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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(Z)-1-(4-phenylsulfanylphenyl)ethylideneamino]thiourea —— C15H15N3S2
    [(Z)-1-(4-phenylsulfanylphenyl)ethylideneamino]thiourea
    —— 2-methoxy-N-(3-methylsulfonylpropyl)propan-1-amine —— C8H19NO3S
    2-methoxy-N-(3-methylsulfonylpropyl)propan-1-amine
    —— Tert-butyl 4-[2-[3-cyano-6-(trifluoromethyl)pyridin-2-yl]sulfanyl-2-(1,3-thiazol-5-yl)ethyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate —— C22H25F3N4O3S2
    Tert-butyl 4-[2-[3-cyano-6-(trifluoromethyl)pyridin-2-yl]sulfanyl-2-(1,3-thiazol-5-yl)ethyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
    —— 3-[3-[4-(Methoxyiminomethyl)oxan-4-yl]phenyl]sulfanylpropanoic acid —— C16H21NO4S
    3-[3-[4-(Methoxyiminomethyl)oxan-4-yl]phenyl]sulfanylpropanoic acid
    —— (2E)-2-cyano-N-(furan-2-ylmethyl)-3-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}prop-2-enamide —— C20H16N2O3S
    (2E)-2-cyano-N-(furan-2-ylmethyl)-3-{5-[(4-methylphenyl)sulfanyl]furan-2-yl}prop-2-enamide
    —— ethane;2-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-3-one —— C8H15N3OS
    ethane;2-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3]thiazin-3-one
    —— (E)-4-oxo-4-[2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylanilino]but-2-enoic acid —— C15H10F3N3O3S
    (E)-4-oxo-4-[2-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylanilino]but-2-enoic acid
    —— 1-(1,1-Difluoroethylsulfanyl)propane —— C5H10F2S
    1-(1,1-Difluoroethylsulfanyl)propane
    —— ethyl N'-(2-hydroxyethoxy)carbamimidothioate —— C5H12N2O2S
    ethyl N'-(2-hydroxyethoxy)carbamimidothioate
    —— (Z)-5-((2-((4-chlorophenyl)thio)-6-methoxyquinolin-3-yl)methylene)-2-thioxothiazolidin-4-one —— C20H13ClN2O2S3
    (Z)-5-((2-((4-chlorophenyl)thio)-6-methoxyquinolin-3-yl)methylene)-2-thioxothiazolidin-4-one
    —— (E)-N-[(4-chlorophenyl)methoxy]-2-(4-chlorophenyl)sulfanyl-1-phenylethanimine —— C21H17Cl2NOS
    (E)-N-[(4-chlorophenyl)methoxy]-2-(4-chlorophenyl)sulfanyl-1-phenylethanimine
    —— O-ethyl N-prop-2-enoylcarbamothioate —— C6H9NO2S
    O-ethyl N-prop-2-enoylcarbamothioate
    —— 3-(phenylsulfanyl)-N'-[(1E)-1-(thiophen-2-yl)ethylidene]propanehydrazide —— C15H16N2OS2
    3-(phenylsulfanyl)-N'-[(1E)-1-(thiophen-2-yl)ethylidene]propanehydrazide
    —— [(Z)-[3,3-dimethyl-1-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-2-ylidene]amino] N-phenylcarbamate —— C18H21N3O3S
    [(Z)-[3,3-dimethyl-1-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-2-ylidene]amino] N-phenylcarbamate
    —— N-[(E)-2-methoxyethenyl]tetradecanethioamide —— C17H33NOS
    N-[(E)-2-methoxyethenyl]tetradecanethioamide
    —— 2-Hept-2-en-3-ylsulfanyl-3-iminopropanenitrile —— C10H16N2S
    2-Hept-2-en-3-ylsulfanyl-3-iminopropanenitrile
    —— 1-Butan-2-yl-3-propan-2-ylsulfanylpyrrole-2,5-diol —— C11H19NO2S
    1-Butan-2-yl-3-propan-2-ylsulfanylpyrrole-2,5-diol
    —— [2-(4-Propylphenyl)sulfanylphenyl]hydrazine —— C15H18N2S
    [2-(4-Propylphenyl)sulfanylphenyl]hydrazine
    —— ethyl {3-[4-(1-butyl-3-phenethylureido)phenylsulphanyl]phenyl}acetate 735273-85-5 C29H34N2O3S
    ethyl {3-[4-(1-butyl-3-phenethylureido)phenylsulphanyl]phenyl}acetate
    —— N-[4-[2-[2-(1-methyl-2,5-dihydro-1,3-benzodiazepin-5-yl)ethenyl]phenyl]sulfanylphenyl]acetamide —— C26H25N3OS
    N-[4-[2-[2-(1-methyl-2,5-dihydro-1,3-benzodiazepin-5-yl)ethenyl]phenyl]sulfanylphenyl]acetamide
    —— 2-(2-Fluorophenyl)sulfanyl-1-methylimidazole —— C10H9FN2S
    2-(2-Fluorophenyl)sulfanyl-1-methylimidazole
    —— N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]-3-(trifluoromethyl)benzamide —— C19H13F3N2O2S
    N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]-3-(trifluoromethyl)benzamide
    —— (5-cyano-4-methylsulfanylpyridin-2-yl)methyl N-tert-butylcarbamate —— C13H17N3O2S
    (5-cyano-4-methylsulfanylpyridin-2-yl)methyl N-tert-butylcarbamate
    —— tert-butyl (4S)-4-[(2R)-2-(3-cyanopyridin-2-yl)sulfanyl-2-phenylethyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate —— C24H29N3O3S
    tert-butyl (4S)-4-[(2R)-2-(3-cyanopyridin-2-yl)sulfanyl-2-phenylethyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
    —— N-[(Z)-1-(3-bromophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H19BrN4OS3
    N-[(Z)-1-(3-bromophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]pyridine-3-carboxamide —— C17H11BrClN3O2S
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]pyridine-3-carboxamide
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-(3-bromophenyl)ethylideneamino]acetamide —— C19H17BrN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-(3-bromophenyl)ethylideneamino]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(2,4,6-trimethylphenyl)methylideneamino]triazole-4-carboxamide —— C22H21ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(2,4,6-trimethylphenyl)methylideneamino]triazole-4-carboxamide
    —— 2-(2-Hydroxy-3,5-dimethylphenyl)sulfanyl-4,6-dimethylphenol;(2-hydroxy-3-methyl-5-pentylphenyl) 2-hydroxy-3-methyl-5-pentylbenzenesulfinate —— C40H52O6S2
    2-(2-Hydroxy-3,5-dimethylphenyl)sulfanyl-4,6-dimethylphenol;(2-hydroxy-3-methyl-5-pentylphenyl) 2-hydroxy-3-methyl-5-pentylbenzenesulfinate
    —— N-octadecylthiolan-2-imine —— C22H43NS
    N-octadecylthiolan-2-imine
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C19H18N4OS4
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 5-(2-{[(2-Bromobenzyl)oxy]imino}ethyl)-3-{[3-chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-4-isothiazolecarbonitrile —— C19H11BrClF3N4OS2
    5-(2-{[(2-Bromobenzyl)oxy]imino}ethyl)-3-{[3-chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-4-isothiazolecarbonitrile
    —— Ethane;methanethione —— C3H8S
    Ethane;methanethione
    —— ethyl (2Z)-5-amino-6-cyano-2-[4-(methylsulfanyl)benzylidene]-7-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-7H-[1,3]thiazolo[3,2-a]pyridine-8-carboxylate —— C26H23N3O3S3
    ethyl (2Z)-5-amino-6-cyano-2-[4-(methylsulfanyl)benzylidene]-7-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-7H-[1,3]thiazolo[3,2-a]pyridine-8-carboxylate
    —— [(Z)-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylideneamino] benzoate —— C19H13ClF3N3O2S
    [(Z)-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylideneamino] benzoate
    —— [3-[3-[Hexylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C31H38N2O3S
    [3-[3-[Hexylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 2-(3-Chloropropylsulfinyl)ethanimine —— C5H10ClNOS
    2-(3-Chloropropylsulfinyl)ethanimine
    —— 5-Thieno[3,2-b]pyridin-7-ylsulfanylpyridin-2-amine —— C12H9N3S2
    5-Thieno[3,2-b]pyridin-7-ylsulfanylpyridin-2-amine
    —— N-[1-(4-chlorophenyl)-3-(4-fluorophenylthio)-2-propenylidene]-2-fluoroaniline 1140915-66-7 C21H14ClF2NS
    N-[1-(4-chlorophenyl)-3-(4-fluorophenylthio)-2-propenylidene]-2-fluoroaniline
    —— 6,7-Dihydro-1,4-thiazepine —— C5H7NS
    6,7-Dihydro-1,4-thiazepine
    —— [4-[4-[Heptyl(2-phenylethylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate —— C32H40N2O3S
    [4-[4-[Heptyl(2-phenylethylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C22H16BrN3S2
    N-[(Z)-(4-bromophenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— (2Z)-6-chloro-4-methyl-2-(pyridin-3-ylmethylidene)-1-benzothiophen-3-one —— C15H10ClNOS
    (2Z)-6-chloro-4-methyl-2-(pyridin-3-ylmethylidene)-1-benzothiophen-3-one
    —— Carbamoyloxycarbothioyl carbamate —— C3H4N2O4S
    Carbamoyloxycarbothioyl carbamate
    —— S-[5-(trifluoromethyl)pyridin-2-yl] (E)-3-thiophen-2-yl-2-thiophen-3-ylprop-2-enethioate —— C17H10F3NOS3
    S-[5-(trifluoromethyl)pyridin-2-yl] (E)-3-thiophen-2-yl-2-thiophen-3-ylprop-2-enethioate
    —— 4-[2-[6-amino-8-(3-methylthiophen-2-yl)sulfanyl-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde —— C18H23N6OS2+
    4-[2-[6-amino-8-(3-methylthiophen-2-yl)sulfanyl-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde
    —— 1-(Tricosyldisulfanyl)tricosane —— C46H94S2
    1-(Tricosyldisulfanyl)tricosane
    —— 2,3-Dihydrothieno[3,4-b][1,4]oxathiine;ethane —— C8H12OS2
    2,3-Dihydrothieno[3,4-b][1,4]oxathiine;ethane
    —— 1-(4,5,6,7-Tetrahydro-1-benzothiophen-2-ylsulfanyl)ethanethiol —— C10H14S3
    1-(4,5,6,7-Tetrahydro-1-benzothiophen-2-ylsulfanyl)ethanethiol
    —— 3-(Disulfanyl)-2-methylhexa-2,4-diene —— C7H12S2
    3-(Disulfanyl)-2-methylhexa-2,4-diene