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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-{[5-(4-amino-1,2,5-oxadiazol-3-yl)-4-ethyl-4H-1,2,4-triazol-3-yl]sulfanyl}-N-cyclohexylacetamide —— C14H21N7O2S
    2-{[5-(4-amino-1,2,5-oxadiazol-3-yl)-4-ethyl-4H-1,2,4-triazol-3-yl]sulfanyl}-N-cyclohexylacetamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-(1H-pyrazol-4-ylmethyl)propanamide —— C13H14ClN3OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-(1H-pyrazol-4-ylmethyl)propanamide
    —— (2S)-N-(1H-pyrazol-4-ylmethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide —— C13H13N3OS
    (2S)-N-(1H-pyrazol-4-ylmethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— 4-({4-methyl-5-[(3-nitropyridin-2-yl)sulfanyl]-4H-1,2,4-triazol-3-yl}methyl)morpholine —— C13H16N6O3S
    4-({4-methyl-5-[(3-nitropyridin-2-yl)sulfanyl]-4H-1,2,4-triazol-3-yl}methyl)morpholine
    —— 3-[2-(5-chlorothiophen-2-yl)-2-oxoethyl]sulfanyl-6-thiophen-2-yl-4H-1,2,4-triazin-5-one —— C13H8ClN3O2S3
    3-[2-(5-chlorothiophen-2-yl)-2-oxoethyl]sulfanyl-6-thiophen-2-yl-4H-1,2,4-triazin-5-one
    —— Ethyl ({[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetyl)carbamate —— C8H11N3O3S3
    Ethyl ({[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetyl)carbamate
    —— 3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-6-thiophen-2-yl-4H-1,2,4-triazin-5-one —— C13H9N3O2S3
    3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-6-thiophen-2-yl-4H-1,2,4-triazin-5-one
    —— 3-[2-(5-bromothiophen-2-yl)-2-oxoethyl]sulfanyl-6-thiophen-2-yl-4H-1,2,4-triazin-5-one —— C13H8BrN3O2S3
    3-[2-(5-bromothiophen-2-yl)-2-oxoethyl]sulfanyl-6-thiophen-2-yl-4H-1,2,4-triazin-5-one
    —— 3-Nitro-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]pyridine —— C13H8N4O3S
    3-Nitro-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]pyridine
    —— 1-(5-Chlorothiophen-2-yl)-2-[(8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl)sulfanyl]ethanone —— C17H18ClN3OS2
    1-(5-Chlorothiophen-2-yl)-2-[(8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl)sulfanyl]ethanone
    —— 1-(5-Bromothiophen-2-yl)-2-[(8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl)sulfanyl]ethanone —— C17H18BrN3OS2
    1-(5-Bromothiophen-2-yl)-2-[(8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl)sulfanyl]ethanone
    —— 1-(5-Bromothiophen-2-yl)-2-(5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-ylsulfanyl)ethanone —— C13H12BrN3OS2
    1-(5-Bromothiophen-2-yl)-2-(5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-ylsulfanyl)ethanone
    —— 1-(5-Chlorothiophen-2-yl)-2-(5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-ylsulfanyl)ethanone —— C13H12ClN3OS2
    1-(5-Chlorothiophen-2-yl)-2-(5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-ylsulfanyl)ethanone
    —— 1-(5-Chlorothiophen-2-yl)-2-[(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C19H12ClN5OS2
    1-(5-Chlorothiophen-2-yl)-2-[(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— N-(2-phenylethyl)-2-(1H-1,2,3-triazol-5-ylsulfanyl)acetamide —— C12H14N4OS
    N-(2-phenylethyl)-2-(1H-1,2,3-triazol-5-ylsulfanyl)acetamide
    —— 2-[(4-amino-5-cyanopyrimidin-2-yl)sulfanyl]-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide —— C17H21N5OS
    2-[(4-amino-5-cyanopyrimidin-2-yl)sulfanyl]-N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)acetamide
    —— 2-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone —— C17H10ClN3O3S2
