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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(Prenylthio)ethanal —— C7H12OS
    2-(Prenylthio)ethanal
    —— 2-(Isopentylthio)ethanal —— C7H14OS
    2-(Isopentylthio)ethanal
    —— Methyl 2-methylbutyl disulfide —— C6H14S2
    Methyl 2-methylbutyl disulfide
    —— (2Z)-3-{4-bromo-5-[(4-methylphenyl)sulfanyl]furan-2-yl}-2-(3-chlorophenyl)prop-2-enenitrile —— C20H13BrClNOS
    (2Z)-3-{4-bromo-5-[(4-methylphenyl)sulfanyl]furan-2-yl}-2-(3-chlorophenyl)prop-2-enenitrile
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(3-chlorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C20H17ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(3-chlorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— Methyl-2-ethyl furyl sulfide —— C7H10OS
    Methyl-2-ethyl furyl sulfide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]furan-2-carboxamide —— C17H11N3O3S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]furan-2-carboxamide
    —— 4,4'-Thiobis(2-tert-butyl-1-hydroxy-5-methylphenyl), bistrifluoroacetate —— C26H28F6O4S
    4,4'-Thiobis(2-tert-butyl-1-hydroxy-5-methylphenyl), bistrifluoroacetate
    —— 3-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-5-(2-{[(4-methylbenzyl)oxy]imino}ethyl)-4-isothiazolecarbonitrile —— C20H14ClF3N4OS2
    3-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-5-(2-{[(4-methylbenzyl)oxy]imino}ethyl)-4-isothiazolecarbonitrile
    —— 3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine-1-carbothioamide —— C15H18N4S2
    3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine-1-carbothioamide
    —— 6-hydroxy-5,8-dioctyl-1,4-benzoxathiin-2(3H)-one —— C24H38O3S
    6-hydroxy-5,8-dioctyl-1,4-benzoxathiin-2(3H)-one
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-(4-chlorophenoxy)acetamide —— C22H15ClN4O4S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-(4-chlorophenoxy)acetamide
    —— 2-(2-Chloro-but-2-enylsulfanyl)-5-methoxy-pyrimidin-4-OL —— C9H11ClN2O2S
    2-(2-Chloro-but-2-enylsulfanyl)-5-methoxy-pyrimidin-4-OL
    —— ethyl (E)-2-cyano-3-(2-ethylsulfanyl-5-methylfuran-3-yl)prop-2-enoate —— C13H15NO3S
    ethyl (E)-2-cyano-3-(2-ethylsulfanyl-5-methylfuran-3-yl)prop-2-enoate
    —— N-[(Z)-(3-bromophenyl)methylideneamino]-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C21H20BrClN6OS
    N-[(Z)-(3-bromophenyl)methylideneamino]-2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-6-nitro-1,3-benzothiazol-2-amine —— C21H12N6O4S3
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-6-nitro-1,3-benzothiazol-2-amine
    —— 2-(4-methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-phenylhexylideneamino]acetamide —— C23H31N5O2S
    2-(4-methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-phenylhexylideneamino]acetamide
    —— 4,4'-Sulfanediylbis(2,6-dimethoxypyrimidine) —— C12H14N4O4S
    4,4'-Sulfanediylbis(2,6-dimethoxypyrimidine)
    —— methyl (2E)-2-cyano-3-[5-(phenylsulfanyl)-2-furyl]-2-propenoate —— C15H11NO3S
    methyl (2E)-2-cyano-3-[5-(phenylsulfanyl)-2-furyl]-2-propenoate
    —— 6-[2-[[(E)-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino]phenyl]-3-pentylsulfanyl-2H-1,2,4-triazin-5-one —— C25H26N6O2S
    6-[2-[[(E)-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino]phenyl]-3-pentylsulfanyl-2H-1,2,4-triazin-5-one
    —— 1,1'-Sulfanediylbis(heptafluorocyclobutane) —— C8F14S
    1,1'-Sulfanediylbis(heptafluorocyclobutane)
    —— (3Z)-3-[(5-nitropyridin-2-yl)hydrazinylidene]-1-benzothiophen-2-one —— C13H8N4O3S
    (3Z)-3-[(5-nitropyridin-2-yl)hydrazinylidene]-1-benzothiophen-2-one
    —— 2-[[5-[1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C21H22BrFN6OS
    2-[[5-[1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide —— C18H19BrN2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide
    —— 2,2,2-trifluoro-N-{2-[(1-methyl-1H-tetrazol-5-yl)sulfanyl]pyridin-3-yl}acetamide —— C9H7F3N6OS
    2,2,2-trifluoro-N-{2-[(1-methyl-1H-tetrazol-5-yl)sulfanyl]pyridin-3-yl}acetamide
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-methoxybenzamide —— C21H16ClN3O4S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-methoxybenzamide
    —— 2-methyl-N-[(Z)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide —— C22H17N3O2S
    2-methyl-N-[(Z)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— [(2-Methyl-4,6-dioxaheptyl)thio]benzene —— C12H18O2S
    [(2-Methyl-4,6-dioxaheptyl)thio]benzene
    —— (Z)-1-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C16H13N5O2S
    (Z)-1-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— (2Z,5Z)-3-(2-methoxyethyl)-5-[4-(methylsulfanyl)benzylidene]-2-(phenylimino)-1,3-thiazolidin-4-one —— C20H20N2O2S2
    (2Z,5Z)-3-(2-methoxyethyl)-5-[4-(methylsulfanyl)benzylidene]-2-(phenylimino)-1,3-thiazolidin-4-one
    —— N-(5-chloro-2-methylphenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C26H20ClN3O5S2
    N-(5-chloro-2-methylphenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— (E)-2-amino-3-[(4-methylsulfanylphenyl)methylideneamino]but-2-enedinitrile —— C12H10N4S
    (E)-2-amino-3-[(4-methylsulfanylphenyl)methylideneamino]but-2-enedinitrile
    —— Ethyl 5-(([3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl)methyl)-1,2-oxazole-3-carboxylate —— C16H17N3O4S
    Ethyl 5-(([3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl)methyl)-1,2-oxazole-3-carboxylate
    —— (2Z)-2-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)benzylidene]hydrazinecarboximidamide —— C10H10N8O2S
    (2Z)-2-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)benzylidene]hydrazinecarboximidamide
    —— (NZ)-N-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclooctylidene]hydroxylamine —— C11H18N4OS
    (NZ)-N-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]cyclooctylidene]hydroxylamine
    —— 4-methoxy-N-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]benzamide —— C25H19N3O5S3
    4-methoxy-N-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]benzamide
    —— 5,6-Dimethyl-2-(propylsulfanyl)pyridine-3,4-dicarbonitrile —— C12H13N3S
    5,6-Dimethyl-2-(propylsulfanyl)pyridine-3,4-dicarbonitrile
    —— (7E)-2-(2-ethoxyethylsulfanyl)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C22H20N2OS3
    (7E)-2-(2-ethoxyethylsulfanyl)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— (Z)-3-anilino-3-methylsulfanyl-2-phenylsulfanylprop-2-enenitrile —— C16H14N2S2
    (Z)-3-anilino-3-methylsulfanyl-2-phenylsulfanylprop-2-enenitrile
    —— (NZ)-N-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]cyclododecylidene]hydroxylamine —— C14H24N4OS2
    (NZ)-N-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]cyclododecylidene]hydroxylamine
    —— 5-bromo-2-hydroxy-N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide —— C21H16BrN3O4S
    5-bromo-2-hydroxy-N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide
    —— (NE)-N-[[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylidene]hydroxylamine —— C13H13N3O3S
    (NE)-N-[[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylidene]hydroxylamine
    —— 1-amino-3-[(Z)-3,3-dimethylbutan-2-ylideneamino]thiourea —— C7H16N4S
    1-amino-3-[(Z)-3,3-dimethylbutan-2-ylideneamino]thiourea
    —— 2-methoxy-5-methylsulfanyl-3-[(E)-2-nitroethenyl]thiophene —— C8H9NO3S2
    2-methoxy-5-methylsulfanyl-3-[(E)-2-nitroethenyl]thiophene
    —— 2,6-di-tert-butyl-4-({2-[(2E)-2-(2,4-dichlorobenzylidene)hydrazinyl]-3,5,6-trifluoropyridin-4-yl}sulfanyl)phenol —— C26H26Cl2F3N3OS
    2,6-di-tert-butyl-4-({2-[(2E)-2-(2,4-dichlorobenzylidene)hydrazinyl]-3,5,6-trifluoropyridin-4-yl}sulfanyl)phenol
    —— (E)-2-cyano-3-(2-ethylsulfanyl-5-methylfuran-3-yl)prop-2-enethioamide —— C11H12N2OS2
    (E)-2-cyano-3-(2-ethylsulfanyl-5-methylfuran-3-yl)prop-2-enethioamide
    —— propan-2-yl (2Z)-5-(4-methoxyphenyl)-7-methyl-3-oxo-2-[(5-phenylsulfanylfuran-2-yl)methylidene]-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C29H26N2O5S2
    propan-2-yl (2Z)-5-(4-methoxyphenyl)-7-methyl-3-oxo-2-[(5-phenylsulfanylfuran-2-yl)methylidene]-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(Z)-[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]-4,6-di(piperidin-1-yl)-1,3,5-triazin-2-amine —— C26H30ClN7S
    N-[(Z)-[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]-4,6-di(piperidin-1-yl)-1,3,5-triazin-2-amine
    —— Thiazole, 2-chloro-5-(methylthio)- —— C4H4ClNS2
    Thiazole, 2-chloro-5-(methylthio)-
    —— Bis(5-methyl-2-pyrimidinyl) sulfide —— C10H10N4S
    Bis(5-methyl-2-pyrimidinyl) sulfide