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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(2-fluoro-6-methylsulfanylphenyl)-N,1-dimethylpyrrolidin-3-amine —— C13H19FN2S
    N-(2-fluoro-6-methylsulfanylphenyl)-N,1-dimethylpyrrolidin-3-amine
    —— [Diphenyl-(5-phenylsulfanylthiophen-2-yl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium —— C23H18F3O3S4+
    [Diphenyl-(5-phenylsulfanylthiophen-2-yl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium
    —— (Ethyldisulfanyl)ethane;1-(pent-2-enyldisulfanyl)pent-2-ene —— C14H28S4
    (Ethyldisulfanyl)ethane;1-(pent-2-enyldisulfanyl)pent-2-ene
    —— [[2-(4-Fluorophenyl)sulfanyl-1-phenylethylidene]amino]urea —— C15H14FN3OS
    [[2-(4-Fluorophenyl)sulfanyl-1-phenylethylidene]amino]urea
    —— Ethane;methanol;phenylsulfanylbenzene —— C19H32OS
    Ethane;methanol;phenylsulfanylbenzene
    —— [4-[4-[Heptyl-[(4-methoxyphenyl)carbamoyl]amino]phenyl]sulfanylphenyl] butanoate —— C31H38N2O4S
    [4-[4-[Heptyl-[(4-methoxyphenyl)carbamoyl]amino]phenyl]sulfanylphenyl] butanoate
    —— 3-(Ethylsulfonylmethyl)octane —— C11H24O2S
    3-(Ethylsulfonylmethyl)octane
    —— 8-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2,4,5-triazatricyclo[7.3.0.03,7]dodeca-1,3(7),5-triene-10,11-dione —— C20H13N5O3S
    8-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2,4,5-triazatricyclo[7.3.0.03,7]dodeca-1,3(7),5-triene-10,11-dione
    —— Diphenyl-[[1-(phenylsulfanylmethyl)triazol-4-yl]methyl]phosphane;4-ethyl-1-(phenylsulfanylmethyl)triazole —— C33H33N6PS2
    Diphenyl-[[1-(phenylsulfanylmethyl)triazol-4-yl]methyl]phosphane;4-ethyl-1-(phenylsulfanylmethyl)triazole
    —— 2-Methylsulfanyl-2-methylsulfonylbutane —— C6H14O2S2
    2-Methylsulfanyl-2-methylsulfonylbutane
    —— 4-methyl-N-[5-(1-methylimidazol-2-yl)sulfanylpyridin-2-yl]-1,3-thiazol-2-amine —— C13H13N5S2
    4-methyl-N-[5-(1-methylimidazol-2-yl)sulfanylpyridin-2-yl]-1,3-thiazol-2-amine
    —— 3-{(Z)-[4-oxo-3-(tetrahydrofuran-2-ylmethyl)-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C23H19N3O3S3
    3-{(Z)-[4-oxo-3-(tetrahydrofuran-2-ylmethyl)-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— (5E)-3-benzyl-5-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]-2-thioxo-1,3-thiazolidin-4-one —— C22H15N3O3S3
    (5E)-3-benzyl-5-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]-2-thioxo-1,3-thiazolidin-4-one
    —— (1-Bromo-2,2,2-trifluoroethyl)-[2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfanyl)phenyl]diazene —— C11H8BrF7N2S
    (1-Bromo-2,2,2-trifluoroethyl)-[2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfanyl)phenyl]diazene
    —— 4-[5-[(5-Chloro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]-1,4,4a,6,7,8-hexahydropyrazolo[3,4-b][1,7]naphthyridin-5-one —— C20H14ClN5O2S2
    4-[5-[(5-Chloro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl]-1,4,4a,6,7,8-hexahydropyrazolo[3,4-b][1,7]naphthyridin-5-one
    —— 3-[3,3-Bis(sulfanyl)propyldisulfanyl]propane-1,1-dithiol —— C6H14S6
    3-[3,3-Bis(sulfanyl)propyldisulfanyl]propane-1,1-dithiol
    —— 3-(Amino-hydroxy-oxo-lambda6-sulfanylidene)-2,2-dimethylbutane —— C6H15NO2S
    3-(Amino-hydroxy-oxo-lambda6-sulfanylidene)-2,2-dimethylbutane
    —— (1-Methylcyclopropyl)-methylidene-oxo-propan-2-yloxy-lambda6-sulfane —— C8H16O2S
    (1-Methylcyclopropyl)-methylidene-oxo-propan-2-yloxy-lambda6-sulfane
    —— 4-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]butanoic acid —— C16H14BrN5O4S
    4-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]butanoic acid
    —— [4-Bromo-3,5-bis(methylsulfanyl)phenyl]methanimine —— C9H10BrNS2
    [4-Bromo-3,5-bis(methylsulfanyl)phenyl]methanimine
    —— ethyl (2E)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-(thiophen-3-ylmethylidene)-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C22H20N2O3S3
    ethyl (2E)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-(thiophen-3-ylmethylidene)-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 1-Methylsulfonylsulfanyl-2-(sulfinatoamino)ethane —— C3H8NO4S3-
    1-Methylsulfonylsulfanyl-2-(sulfinatoamino)ethane
    —— 9-(Trisulfanyl)non-3-ene —— C9H18S3
    9-(Trisulfanyl)non-3-ene
    —— propan-2-yl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-(pyridin-3-ylmethylidene)-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H23N3O3S2
    propan-2-yl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-(pyridin-3-ylmethylidene)-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— [(Z)-(4-bromophenyl)methylideneamino] 2-pyrimidin-2-ylsulfanylacetate —— C13H10BrN3O2S
    [(Z)-(4-bromophenyl)methylideneamino] 2-pyrimidin-2-ylsulfanylacetate
    —— 1-(4-Tert-butyl-2-methoxyphenyl)-3-(4-pyridin-4-ylsulfanylphenyl)urea —— C23H25N3O2S
    1-(4-Tert-butyl-2-methoxyphenyl)-3-(4-pyridin-4-ylsulfanylphenyl)urea
    —— Ethane;2-phenylsulfanylpyridin-3-ol —— C17H27NOS
    Ethane;2-phenylsulfanylpyridin-3-ol
    —— isopropyl 7-methyl-2-[(5-methyl-2-furyl)methylene]-5-[4-(methylthio)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H24N2O4S2
    isopropyl 7-methyl-2-[(5-methyl-2-furyl)methylene]-5-[4-(methylthio)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 1-(Amino-hydroxy-oxo-lambda6-sulfanylidene)-4-methylpentane —— C6H15NO2S
    1-(Amino-hydroxy-oxo-lambda6-sulfanylidene)-4-methylpentane
    —— isopropyl 7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2-(4-pyridinylmethylene)-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H23N3O3S2
    isopropyl 7-methyl-5-[4-(methylsulfanyl)phenyl]-3-oxo-2-(4-pyridinylmethylene)-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— [11C]2-(2-((Dimethylamino)methyl)phenylthio)-5-(2-fluoroethyl)phenylamine —— C16H19FN2S
    [11C]2-(2-((Dimethylamino)methyl)phenylthio)-5-(2-fluoroethyl)phenylamine
    —— Ethane-1,2-dithiol;ethanol;propane —— C7H20OS2
    Ethane-1,2-dithiol;ethanol;propane
    —— 5-[(5-chloro-2-methylsulfanylpyrimidin-4-yl)methyl]-N-phenyl-1,3-thiazol-2-amine —— C15H13ClN4S2
    5-[(5-chloro-2-methylsulfanylpyrimidin-4-yl)methyl]-N-phenyl-1,3-thiazol-2-amine
    —— [1-[2-Ethyl-3-[4-(trimethyl-lambda4-sulfanyl)butyl]cyclopropyl]-2,4-dimethylhex-2-en-3-yl]-methylphosphane —— C21H43PS
    [1-[2-Ethyl-3-[4-(trimethyl-lambda4-sulfanyl)butyl]cyclopropyl]-2,4-dimethylhex-2-en-3-yl]-methylphosphane
    —— [4-[3-[Heptylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C32H40N2O3S
    [4-[3-[Heptylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 5-(2,5-Dihydroxy-3-propylsulfanylpyrrol-1-yl)pentan-2-one —— C12H19NO3S
    5-(2,5-Dihydroxy-3-propylsulfanylpyrrol-1-yl)pentan-2-one
    —— S-(2,2-difluoroacetyl) 2,2-difluoroethanethioate —— C4H2F4O2S
    S-(2,2-difluoroacetyl) 2,2-difluoroethanethioate
    —— [(3Z)-hexa-1,3,5-trien-2-yl]-methyl-methylidene-oxo-lambda6-sulfane —— C8H12OS
    [(3Z)-hexa-1,3,5-trien-2-yl]-methyl-methylidene-oxo-lambda6-sulfane
    —— (+/-)-Methyl {8-bromo-6-fluoro-9-[(2,4,5-trichlorophenyl)thio]-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl}acetate —— C20H14BrCl3FNO2S
    (+/-)-Methyl {8-bromo-6-fluoro-9-[(2,4,5-trichlorophenyl)thio]-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl}acetate
    —— (Z)-2-((3-cyano-4-(thiophen-2-yl)-7-(thiophen-2-ylmethylene)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)thio)acetamide —— C20H15N3OS3
    (Z)-2-((3-cyano-4-(thiophen-2-yl)-7-(thiophen-2-ylmethylene)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)thio)acetamide
    —— 5-hydroxy-3-methyl-4-octylsulfanyl-1H-imidazol-2-one —— C12H22N2O2S
    5-hydroxy-3-methyl-4-octylsulfanyl-1H-imidazol-2-one
    —— 5-ethyl-3-fluoro-N-(2-fluoro-4-methylsulfanylphenyl)-4-[[5-methyl-6-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)-2-bicyclo[2.2.2]octanyl]oxy]pyridin-2-amine —— C28H34F2N4O2S
    5-ethyl-3-fluoro-N-(2-fluoro-4-methylsulfanylphenyl)-4-[[5-methyl-6-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)-2-bicyclo[2.2.2]octanyl]oxy]pyridin-2-amine
    —— N-[(2-aminophenyl)methyl]-4-(4-hydroxyphenyl)sulfanylpentanamide —— C18H22N2O2S
    N-[(2-aminophenyl)methyl]-4-(4-hydroxyphenyl)sulfanylpentanamide
    —— Fluorovinyl sulfide —— C4H4F2S
    Fluorovinyl sulfide
    —— [Tert-butyl-(2-cyclopentyl-2-oxoethyl)-methyl-lambda4-sulfanyl]-butylsulfonyloxidanium —— C16H33O4S2+
    [Tert-butyl-(2-cyclopentyl-2-oxoethyl)-methyl-lambda4-sulfanyl]-butylsulfonyloxidanium
    —— 4-Tert-butyl-4,6,6-trimethyl-1-methylsulfonylheptan-3-one —— C15H30O3S
    4-Tert-butyl-4,6,6-trimethyl-1-methylsulfonylheptan-3-one
    —— Carbamothioyl propanoate —— C4H7NO2S
    Carbamothioyl propanoate
    —— 6-Sulfanylidenedodeca-2,4,7,10-tetraenethial —— C12H14S2
    6-Sulfanylidenedodeca-2,4,7,10-tetraenethial
    —— 3-(4-Chlorophenyl)-5-{[5-(phenylsulfanyl)-2-furyl]methylene}-1,3-thiazolidine-2,4-dione —— C20H12ClNO3S2
    3-(4-Chlorophenyl)-5-{[5-(phenylsulfanyl)-2-furyl]methylene}-1,3-thiazolidine-2,4-dione
    —— 3-Butyl-5-methylhept-2-ene-1-thiol —— C12H24S
    3-Butyl-5-methylhept-2-ene-1-thiol