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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[[(2S)-oxan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C21H21N3OS
    3-[[(2S)-oxan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— (6R,7R)-3-(2-methoxyethyl)-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C9H16N4OS
    (6R,7R)-3-(2-methoxyethyl)-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(1-Methylpyridin-1-ium-2-yl)sulfanyl-5,6-diphenyl-1,2,4-triazine —— C21H17N4S+
    3-(1-Methylpyridin-1-ium-2-yl)sulfanyl-5,6-diphenyl-1,2,4-triazine
    —— (6R,7S)-3,6,7-trimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C7H12N4S
    (6R,7S)-3,6,7-trimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S)-3-cyclohexyl-6-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C13H22N4S
    (6S)-3-cyclohexyl-6-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S,7R)-3,6,7-trimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C7H12N4S
    (6S,7R)-3,6,7-trimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R)-6-tert-butyl-3-[(2S)-oxolan-2-yl]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C12H20N4OS
    (6R)-6-tert-butyl-3-[(2S)-oxolan-2-yl]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide —— C27H34N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide
    —— (6R,7R)-3-butyl-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C10H18N4S
    (6R,7R)-3-butyl-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R)-3-ethyl-6-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C7H12N4S
    (6R)-3-ethyl-6-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S,7R)-3-[(4-fluorophenyl)methyl]-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C13H15FN4S
    (6S,7R)-3-[(4-fluorophenyl)methyl]-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R)-3-tert-butyl-6-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C9H16N4S
    (6R)-3-tert-butyl-6-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R,7S)-3-[(4-fluorophenyl)methyl]-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C13H15FN4S
    (6R,7S)-3-[(4-fluorophenyl)methyl]-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R,7R)-6,7-dimethyl-3-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C9H16N4S
    (6R,7R)-6,7-dimethyl-3-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (3S,7S)-12-benzyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C14H16N4S
    (3S,7S)-12-benzyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3S,7R)-12-[(4-fluorophenyl)methyl]-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C14H15FN4S
    (3S,7R)-12-[(4-fluorophenyl)methyl]-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]ethanone —— C25H28N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]ethanone
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide —— C22H22N4O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide
    —— 3-[[(2S)-oxolan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C20H19N3OS
    3-[[(2S)-oxolan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-diethylacetamide —— C23H26N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone —— C23H18ClN3OS2
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone
    —— N-benzyl-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-tert-butylacetamide —— C30H32N4OS
    N-benzyl-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-tert-butylacetamide
    —— 1-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-3,3-dimethylbutan-2-one —— C21H21N3OS
    1-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-3,3-dimethylbutan-2-one
    —— 6-Amino-5-[2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetyl]-1,3-dimethylpyrimidine-2,4-dione —— C25H24N6O3S
    6-Amino-5-[2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetyl]-1,3-dimethylpyrimidine-2,4-dione
    —— 4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanylmethyl]-2-phenyl-1,3-thiazole —— C25H18N4S2
    4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanylmethyl]-2-phenyl-1,3-thiazole
    —— (2R)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propanenitrile —— C20H18N4S
    (2R)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propanenitrile
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclohexyl-N-methylacetamide —— C26H30N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclohexyl-N-methylacetamide
    —— 1-[2,5-Dimethyl-1-(3-methylbutyl)pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C28H30N4OS
    1-[2,5-Dimethyl-1-(3-methylbutyl)pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— (2S)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]propanamide —— C23H24N4O2S
    (2S)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]propanamide
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetamide —— C19H18N4OS
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetamide
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(3-phenylpropyl)acetamide —— C26H24N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(3-phenylpropyl)acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-dimethylacetamide —— C21H22N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-dimethylacetamide
    —— N-cycloheptyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C24H26N4OS
    N-cycloheptyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 1-(Azepan-1-yl)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]ethanone —— C25H28N4OS
    1-(Azepan-1-yl)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]ethanone
    —— N-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide —— C23H19N5O2S
    N-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]ethanone —— C30H32N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]ethanone
    —— 1-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C28H28N4O2S
    1-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole —— C24H17N5OS
    2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanylmethyl]-5-phenyl-1,3,4-oxadiazole
    —— N-benzyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide —— C25H22N4OS
    N-benzyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]ethanone —— C30H32N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]ethanone
    —— 3-[(2-Chlorophenyl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C22H16ClN3S
    3-[(2-Chlorophenyl)methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C25H22N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— (3S)-3-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]oxolan-2-one —— C19H15N3O2S
    (3S)-3-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]oxolan-2-one
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclohexylacetamide —— C25H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclohexylacetamide
    —— 2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-[(2-chlorophenyl)methyl]acetamide —— C26H23ClN4OS
    2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-[(2-chlorophenyl)methyl]acetamide
    —— N-[(2S)-4-phenylbutan-2-yl]-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C21H22N4OS
    N-[(2S)-4-phenylbutan-2-yl]-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— N-[(2R)-4-phenylbutan-2-yl]-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C21H22N4OS
    N-[(2R)-4-phenylbutan-2-yl]-2-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— N-[2-(cyclohex-1-en-1-yl)ethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C25H26N4OS
    N-[2-(cyclohex-1-en-1-yl)ethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2S)-butan-2-yl]acetamide —— C23H26N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2S)-butan-2-yl]acetamide
    —— 3,5-Bis[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazine —— C18H15Cl2N3S2
    3,5-Bis[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazine