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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-amino-5-pyrazin-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(Z)-benzylideneamino]acetamide —— C15H14N8OS
    2-[(4-amino-5-pyrazin-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(Z)-benzylideneamino]acetamide
    —— 2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]-1,3-benzoxazole —— C12H11N3OS
    2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]-1,3-benzoxazole
    —— (6S)-3-[(3-chlorophenyl)methylideneamino]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-ol —— C12H11ClN4OS
    (6S)-3-[(3-chlorophenyl)methylideneamino]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-ol
    —— [(6S)-3-benzyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-yl] methyl sulfite —— C13H15N3O3S2
    [(6S)-3-benzyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-yl] methyl sulfite
    —— methyl N-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]carbamodithioate —— C9H14N2S2
    methyl N-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]carbamodithioate
    —— (2S)-1-(cyclohexylamino)-3-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-2-ol —— C15H22N6OS
    (2S)-1-(cyclohexylamino)-3-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-2-ol
    —— N-[(Z)-benzylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H11N5OS
    N-[(Z)-benzylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (2S)-1-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(cyclohexylamino)propan-2-ol —— C18H26N4OS
    (2S)-1-[(5-benzyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(cyclohexylamino)propan-2-ol
    —— (2R)-1-[(4-amino-5-pyrazin-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-chloropropan-2-ol —— C9H11ClN6OS
    (2R)-1-[(4-amino-5-pyrazin-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-chloropropan-2-ol
    —— (6R)-3-[(4-chlorophenyl)methylideneamino]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-ol —— C12H11ClN4OS
    (6R)-3-[(4-chlorophenyl)methylideneamino]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-ol
    —— N-[(Z)-(2-chlorophenyl)methylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H10ClN5OS
    N-[(Z)-(2-chlorophenyl)methylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (6S)-3-[(4-bromophenyl)methylideneamino]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-ol —— C12H11BrN4OS
    (6S)-3-[(4-bromophenyl)methylideneamino]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-6-ol
    —— 5-Methylsulfanyl-4-pyridin-1-ium-1-yl-1,2-dihydropyrazol-3-one —— C9H10N3OS+
    5-Methylsulfanyl-4-pyridin-1-ium-1-yl-1,2-dihydropyrazol-3-one
    —— 3-Pyrazin-2-yl-[1,3]thiazolo[2,3-c][1,2,4]triazol-5-one —— C8H5N5OS
    3-Pyrazin-2-yl-[1,3]thiazolo[2,3-c][1,2,4]triazol-5-one
    —— (1S,6R)-N-butyl-6-(3-ethylsulfanyl-1H-1,2,4-triazol-5-yl)cyclohex-3-ene-1-carboxamide —— C15H24N4OS
    (1S,6R)-N-butyl-6-(3-ethylsulfanyl-1H-1,2,4-triazol-5-yl)cyclohex-3-ene-1-carboxamide
    —— (1S,6S)-N-benzyl-6-(3-methylsulfanyl-1H-1,2,4-triazol-5-yl)cyclohex-3-ene-1-carboxamide —— C17H20N4OS
    (1S,6S)-N-benzyl-6-(3-methylsulfanyl-1H-1,2,4-triazol-5-yl)cyclohex-3-ene-1-carboxamide
    —— [4-(2-Hydroxy-ethyl)-5-pyrazin-2-yl-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid hydrazide —— C10H13N7O2S
    [4-(2-Hydroxy-ethyl)-5-pyrazin-2-yl-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid hydrazide
    —— (6-Tert-butylsulfanylpyrazin-2-yl)thiourea —— C9H14N4S2
    (6-Tert-butylsulfanylpyrazin-2-yl)thiourea
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]propanamide —— C16H23NO3S2
    3-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]propanamide
    —— N-[(2S)-3-methylbutan-2-yl]-2-(4-methylphenyl)sulfanylacetamide —— C14H21NOS
    N-[(2S)-3-methylbutan-2-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C12H14F3NOS
    (2S)-2-(4-methylphenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— (2S)-2-(4-bromophenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C11H11BrF3NOS
    (2S)-2-(4-bromophenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— 2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[(2S)-pentan-2-yl]acetamide —— C12H18N2O2S
    2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[(2S)-pentan-2-yl]acetamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide —— C12H14F3NOS
    (2R)-2-(4-methylphenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propanamide
    —— 4-(difluoromethylsulfanyl)-N-[(1R)-1-(1-methylpyrazol-4-yl)ethyl]aniline —— C13H15F2N3S
    4-(difluoromethylsulfanyl)-N-[(1R)-1-(1-methylpyrazol-4-yl)ethyl]aniline
    —— (4R)-4-chloro-1-methylsulfonylheptane —— C8H17ClO2S
    (4R)-4-chloro-1-methylsulfonylheptane
    —— (2R,4S)-2-(2-methylsulfonylethyl)-4-propylcyclohexan-1-one —— C12H22O3S
    (2R,4S)-2-(2-methylsulfonylethyl)-4-propylcyclohexan-1-one
    —— (4S)-4-chloro-1-methylsulfonylheptane —— C8H17ClO2S
    (4S)-4-chloro-1-methylsulfonylheptane
    —— 2-[(1S)-1-cyanoethyl]sulfonylacetic acid —— C5H7NO4S
    2-[(1S)-1-cyanoethyl]sulfonylacetic acid
    —— N-[(3,4-difluorophenyl)methyl]-2-(2-fluorophenyl)sulfanyl-N-methylacetamide —— C16H14F3NOS
    N-[(3,4-difluorophenyl)methyl]-2-(2-fluorophenyl)sulfanyl-N-methylacetamide
    —— (3R)-N-[4-(difluoromethylsulfanyl)phenyl]piperidin-3-amine —— C12H16F2N2S
    (3R)-N-[4-(difluoromethylsulfanyl)phenyl]piperidin-3-amine
    —— (1S,2S)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-nitrocyclopropane-1-carboxamide —— C16H16N4O3S
    (1S,2S)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-nitrocyclopropane-1-carboxamide
    —— (1R,2R)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-nitrocyclopropane-1-carboxamide —— C16H16N4O3S
    (1R,2R)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-nitrocyclopropane-1-carboxamide
    —— (2R)-2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one —— C20H29N5OS
    (2R)-2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— (1S)-1-(5-benzylsulfanyl-4-butyl-1,2,4-triazol-3-yl)-N,N-dimethylpropan-1-amine —— C18H28N4S
    (1S)-1-(5-benzylsulfanyl-4-butyl-1,2,4-triazol-3-yl)-N,N-dimethylpropan-1-amine
    —— (2S)-N-[2-[di(propan-2-yl)amino]ethyl]-2-phenylsulfanylpropanamide —— C17H28N2OS
    (2S)-N-[2-[di(propan-2-yl)amino]ethyl]-2-phenylsulfanylpropanamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]propanamide —— C14H20ClNOS
    3-(4-chlorophenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]propanamide
    —— (1R)-1-[4-butyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C19H30N4S
    (1R)-1-[4-butyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C19H29N5O2S
    (2R)-1-(4-ethylpiperazin-1-yl)-2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— (1R)-1-[4-butyl-5-[(3-chlorophenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C18H27ClN4S
    (1R)-1-[4-butyl-5-[(3-chlorophenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— (2R)-N-[(2S)-3-methylbutan-2-yl]-2-phenylsulfanylpropanamide —— C14H21NOS
    (2R)-N-[(2S)-3-methylbutan-2-yl]-2-phenylsulfanylpropanamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]propanamide —— C14H20ClNOS
    3-(4-chlorophenyl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]propanamide
    —— N-(cyclohexylmethyl)-2-phenylsulfanylacetamide —— C15H21NOS
    N-(cyclohexylmethyl)-2-phenylsulfanylacetamide
    —— (1R)-1-[4-butyl-5-[(2-fluorophenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C18H27FN4S
    (1R)-1-[4-butyl-5-[(2-fluorophenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— 1-[[5-[[2-(2-chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one —— C17H15ClN4O2S2
    1-[[5-[[2-(2-chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one
    —— 2-(3,4-dimethylphenyl)-5-[[3-(furan-2-yl)-1,2,4-oxadiazol-5-yl]methylsulfanyl]-1,3,4-oxadiazole —— C17H14N4O3S
    2-(3,4-dimethylphenyl)-5-[[3-(furan-2-yl)-1,2,4-oxadiazol-5-yl]methylsulfanyl]-1,3,4-oxadiazole
    —— 3-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H12FN3S2
    3-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 3-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H12FN3S2
    3-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H20N4O2S
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 5-[(1R)-1-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C16H20N6O2S
    5-[(1R)-1-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole