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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(4-Aminophenyl)sulfanyl-2-(1,1,1-trifluoro-2-methylpropan-2-yl)aniline —— C16H17F3N2S
    4-(4-Aminophenyl)sulfanyl-2-(1,1,1-trifluoro-2-methylpropan-2-yl)aniline
    —— 4-Pentoxycyclohex-2-ene-1-thione —— C11H18OS
    4-Pentoxycyclohex-2-ene-1-thione
    —— (2Z)-3-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-phenylprop-2-enenitrile —— C19H11BrClNOS
    (2Z)-3-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-phenylprop-2-enenitrile
    —— 2-Oxoethyl thiohypobromite —— C2H3BrOS
    2-Oxoethyl thiohypobromite
    —— ethane;N-[(2-methylsulfanylphenyl)methyl]-N-(3-oxobutan-2-yl)acetamide —— C16H25NO2S
    ethane;N-[(2-methylsulfanylphenyl)methyl]-N-(3-oxobutan-2-yl)acetamide
    —— N-[(Z)-benzylideneamino]-2-(5-chloropyrimidin-2-yl)sulfanylacetamide —— C13H11ClN4OS
    N-[(Z)-benzylideneamino]-2-(5-chloropyrimidin-2-yl)sulfanylacetamide
    —— 1-Methylsulfanyl-4-(2,2,2-trifluoro-1-nitrosoethyl)benzene —— C9H8F3NOS
    1-Methylsulfanyl-4-(2,2,2-trifluoro-1-nitrosoethyl)benzene
    —— 3-benzyl-N-[(2-methoxypyridin-4-yl)methyl]-1-methyl-2,4,7-trioxo-8H-pyrimido[5,4-b][1,4]thiazine-6-carboxamide —— C22H21N5O5S
    3-benzyl-N-[(2-methoxypyridin-4-yl)methyl]-1-methyl-2,4,7-trioxo-8H-pyrimido[5,4-b][1,4]thiazine-6-carboxamide
    —— Methyl-[1-(2-methylcyclopropyl)ethyl]-methylidene-lambda4-sulfane —— C8H16S
    Methyl-[1-(2-methylcyclopropyl)ethyl]-methylidene-lambda4-sulfane
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(5-chlorothiophen-2-yl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C19H17ClN8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(5-chlorothiophen-2-yl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— N-(2-propylsulfanylphenyl)methanimine —— C10H13NS
    N-(2-propylsulfanylphenyl)methanimine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C20H17FN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 7,7-dimethyl-4-[5-[[6-(trifluoromethyl)-1H-benzimidazol-2-yl]sulfanyl]furan-2-yl]-4,4a,6,8-tetrahydro-1H-pyrazolo[3,4-b]quinolin-5-one —— C24H20F3N5O2S
    7,7-dimethyl-4-[5-[[6-(trifluoromethyl)-1H-benzimidazol-2-yl]sulfanyl]furan-2-yl]-4,4a,6,8-tetrahydro-1H-pyrazolo[3,4-b]quinolin-5-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-pyridin-3-ylmethylideneamino]triazole-4-carboxamide —— C19H17N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-pyridin-3-ylmethylideneamino]triazole-4-carboxamide
    —— 2-(4-Phenylsulfanylphenyl)thieno[2,3-d][1,3]oxazin-4-one —— C18H11NO2S2
    2-(4-Phenylsulfanylphenyl)thieno[2,3-d][1,3]oxazin-4-one
    —— 4-Methylidene-2-methylsulfanylhex-2-ene —— C8H14S
    4-Methylidene-2-methylsulfanylhex-2-ene
    —— 2-[4-(4-hydroxyphenyl)sulfanylphenyl]ethyl N-tert-butyl-N-[(2R)-2-(3-chlorophenyl)-2-hydroxyethyl]carbamate —— C27H30ClNO4S
    2-[4-(4-hydroxyphenyl)sulfanylphenyl]ethyl N-tert-butyl-N-[(2R)-2-(3-chlorophenyl)-2-hydroxyethyl]carbamate
    —— 2-Cyclohexa-2,4-dien-1-yl-2-(cyclohexen-1-yl)ethanethiol —— C14H20S
    2-Cyclohexa-2,4-dien-1-yl-2-(cyclohexen-1-yl)ethanethiol
    —— 6-[[6-amino-3-[2-(2-chlorophenyl)ethyl]-7H-purin-3-ium-8-yl]sulfanyl]-1,3-benzodioxole-5-carbonitrile —— C21H16ClN6O2S+
    6-[[6-amino-3-[2-(2-chlorophenyl)ethyl]-7H-purin-3-ium-8-yl]sulfanyl]-1,3-benzodioxole-5-carbonitrile
    —— 4-(2-methylsulfanylphenyl)-6-propyl-4,5-dihydro-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile —— C17H18N4S
    4-(2-methylsulfanylphenyl)-6-propyl-4,5-dihydro-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile
    —— 1-[C-(2-imino-3,3-dimethylbutyl)-N-(4-methylphenyl)carbonimidoyl]-3-[4-[6-imino-1-[3-(2-morpholin-4-ylethoxy)benzenecarboximidoyl]pyridin-3-yl]sulfanylphenyl]urea —— C39H46N8O3S
    1-[C-(2-imino-3,3-dimethylbutyl)-N-(4-methylphenyl)carbonimidoyl]-3-[4-[6-imino-1-[3-(2-morpholin-4-ylethoxy)benzenecarboximidoyl]pyridin-3-yl]sulfanylphenyl]urea
    —— 4-Ethylsulfanyl-1,1,1-trifluorobut-2-yne —— C6H7F3S
    4-Ethylsulfanyl-1,1,1-trifluorobut-2-yne
    —— N'-methyl-2-nitro-N-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)ethanimidamide —— C14H14N6O2S
    N'-methyl-2-nitro-N-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)ethanimidamide
    —— 2-(6-Methylsulfanyl-5-thiophen-3-ylpyridin-3-yl)-2-(1,3-oxazol-4-yl)acetic acid —— C15H12N2O3S2
    2-(6-Methylsulfanyl-5-thiophen-3-ylpyridin-3-yl)-2-(1,3-oxazol-4-yl)acetic acid
    —— N'-(3-methoxy-5-piperidin-1-ylperoxysulfanylpyridin-2-yl)methanesulfonohydrazide;N'-(4-methyl-2-phenylsulfanylphenyl)octane-1-sulfonohydrazide —— C33H50N6O7S4
    N'-(3-methoxy-5-piperidin-1-ylperoxysulfanylpyridin-2-yl)methanesulfonohydrazide;N'-(4-methyl-2-phenylsulfanylphenyl)octane-1-sulfonohydrazide
    —— N'-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide —— C12H13FN4S2
    N'-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide
    —— 5-(2-(4-Chloroanilino)vinyl)-3-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-4-isothiazolecarbonitrile —— C18H9Cl2F3N4S2
    5-(2-(4-Chloroanilino)vinyl)-3-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-4-isothiazolecarbonitrile
    —— 1-[1-[2-(Dimethylamino)ethyl]indol-5-yl]-3-(4-phenylsulfanylphenyl)urea —— C25H26N4OS
    1-[1-[2-(Dimethylamino)ethyl]indol-5-yl]-3-(4-phenylsulfanylphenyl)urea
    —— 4-Methyl-3-(4-methylphenyl)sulfanylbenzenethiol —— C14H14S2
    4-Methyl-3-(4-methylphenyl)sulfanylbenzenethiol
    —— (+/-)-Methyl [9-[(4-chlorophenyl)thio]-8-isopropyl-6-(1-methyl-1h-tetrazol-5-yl)-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl]acetate —— C25H26ClN5O2S
    (+/-)-Methyl [9-[(4-chlorophenyl)thio]-8-isopropyl-6-(1-methyl-1h-tetrazol-5-yl)-2,3-dihydro-1h-pyrrolo[1,2-a]indol-1-yl]acetate
    —— 2,2-Dimethyl-3-(5,6,6-trimethylcyclohex-3-en-1-yl)propanethioamide —— C14H25NS
    2,2-Dimethyl-3-(5,6,6-trimethylcyclohex-3-en-1-yl)propanethioamide
    —— N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-phenylacetamide —— C22H19N3O3S
    N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-phenylacetamide
    —— bis[2-(4-chlorophenyl)sulfanyl-5,5-dimethyl-3-oxocyclohexen-1-yl] (E)-but-2-enedioate —— C32H30Cl2O6S2
    bis[2-(4-chlorophenyl)sulfanyl-5,5-dimethyl-3-oxocyclohexen-1-yl] (E)-but-2-enedioate
    —— 1-(1-Methylcyclopropyl)oxy-3-methylsulfanylpentan-3-amine —— C10H21NOS
    1-(1-Methylcyclopropyl)oxy-3-methylsulfanylpentan-3-amine
    —— Ethylsulfinylmethylcyclohexane —— C9H18OS
    Ethylsulfinylmethylcyclohexane
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-phenylethylideneamino]triazole-4-carboxamide —— C20H17ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-phenylethylideneamino]triazole-4-carboxamide
    —— [(Z)-1-phenylnon-1-en-2-yl]sulfanylbenzene —— C21H26S
    [(Z)-1-phenylnon-1-en-2-yl]sulfanylbenzene
    —— (+/-)-2-[2-[[5-[[(2,3-difluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]propoxy]ethanol 333743-20-7 C18H20F2N4O3S2
    (+/-)-2-[2-[[5-[[(2,3-difluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]propoxy]ethanol
    —— (5E)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(3-methoxypropyl)-2-phenylimino-1,3-thiazolidin-4-one —— C24H21ClN2O3S2
    (5E)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(3-methoxypropyl)-2-phenylimino-1,3-thiazolidin-4-one
    —— 5-[[1-Methyl-2-[3-(trifluoromethyl)phenyl]sulfanylindol-3-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione —— C24H18F3N3O2S2
    5-[[1-Methyl-2-[3-(trifluoromethyl)phenyl]sulfanylindol-3-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 3-[2-[4-oxo-2-sulfanylidene-3-(2-sulfoethyl)-1,3-oxazolidin-5-ylidene]-4H-pyrrolo[3,2-d][1,3]thiazol-1-yl]propane-1-sulfonic acid —— C13H15N3O8S4
    3-[2-[4-oxo-2-sulfanylidene-3-(2-sulfoethyl)-1,3-oxazolidin-5-ylidene]-4H-pyrrolo[3,2-d][1,3]thiazol-1-yl]propane-1-sulfonic acid
    —— 3-[3-(Cyclohexylmethylsulfanyl)cyclohexa-1,3-dien-1-yl]prop-2-yn-1-amine —— C16H23NS
    3-[3-(Cyclohexylmethylsulfanyl)cyclohexa-1,3-dien-1-yl]prop-2-yn-1-amine
    —— [4-(4-Cyanophenyl)sulfanylphenyl] butanoate —— C17H15NO2S
    [4-(4-Cyanophenyl)sulfanylphenyl] butanoate
    —— 4-Ethyl-5-iminohexane-2-thione —— C8H15NS
    4-Ethyl-5-iminohexane-2-thione
    —— (2Z,5E)-6-(trifluoromethyl)nona-2,5-diene-4-thione —— C10H13F3S
    (2Z,5E)-6-(trifluoromethyl)nona-2,5-diene-4-thione
    —— [(Z)-3-carbamimidoylsulfanylprop-2-enyl] carbamimidothioate —— C5H10N4S2
    [(Z)-3-carbamimidoylsulfanylprop-2-enyl] carbamimidothioate
    —— [Tert-butyl-(3,3-dimethyl-2-oxobutyl)-methyl-lambda4-sulfanyl]-butylsulfonyloxidanium —— C15H33O4S2+
    [Tert-butyl-(3,3-dimethyl-2-oxobutyl)-methyl-lambda4-sulfanyl]-butylsulfonyloxidanium
    —— 4-Methyl-4-methylsulfanylpent-1-ene —— C7H14S
    4-Methyl-4-methylsulfanylpent-1-ene
    —— 4-[[4-(2,5-dihydro-1H-triazol-4-ylsulfanylmethyl)phenyl]methylsulfanyl]-2H-triazole —— C12H14N6S2
    4-[[4-(2,5-dihydro-1H-triazol-4-ylsulfanylmethyl)phenyl]methylsulfanyl]-2H-triazole
    —— Ethylsulfonyl(methylsulfonyl)methanimine —— C4H9NO4S2
    Ethylsulfonyl(methylsulfonyl)methanimine