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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-Fluoro-4-methoxy-2-methyl-5-phenylsulfanyloxan-3-ol;4-methoxy-2,5,6-trimethyloxane-3-carbaldehyde —— C23H35FO6S
    6-Fluoro-4-methoxy-2-methyl-5-phenylsulfanyloxan-3-ol;4-methoxy-2,5,6-trimethyloxane-3-carbaldehyde
    —— (Z)-1-[6-(4-chlorophenyl)sulfanylpyridin-3-yl]-N-[(2,4-dichlorophenyl)methoxy]methanimine —— C19H13Cl3N2OS
    (Z)-1-[6-(4-chlorophenyl)sulfanylpyridin-3-yl]-N-[(2,4-dichlorophenyl)methoxy]methanimine
    —— 2-(2-methoxyethylsulfonyl)ethyl N-tert-butylcarbamate —— C10H21NO5S
    2-(2-methoxyethylsulfonyl)ethyl N-tert-butylcarbamate
    —— 1H-thieno[2,3-e][1,3,4]thiadiazine-3-carboxamide —— C6H5N3OS2
    1H-thieno[2,3-e][1,3,4]thiadiazine-3-carboxamide
    —— 3-[[(E)-[(E)-[(E)-(dimethylhydrazinylidene)hydrazinylidene]hydrazinylidene]hydrazinylidene]carbamothioyl]-1,1-dimethylthiourea —— C6H13N11S2
    3-[[(E)-[(E)-[(E)-(dimethylhydrazinylidene)hydrazinylidene]hydrazinylidene]hydrazinylidene]carbamothioyl]-1,1-dimethylthiourea
    —— propan-2-yl N-[5-[(5-propan-2-yl-2,3-dihydro-1,3-oxazol-2-yl)methylsulfanyl]-1,3-thiazol-2-yl]carbamate —— C14H21N3O3S2
    propan-2-yl N-[5-[(5-propan-2-yl-2,3-dihydro-1,3-oxazol-2-yl)methylsulfanyl]-1,3-thiazol-2-yl]carbamate
    —— N-phenylmethoxy-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide —— C28H22N4O2S
    N-phenylmethoxy-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide
    —— 2-Oxoethyl chloromethanedithioate —— C3H3ClOS2
    2-Oxoethyl chloromethanedithioate
    —— 2-(4-Chloro-2-ethylsulfanyl-7-methyl-2,3-dihydro-1-benzothiophene-5-carbonyl)cyclohexane-1,3-dione —— C18H19ClO3S2
    2-(4-Chloro-2-ethylsulfanyl-7-methyl-2,3-dihydro-1-benzothiophene-5-carbonyl)cyclohexane-1,3-dione
    —— N'-pyridin-2-yl-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzohydrazide —— C26H20N6OS
    N'-pyridin-2-yl-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzohydrazide
    —— 3,3,4-Trimethyl-6-propylsulfanylhex-1-ene —— C12H24S
    3,3,4-Trimethyl-6-propylsulfanylhex-1-ene
    —— (+/-)-Methyl {8-bromo-9-[(4-chlorophenyl)thio]-6-cyano-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl}acetate —— C21H16BrClN2O2S
    (+/-)-Methyl {8-bromo-9-[(4-chlorophenyl)thio]-6-cyano-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl}acetate
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (E)-3-(furan-2-yl)prop-2-enoate —— C21H17NO4S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (E)-3-(furan-2-yl)prop-2-enoate
    —— 3-[2-(4-cyclopentylpiperazin-1-yl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine —— C24H34N7O2S+
    3-[2-(4-cyclopentylpiperazin-1-yl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine
    —— 4-[2-[4-[5-(Cyclohexa-1,3-dien-1-ylmethyl)-1,4-dioxin-2-yl]piperazin-1-yl]ethylsulfanyl]pyrimidine-5-carbonitrile —— C22H25N5O2S
    4-[2-[4-[5-(Cyclohexa-1,3-dien-1-ylmethyl)-1,4-dioxin-2-yl]piperazin-1-yl]ethylsulfanyl]pyrimidine-5-carbonitrile
    —— 1-Benzyl-3-cyclohexyl-1-[2-[[5-(4-methylpentanoyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]urea —— C24H34N4O3S
    1-Benzyl-3-cyclohexyl-1-[2-[[5-(4-methylpentanoyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]urea
    —— [(E)-2,6-dimethylnon-6-en-2-yl]sulfanylbenzene;(E)-4,8,8-trimethylnon-3-ene —— C29H50S
    [(E)-2,6-dimethylnon-6-en-2-yl]sulfanylbenzene;(E)-4,8,8-trimethylnon-3-ene
    —— 3,3,3-Trifluoro-1-(3,3,3-trifluoroprop-1-enylsulfanyl)prop-1-ene —— C6H4F6S
    3,3,3-Trifluoro-1-(3,3,3-trifluoroprop-1-enylsulfanyl)prop-1-ene
    —— 4,6-Dimethoxy-2-phenylsulfanylpyrimidine —— C12H12N2O2S
    4,6-Dimethoxy-2-phenylsulfanylpyrimidine
    —— 6-[2-(2-Propynylcarbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole —— C24H18N4OS
    6-[2-(2-Propynylcarbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole
    —— (Z)-1-[6-(4-chlorophenyl)sulfanylpyridin-3-yl]-N-methoxymethanimine —— C13H11ClN2OS
    (Z)-1-[6-(4-chlorophenyl)sulfanylpyridin-3-yl]-N-methoxymethanimine
    —— 2-[(5-Ethylsulfanyl-1,3,4-thiadiazol-2-yl)diazenyl]-3-(furan-2-yl)-3-oxopropanenitrile —— C11H9N5O2S2
    2-[(5-Ethylsulfanyl-1,3,4-thiadiazol-2-yl)diazenyl]-3-(furan-2-yl)-3-oxopropanenitrile
    —— (2S,4R,5R)-1,2,4,5,6-pentahydroxyhexane-3-thione —— C6H12O5S
    (2S,4R,5R)-1,2,4,5,6-pentahydroxyhexane-3-thione
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(2,5-dimethylthiophen-3-yl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C17H19N11O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(2,5-dimethylthiophen-3-yl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 3-(3-Chloropropyl)-1-(4-fluorophenyl)-2,4,1-benzodithiazine —— C16H15ClFNS2
    3-(3-Chloropropyl)-1-(4-fluorophenyl)-2,4,1-benzodithiazine
    —— [Dimethylamino(heptylsulfanyl)methylidene]-dimethylazanium —— C12H27N2S+
    [Dimethylamino(heptylsulfanyl)methylidene]-dimethylazanium
    —— 6,8-Bis(sulfanyl)-7-(sulfanylmethyl)octan-1-ol —— C9H20OS3
    6,8-Bis(sulfanyl)-7-(sulfanylmethyl)octan-1-ol
    —— 2-Methylidene-4-[(4-methylsulfanylphenyl)methylidene]-1,3-oxazolidin-5-one —— C12H11NO2S
    2-Methylidene-4-[(4-methylsulfanylphenyl)methylidene]-1,3-oxazolidin-5-one
    —— (NZ)-N-[2-(4,6-dimethylpyrimidin-2-yl)sulfanylcyclooctylidene]hydroxylamine —— C14H21N3OS
    (NZ)-N-[2-(4,6-dimethylpyrimidin-2-yl)sulfanylcyclooctylidene]hydroxylamine
    —— 1-Methylidene-2-methylsulfanyl-3-propan-2-ylcyclopropane —— C8H13S+
    1-Methylidene-2-methylsulfanyl-3-propan-2-ylcyclopropane
    —— (2-Amino-2-oxoethyl)-diethyl-[6-[[6-(oxolan-3-yloxy)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulfanyl]-1,3-benzothiazol-2-yl]azanium —— C22H26N7O3S2+
    (2-Amino-2-oxoethyl)-diethyl-[6-[[6-(oxolan-3-yloxy)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulfanyl]-1,3-benzothiazol-2-yl]azanium
    —— 1-Ethylsulfanyl-4,4,5,5,6,6,6-heptafluoro-3-methylhex-2-ene —— C9H11F7S
    1-Ethylsulfanyl-4,4,5,5,6,6,6-heptafluoro-3-methylhex-2-ene
    —— 2-(2-Ethylcyclohexa-2,4-dien-1-yl)-5-methylsulfanyl-4,5-dihydro-1,3-thiazole —— C12H17NS2
    2-(2-Ethylcyclohexa-2,4-dien-1-yl)-5-methylsulfanyl-4,5-dihydro-1,3-thiazole
    —— N-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]thiophene-2-carboxamide —— C22H15N3O4S4
    N-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]thiophene-2-carboxamide
    —— 8,8-Dimethylcyclohepta[b][1,4]benzodithiine —— C15H14S2
    8,8-Dimethylcyclohepta[b][1,4]benzodithiine
    —— 2-Methanidyl-4-phenylsulfanylpyrrolidine —— C11H14NS-
    2-Methanidyl-4-phenylsulfanylpyrrolidine
    —— 4-N-(3-chloro-4-methoxyphenyl)-2-N-cycloheptyl-6-[4-(2-methylpropyl)phenyl]sulfanyl-1,3,5-triazine-2,4-diamine —— C27H34ClN5OS
    4-N-(3-chloro-4-methoxyphenyl)-2-N-cycloheptyl-6-[4-(2-methylpropyl)phenyl]sulfanyl-1,3,5-triazine-2,4-diamine
    —— ethyl 2-[[(E)-3-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]-2-cyanoprop-2-enoyl]amino]-4,5-dimethylthiophene-3-carboxylate —— C24H19N3O4S3
    ethyl 2-[[(E)-3-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]-2-cyanoprop-2-enoyl]amino]-4,5-dimethylthiophene-3-carboxylate
    —— 4,8-Dimethyl-3,7,11,15,19,23,27-heptaoxa-31-thia-33,34,35,36,37,38,39,40-octazanonacyclo[28.2.1.12,5.16,9.110,13.114,17.118,21.122,25.126,29]tetraconta-1,4,6(39),8,10(38),12,14(37),16,18(36),20,22(35),24,26(34),28,30(33)-pentadecaene —— C26H14N8O7S
    4,8-Dimethyl-3,7,11,15,19,23,27-heptaoxa-31-thia-33,34,35,36,37,38,39,40-octazanonacyclo[28.2.1.12,5.16,9.110,13.114,17.118,21.122,25.126,29]tetraconta-1,4,6(39),8,10(38),12,14(37),16,18(36),20,22(35),24,26(34),28,30(33)-pentadecaene
    —— Methoxy(methylsulfanyl)methane;2-methylsulfanylacetaldehyde —— C9H22O3S3
    Methoxy(methylsulfanyl)methane;2-methylsulfanylacetaldehyde
    —— 7-(3-Ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)heptan-2-one —— C13H21NO3S
    7-(3-Ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)heptan-2-one
    —— 1,1-Difluoro-1-propylsulfanylpropane —— C6H12F2S
    1,1-Difluoro-1-propylsulfanylpropane
    —— 4-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperazine-2-carboximidamide —— C16H19N7S
    4-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperazine-2-carboximidamide
    —— (2S,6S)-3-[(4-fluorophenyl)sulfanylmethyl]bicyclo[4.1.0]heptane-2-carboxylic acid —— C15H17FO2S
    (2S,6S)-3-[(4-fluorophenyl)sulfanylmethyl]bicyclo[4.1.0]heptane-2-carboxylic acid
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-2-ylmethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C17H14N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-2-ylmethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— Chloro 2-methylsulfanylacetate —— C3H5ClO2S
    Chloro 2-methylsulfanylacetate
    —— N'-diazenyl-4-ethyl-5-methyl-6-(1-phosphanylethenylsulfanyl)pyrimidine-2-carboximidamide —— C10H15N6PS
    N'-diazenyl-4-ethyl-5-methyl-6-(1-phosphanylethenylsulfanyl)pyrimidine-2-carboximidamide
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-morpholin-4-ylacetamide —— C19H19ClN4O4S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-morpholin-4-ylacetamide
    —— 2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzohydrazide —— C21H17N5OS
    2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzohydrazide
    —— 6-(3,3-Dimethylbutyl)-2-methyl-3-[(4-pyridin-4-ylsulfanylphenyl)methoxy]phenol —— C25H29NO2S
    6-(3,3-Dimethylbutyl)-2-methyl-3-[(4-pyridin-4-ylsulfanylphenyl)methoxy]phenol