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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Methoxy-1-(2-methoxyethylsulfanyl)adamantane-2-thione —— C14H22O2S2
    5-Methoxy-1-(2-methoxyethylsulfanyl)adamantane-2-thione
    —— 1,4-Bis(methylsulfanyl)bicyclo[2.2.2]octane —— C10H18S2
    1,4-Bis(methylsulfanyl)bicyclo[2.2.2]octane
    —— 1.3-Dimethylthio-2-isopropylthio-propan 69652-43-3 C8H18S3
    1.3-Dimethylthio-2-isopropylthio-propan
    —— 1-Methyl-4-[4-[4-(4-methylsulfanylphenyl)sulfonylphenyl]sulfanylphenyl]sulfonylbenzene —— C26H22O4S4
    1-Methyl-4-[4-[4-(4-methylsulfanylphenyl)sulfonylphenyl]sulfanylphenyl]sulfonylbenzene
    —— N'-({4-bromo-5-[(4-chlorophenyl)sulfanyl]-2-furyl}methylene)-2-(1-naphthyloxy)acetohydrazide —— C23H16BrClN2O3S
    N'-({4-bromo-5-[(4-chlorophenyl)sulfanyl]-2-furyl}methylene)-2-(1-naphthyloxy)acetohydrazide
    —— 2-(aminodiazenyl)-5-phenylsulfanyl-9H-pyrimido[4,5-b]indol-4-amine —— C16H13N7S
    2-(aminodiazenyl)-5-phenylsulfanyl-9H-pyrimido[4,5-b]indol-4-amine
    —— 4-Methyl-1,1,3-trioxo-1,3-dithietan-2-one —— C3H4O4S2
    4-Methyl-1,1,3-trioxo-1,3-dithietan-2-one
    —— 4-[3-Fluoro-4-phenylsulfanyl-5-(trifluoromethyl)phenyl]-1,5-dihydro-1,2,4-triazole-3,5-diamine —— C15H13F4N5S
    4-[3-Fluoro-4-phenylsulfanyl-5-(trifluoromethyl)phenyl]-1,5-dihydro-1,2,4-triazole-3,5-diamine
    —— 5-Ethyl-2-methylsulfanylpyrimidine-4,6-diamine —— C7H12N4S
    5-Ethyl-2-methylsulfanylpyrimidine-4,6-diamine
    —— 1-[3-Chloro-4-(4-methoxyphenyl)sulfanyl-5-(trifluoromethyl)phenyl]-1,2,4-triazole-3,5-diamine —— C16H13ClF3N5OS
    1-[3-Chloro-4-(4-methoxyphenyl)sulfanyl-5-(trifluoromethyl)phenyl]-1,2,4-triazole-3,5-diamine
    —— 3,5-Dichloro-2-[2-(trifluoromethyl)phenyl]sulfanylaniline —— C13H8Cl2F3NS
    3,5-Dichloro-2-[2-(trifluoromethyl)phenyl]sulfanylaniline
    —— 1-[3,5-Dichloro-4-(4-methoxyphenyl)sulfanylphenyl]-1,2,4-triazole-3,5-diamine —— C15H13Cl2N5OS
    1-[3,5-Dichloro-4-(4-methoxyphenyl)sulfanylphenyl]-1,2,4-triazole-3,5-diamine
    —— (3R)-3-amino-3-[3-[3-(2,6-dimethylphenyl)sulfanylprop-1-ynyl]phenyl]propan-1-ol —— C20H23NOS
    (3R)-3-amino-3-[3-[3-(2,6-dimethylphenyl)sulfanylprop-1-ynyl]phenyl]propan-1-ol
    —— 2-[(2S)-2-(pyrrolidin-1-ylmethyl)pyrrolidin-1-yl]-6-[4-(trifluoromethoxy)phenyl]sulfanylpyridine-3-carbaldehyde —— C22H24F3N3O2S
    2-[(2S)-2-(pyrrolidin-1-ylmethyl)pyrrolidin-1-yl]-6-[4-(trifluoromethoxy)phenyl]sulfanylpyridine-3-carbaldehyde
    —— 2,5-Diethyl-2,3-dihydro-[1,3]thiazolo[5,4-d][1,3]thiazole —— C8H12N2S2
    2,5-Diethyl-2,3-dihydro-[1,3]thiazolo[5,4-d][1,3]thiazole
    —— 2-Ethyl-6-methyl-2,3-dihydro-1-benzothiophene —— C11H14S
    2-Ethyl-6-methyl-2,3-dihydro-1-benzothiophene
    —— (3S)-3-amino-5-methylsulfanylpent-1-ene-2-thiol —— C6H13NS2
    (3S)-3-amino-5-methylsulfanylpent-1-ene-2-thiol
    —— 2-[(5-Methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]benzene-1,4-diol —— C9H8N2O2S3
    2-[(5-Methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]benzene-1,4-diol
    —— 2-(2-Chloroethylsulfanyl)acetaldehyde —— C4H7ClOS
    2-(2-Chloroethylsulfanyl)acetaldehyde
    —— Methylsulfanylmethoxy(methylsulfanylmethoxymethoxy)methane —— C6H14O3S2
    Methylsulfanylmethoxy(methylsulfanylmethoxymethoxy)methane
    —— 2-Bromo-1-(2-bromophenyl)sulfanyl-3-fluorobenzene —— C12H7Br2FS
    2-Bromo-1-(2-bromophenyl)sulfanyl-3-fluorobenzene
    —— (3R)-5-butoxy-3-hydroxy-N,N-bis(prop-2-enyl)pentanethioamide —— C15H27NO2S
    (3R)-5-butoxy-3-hydroxy-N,N-bis(prop-2-enyl)pentanethioamide
    —— (3R)-3-hydroxy-N,N-bis(prop-2-enyl)hexanethioamide —— C12H21NOS
    (3R)-3-hydroxy-N,N-bis(prop-2-enyl)hexanethioamide
    —— N-[(2S,3R)-2-(pyridin-3-ylmethyl)-1-azabicyclo[2.2.2]octan-3-yl]-3-pyridin-2-ylsulfanylbenzamide —— C25H26N4OS
    N-[(2S,3R)-2-(pyridin-3-ylmethyl)-1-azabicyclo[2.2.2]octan-3-yl]-3-pyridin-2-ylsulfanylbenzamide
    —— 3-(4-ethylsulfanylphenyl)-5-(3-hydroxypropyl)-3H-[1,3,4]oxadiazol-2-one 1618677-55-6 C13H16N2O3S
    3-(4-ethylsulfanylphenyl)-5-(3-hydroxypropyl)-3H-[1,3,4]oxadiazol-2-one
    —— 3-[4-(4-Ethylsulfanylphenyl)-5-oxo-1,3,4-oxadiazol-2-yl]propanal —— C13H14N2O3S
    3-[4-(4-Ethylsulfanylphenyl)-5-oxo-1,3,4-oxadiazol-2-yl]propanal
    —— [2-(5-Bromo-2-methylsulfanylpyrimidin-4-yl)-2-(3,5-difluorophenyl)ethyl]carbamic acid —— C14H12BrF2N3O2S
    [2-(5-Bromo-2-methylsulfanylpyrimidin-4-yl)-2-(3,5-difluorophenyl)ethyl]carbamic acid
    —— (2S)-2-(5-bromo-2-methylsulfanylpyrimidin-4-yl)-2-(3,5-difluorophenyl)ethanamine —— C13H12BrF2N3S
    (2S)-2-(5-bromo-2-methylsulfanylpyrimidin-4-yl)-2-(3,5-difluorophenyl)ethanamine
    —— [1-(3-Amino-4-phenylsulfanylbutyl)piperidin-4-yl] ditert-butyl phosphate —— C23H41N2O4PS
    [1-(3-Amino-4-phenylsulfanylbutyl)piperidin-4-yl] ditert-butyl phosphate
    —— 2-(2,3,5-Trimethylheptan-4-ylsulfanyl)ethanol —— C12H26OS
    2-(2,3,5-Trimethylheptan-4-ylsulfanyl)ethanol
    —— N-[4-[4-[[(2S)-4-azabicyclo[5.2.0]nonan-2-yl]amino]-6-(1H-pyrazol-5-ylamino)pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide —— C25H30N8OS
    N-[4-[4-[[(2S)-4-azabicyclo[5.2.0]nonan-2-yl]amino]-6-(1H-pyrazol-5-ylamino)pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide
    —— (3R)-3-(1,2-dihydrodiazet-3-ylsulfanyl)-2-hydroxy-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid —— C11H11BN2O4S
    (3R)-3-(1,2-dihydrodiazet-3-ylsulfanyl)-2-hydroxy-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid
    —— 6-[(2R,3S,4S,5S)-3,4,5-trihydroxyoxan-2-yl]sulfanyl-2H-1,2,4-triazine-3,5-dione —— C8H11N3O6S
    6-[(2R,3S,4S,5S)-3,4,5-trihydroxyoxan-2-yl]sulfanyl-2H-1,2,4-triazine-3,5-dione
    —— 3-[Deuterio(trideuteriomethylsulfonyl)methyl]-2,2,4,4-tetramethylpentane —— C11H24O2S
    3-[Deuterio(trideuteriomethylsulfonyl)methyl]-2,2,4,4-tetramethylpentane
    —— 3-Deuterio-3-[deuterio(trideuteriomethylsulfonyl)methyl]-2,2,4,4-tetramethylpentane —— C11H24O2S
    3-Deuterio-3-[deuterio(trideuteriomethylsulfonyl)methyl]-2,2,4,4-tetramethylpentane
    —— 3-(Deuteriomethylsulfonylmethyl)-2,2,4,4-tetramethylpentane —— C11H24O2S
    3-(Deuteriomethylsulfonylmethyl)-2,2,4,4-tetramethylpentane
    —— 3-Deuterio-3-[dideuterio(dideuteriomethylsulfonyl)methyl]-2,2,4,4-tetramethylpentane —— C11H24O2S
    3-Deuterio-3-[dideuterio(dideuteriomethylsulfonyl)methyl]-2,2,4,4-tetramethylpentane
    —— 2-(2,2-Dimethylpropyl)thietane 1,1-dioxide —— C8H16O2S
    2-(2,2-Dimethylpropyl)thietane 1,1-dioxide
    —— 3-Tert-butyl-3-methylthietane 1,1-dioxide —— C8H16O2S
    3-Tert-butyl-3-methylthietane 1,1-dioxide
    —— 2-[3-Ethylsulfanyl-5-(trifluoromethyl)pyridin-2-yl]-6-methyl-[1,3]thiazolo[5,4-b]pyridine —— C15H12F3N3S2
    2-[3-Ethylsulfanyl-5-(trifluoromethyl)pyridin-2-yl]-6-methyl-[1,3]thiazolo[5,4-b]pyridine
    —— 5-[[(3R)-2-hydroxy-8-methyl-3,4-dihydro-1,2-benzoxaborinin-3-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C11H12BN3O2S2
    5-[[(3R)-2-hydroxy-8-methyl-3,4-dihydro-1,2-benzoxaborinin-3-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 3-[[(3R)-2-hydroxy-8-methyl-3,4-dihydro-1,2-benzoxaborinin-3-yl]sulfanyl]-4-methyl-1,2,4-triazole —— C12H14BN3O2S
    3-[[(3R)-2-hydroxy-8-methyl-3,4-dihydro-1,2-benzoxaborinin-3-yl]sulfanyl]-4-methyl-1,2,4-triazole
    —— 4-Heptylundecane-1-thiol —— C18H38S
    4-Heptylundecane-1-thiol
    —— (2R)-N-[(Z)-(3-bromophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H25BrN6OS
    (2R)-N-[(Z)-(3-bromophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-fluorophenyl)methylideneamino]propanamide —— C22H22ClFN6OS
    (2R)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-fluorophenyl)methylideneamino]propanamide
    —— (2R)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(2-chlorophenyl)methylideneamino]propanamide —— C22H22Cl2N6OS
    (2R)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(2-chlorophenyl)methylideneamino]propanamide
    —— 2-Hydroxy-3-(1,3,4-thiadiazol-2-ylsulfanyl)-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid —— C11H9BN2O4S2
    2-Hydroxy-3-(1,3,4-thiadiazol-2-ylsulfanyl)-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid
    —— (2S)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(2-chlorophenyl)methylideneamino]propanamide —— C22H22Cl2N6OS
    (2S)-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(2-chlorophenyl)methylideneamino]propanamide
    —— 2-Hydroxy-3-(1,3-thiazol-2-ylsulfanyl)-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid —— C12H10BNO4S2
    2-Hydroxy-3-(1,3-thiazol-2-ylsulfanyl)-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid
    —— 2-Hydroxy-3-phenylsulfanyl-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid —— C15H13BO4S
    2-Hydroxy-3-phenylsulfanyl-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid