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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]-N-[1-(3-pyridin-4-yl-1,2,4-oxadiazol-5-yl)ethyl]acetamide —— C14H14N6O2S2
    2-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]-N-[1-(3-pyridin-4-yl-1,2,4-oxadiazol-5-yl)ethyl]acetamide
    —— (2Z)-2-cyano-2-[(5E)-3-(3-methoxypropyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-N-(2-morpholin-4-ylethyl)acetamide —— C24H30N4O4S2
    (2Z)-2-cyano-2-[(5E)-3-(3-methoxypropyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-N-(2-morpholin-4-ylethyl)acetamide
    —— N-({5-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]-2-furyl}methyl)-N-(tetrahydrofuran-2-ylmethyl)ethanamine —— C15H22N4O2S
    N-({5-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]-2-furyl}methyl)-N-(tetrahydrofuran-2-ylmethyl)ethanamine
    —— 1-(5-{[2-(ethylthio)pyrimidin-5-yl]methyl}-5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-yl)ethanol —— C16H23N5OS
    1-(5-{[2-(ethylthio)pyrimidin-5-yl]methyl}-5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-yl)ethanol
    —— N-[(5-ethyl-1,3,4-oxadiazol-2-yl)methyl]-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide —— C12H16N4O2S2
    N-[(5-ethyl-1,3,4-oxadiazol-2-yl)methyl]-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide
    —— N-[(4,6-dimethylpyridin-3-yl)methyl]-2-(pyridin-2-ylthio)acetamide —— C15H17N3OS
    N-[(4,6-dimethylpyridin-3-yl)methyl]-2-(pyridin-2-ylthio)acetamide
    —— N-(1-ethylpyrrolidin-3-yl)-2-[(2-methylphenyl)thio]acetamide —— C15H22N2OS
    N-(1-ethylpyrrolidin-3-yl)-2-[(2-methylphenyl)thio]acetamide
    —— 2-cyclopent-2-en-1-yl-N-{2-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]ethyl}acetamide —— C12H17N3OS2
    2-cyclopent-2-en-1-yl-N-{2-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]ethyl}acetamide
    —— cyclopropyl(5-{[(4-methyl-4H-1,2,4-triazol-3-yl)thio]acetyl}-5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-yl)methanol —— C16H22N6O2S
    cyclopropyl(5-{[(4-methyl-4H-1,2,4-triazol-3-yl)thio]acetyl}-5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-yl)methanol
    —— 3-(4-fluorophenyl)-2-[(E)-2-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]ethenyl]quinazolin-4-one —— C26H18FN5O3S
    3-(4-fluorophenyl)-2-[(E)-2-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]ethenyl]quinazolin-4-one
    —— diethyl 2-[amino-[(2E)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]methylidene]propanedioate —— C16H21N3O4S
    diethyl 2-[amino-[(2E)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]methylidene]propanedioate
    —— N-[rac-(1R,5R,6S,7R)-6-amino-2-oxabicyclo[3.2.0]hept-7-yl]-2-(phenylthio)acetamide —— C14H18N2O2S
    N-[rac-(1R,5R,6S,7R)-6-amino-2-oxabicyclo[3.2.0]hept-7-yl]-2-(phenylthio)acetamide
    —— 4-morpholin-4-yl-N-[2-(1H-1,2,4-triazol-5-ylthio)ethyl]pentanamide —— C13H23N5O2S
    4-morpholin-4-yl-N-[2-(1H-1,2,4-triazol-5-ylthio)ethyl]pentanamide
    —— 2-[(4-methylphenyl)thio]-N-[2-(1-methyl-1H-1,2,4-triazol-5-yl)ethyl]propanamide —— C15H20N4OS
    2-[(4-methylphenyl)thio]-N-[2-(1-methyl-1H-1,2,4-triazol-5-yl)ethyl]propanamide
    —— N-{[1-(2-fluorophenyl)cyclopentyl]methyl}-2-(pyrimidin-2-ylthio)acetamide —— C18H20FN3OS
    N-{[1-(2-fluorophenyl)cyclopentyl]methyl}-2-(pyrimidin-2-ylthio)acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(3S,4S)-3-ethoxy-4-hydroxypyrrolidin-1-yl]ethanone —— C10H16N4O3S2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(3S,4S)-3-ethoxy-4-hydroxypyrrolidin-1-yl]ethanone
    —— 2-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]-N-[3-(1H-1,2,3-triazol-1-yl)propyl]acetamide —— C10H15N7OS
    2-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]-N-[3-(1H-1,2,3-triazol-1-yl)propyl]acetamide
    —— 2-(pyrimidin-2-ylthio)-N-[3-(1H-1,2,4-triazol-1-yl)propyl]acetamide —— C11H14N6OS
    2-(pyrimidin-2-ylthio)-N-[3-(1H-1,2,4-triazol-1-yl)propyl]acetamide
    —— 6-(trans-3-aminocyclobutyl)-2-cyclopropyl-N-[2-(1H-1,2,3-triazol-5-ylthio)ethyl]pyrimidin-4-amine —— C15H21N7S
    6-(trans-3-aminocyclobutyl)-2-cyclopropyl-N-[2-(1H-1,2,3-triazol-5-ylthio)ethyl]pyrimidin-4-amine
    —— 2-(4-chloro-1H-pyrazol-1-yl)-N-[2-(1H-1,2,3-triazol-5-ylthio)ethyl]propanamide —— C10H13ClN6OS
    2-(4-chloro-1H-pyrazol-1-yl)-N-[2-(1H-1,2,3-triazol-5-ylthio)ethyl]propanamide
    —— tert-Butyl ((2-(methylthio)pyrimidin-4-yl)methyl)carbamate —— C11H17N3O2S
    tert-Butyl ((2-(methylthio)pyrimidin-4-yl)methyl)carbamate
    —— (4E)-4-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1-phenylpyrazolidine-3,5-dione —— C23H17N3O4S
    (4E)-4-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1-phenylpyrazolidine-3,5-dione
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]octanamide —— C16H24N2OS
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]octanamide
    —— 3-[(3-chloropropyl)sulfanyl]-5-(furan-3-yl)-4-methyl-4H-1,2,4-triazole —— C10H12ClN3OS
    3-[(3-chloropropyl)sulfanyl]-5-(furan-3-yl)-4-methyl-4H-1,2,4-triazole
    —— 5-[2-[(E)-[3-(4-chlorophenyl)pyrazol-4-ylidene]methyl]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile —— C15H11ClN6S2
    5-[2-[(E)-[3-(4-chlorophenyl)pyrazol-4-ylidene]methyl]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile
    —— Propargyl-PEG1-SS-PEG1-acid —— C10H16O4S2
    Propargyl-PEG1-SS-PEG1-acid
    —— lithium thioethoxide —— C2H2OS*Li
    lithium thioethoxide
    —— 2,4,4-Trimethylcyclopentane-1-thione —— C8H14S
    2,4,4-Trimethylcyclopentane-1-thione
    —— 3-methyl-2-((Z)-pent-2-enyl)cyclopent-2-enethione —— C11H16S
    3-methyl-2-((Z)-pent-2-enyl)cyclopent-2-enethione
    —— 2-Propylsulfonylethanimidamide —— C5H12N2O2S
    2-Propylsulfonylethanimidamide
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1E)-1-(furan-2-yl)ethylidene]acetohydrazide —— C17H16N4O2S3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1E)-1-(furan-2-yl)ethylidene]acetohydrazide
    —— (NZ)-N-[(4Z)-8-(4-chlorophenyl)sulfanylcyclooct-4-en-1-ylidene]hydroxylamine —— C14H16ClNOS
    (NZ)-N-[(4Z)-8-(4-chlorophenyl)sulfanylcyclooct-4-en-1-ylidene]hydroxylamine
    —— (E)-[(2-fluorophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide —— C9H7FN2S2
    (E)-[(2-fluorophenyl)sulfanyl-methylsulfanylmethylidene]cyanamide
    —— N-{1-acetyl-2-[(4-ethoxyphenyl)sulfanyl]-1H-indol-3-yl}acetamide —— C20H20N2O3S
    N-{1-acetyl-2-[(4-ethoxyphenyl)sulfanyl]-1H-indol-3-yl}acetamide
    —— Bis-(2-methyl-5-tert.-butyl-4-trimethylsilyloxy)-diphenylthioether 73039-28-8 C28H46O2SSi2
    Bis-(2-methyl-5-tert.-butyl-4-trimethylsilyloxy)-diphenylthioether
    —— 1,2,3,4,6,7-Hexathiocane —— C2H4S6
    1,2,3,4,6,7-Hexathiocane
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-5-fluoro-4-morpholin-4-ylpyrimidin-2-amine —— C21H18ClFN6O3S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-5-fluoro-4-morpholin-4-ylpyrimidin-2-amine
    —— Dimethyl 1,2,3-trithio-4-selenide —— C2H6S3Se
    Dimethyl 1,2,3-trithio-4-selenide
    —— Dimethyl 2,3-dithio-1,4-diselenide —— C2H6S2Se2
    Dimethyl 2,3-dithio-1,4-diselenide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-1-pyridin-4-ylethylideneamino]acetamide —— C17H18BrN3OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-1-pyridin-4-ylethylideneamino]acetamide
    —— 3-Methylpentan-2-thiol, erythro —— C6H14S
    3-Methylpentan-2-thiol, erythro
    —— 2-mercaptophenyl-1-pentanol, TMS —— C14H24OSSi
    2-mercaptophenyl-1-pentanol, TMS
    —— 2-(Methylthiomethyl)ethanal —— C4H8OS2
    2-(Methylthiomethyl)ethanal
    —— (2-Chloroethylthiopropyl) (2-allylthioethyl) ether —— C10H19ClOS2
    (2-Chloroethylthiopropyl) (2-allylthioethyl) ether
    —— 2-Chlorovinyl 2-hydroxyethyl sulfide —— C4H7ClOS
    2-Chlorovinyl 2-hydroxyethyl sulfide
    —— 1-(2-Chloroethylthio)-4-(2-chloroethyldithio)butane —— C8H16Cl2S3
    1-(2-Chloroethylthio)-4-(2-chloroethyldithio)butane
    —— 4a,10a-dihydro-3H-[1,4]benzoxathiino[2,3-d]pyridazin-4-one —— C10H8N2O2S
    4a,10a-dihydro-3H-[1,4]benzoxathiino[2,3-d]pyridazin-4-one
    —— Methyl 3-methylbut-3-enyl sulfide —— C6H12S2
    Methyl 3-methylbut-3-enyl sulfide
    —— S-Isobutyl, S-2-(2-(2-diethylaminoethylthio)ethylthio))ethyl methyldithiophosphonate —— C14H32NOPS4
    S-Isobutyl, S-2-(2-(2-diethylaminoethylthio)ethylthio))ethyl methyldithiophosphonate
    —— 2-[But-3-enylthio]ethanal —— C6H10OS
    2-[But-3-enylthio]ethanal