-methyl-1,2,4-triazol-3-yl)methylsulfanylmethyl]phenyl] N,N-dimethylcarbamothioate
    —— 6-(3,4-Dimethoxyphenyl)sulfanyl-7,8-dimethyl-3-(trifluoromethyl)-[1,2,4]triazolo[4,3-b]pyridazine —— C16H15F3N4O2S
    6-(3,4-Dimethoxyphenyl)sulfanyl-7,8-dimethyl-3-(trifluoromethyl)-[1,2,4]triazolo[4,3-b]pyridazine
    —— 2-[6-(3,5-Dimethylpyrazol-1-yl)pyrazin-2-yl]sulfanyl-1,3-thiazole —— C12H11N5S2
    2-[6-(3,5-Dimethylpyrazol-1-yl)pyrazin-2-yl]sulfanyl-1,3-thiazole
    —— 6-Chloro-2-methyl-3-[[5-methyl-4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine —— C16H17ClN4S2
    6-Chloro-2-methyl-3-[[5-methyl-4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine
    —— 2-Ethyl-4-(1-propan-2-yltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidine —— C12H14N6S2
    2-Ethyl-4-(1-propan-2-yltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidine
    —— 1-(2,5-dimethylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C22H25N3S
    1-(2,5-dimethylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— 2-(2,6-Difluoro-4-nitrophenyl)sulfanyl-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole —— C13H12F2N4O3S
    2-(2,6-Difluoro-4-nitrophenyl)sulfanyl-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole
    —— 4-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]oxan-4-ol —— C15H19N3O2S2
    4-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]oxan-4-ol
    —— 5-Tert-butyl-2-(2-pyrazol-1-ylethylsulfanyl)-1,3-oxazole —— C12H17N3OS
    5-Tert-butyl-2-(2-pyrazol-1-ylethylsulfanyl)-1,3-oxazole
    —— 2-Ethyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C10H14N4O2S
    2-Ethyl-5-[(5-propyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 3-[(5-ethyl-1H-imidazol-2-yl)sulfanylmethyl]-5-[(2-methylphenyl)methyl]-1,2,4-oxadiazole —— C16H18N4OS
    3-[(5-ethyl-1H-imidazol-2-yl)sulfanylmethyl]-5-[(2-methylphenyl)methyl]-1,2,4-oxadiazole