    2-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone
    —— 2-[[5,6-Bis(3-methylthiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-bromothiophen-2-yl)ethanone —— C19H14BrN3OS4
    2-[[5,6-Bis(3-methylthiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-bromothiophen-2-yl)ethanone
    —— 1-(5-Bromothiophen-2-yl)-2-[(5,6-dithiophen-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C17H10BrN3OS4
    1-(5-Bromothiophen-2-yl)-2-[(5,6-dithiophen-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 2-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-bromothiophen-2-yl)ethanone —— C17H10BrN3O3S2
    2-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-bromothiophen-2-yl)ethanone
    —— 2-[(5,6-Dithiophen-2-yl-1,2,4-triazin-3-yl)sulfanyl]-1-thiophen-2-ylethanone —— C17H11N3OS4
    2-[(5,6-Dithiophen-2-yl-1,2,4-triazin-3-yl)sulfanyl]-1-thiophen-2-ylethanone
    —— 2-[[5,6-Bis(3-methylthiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone —— C19H14ClN3OS4
    2-[[5,6-Bis(3-methylthiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-(5-chlorothiophen-2-yl)ethanone
    —— 1-(5-Chlorothiophen-2-yl)-2-[(5,6-dithiophen-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C17H10ClN3OS4
    1-(5-Chlorothiophen-2-yl)-2-[(5,6-dithiophen-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 2-[[5,6-Bis(3-methylthiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-thiophen-2-ylethanone —— C19H15N3OS4
    2-[[5,6-Bis(3-methylthiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-1-thiophen-2-ylethanone
    —— N-[4-(methylsulfanyl)benzyl]-1H-1,2,4-triazol-3-amine —— C10H12N4S
    N-[4-(methylsulfanyl)benzyl]-1H-1,2,4-triazol-3-amine
    —— N~1~,N~1~-Dicyclohexyl-2-[(5-ethyl-4H-1,2,4-triazol-3-YL)sulfanyl]acetamide —— C18H30N4OS
    N~1~,N~1~-Dicyclohexyl-2-[(5-ethyl-4H-1,2,4-triazol-3-YL)sulfanyl]acetamide
    —— Methyl 2-[(5-pyridin-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate 878707-85-8 C10H9N3O3S
    Methyl 2-[(5-pyridin-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— (2S)-2-(2,2,2-trifluoroethylamino)-2-[4-(trifluoromethylsulfanyl)phenyl]acetonitrile —— C11H8F6N2S
    (2S)-2-(2,2,2-trifluoroethylamino)-2-[4-(trifluoromethylsulfanyl)phenyl]acetonitrile
    —— (2R)-2-(cyclopentylamino)-2-[4-(trifluoromethylsulfanyl)phenyl]acetonitrile —— C14H15F3N2S
    (2R)-2-(cyclopentylamino)-2-[4-(trifluoromethylsulfanyl)phenyl]acetonitrile
    —— (2S)-2-(cyclohexylamino)-2-(4-methylsulfanylphenyl)acetonitrile —— C15H20N2S
    (2S)-2-(cyclohexylamino)-2-(4-methylsulfanylphenyl)acetonitrile
    —— (2S)-2-(cyclohexylamino)-2-[4-(trifluoromethylsulfanyl)phenyl]acetonitrile —— C15H17F3N2S
    (2S)-2-(cyclohexylamino)-2-[4-(trifluoromethylsulfanyl)phenyl]acetonitrile
    —— 2-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-methylpiperazin-1-yl)ethanone —— C15H17ClN4O2S
    2-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-methylpiperazin-1-yl)ethanone
    —— (2R)-2-(cyclopentylamino)-2-(4-methylsulfanylphenyl)acetonitrile —— C14H18N2S
    (2R)-2-(cyclopentylamino)-2-(4-methylsulfanylphenyl)acetonitrile
    —— 2-[5-[(E)-2-(1-methylpyridin-1-ium-4-yl)ethenyl]furan-2-yl]sulfanylpyrimidine —— C16H14N3OS+
    2-[5-[(E)-2-(1-methylpyridin-1-ium-4-yl)ethenyl]furan-2-yl]sulfanylpyrimidine
    —— (2S)-2-(cyclopentylamino)-2-(4-methylsulfanylphenyl)acetonitrile —— C14H18N2S
    (2S)-2-(cyclopentylamino)-2-(4-methylsulfanylphenyl)acetonitrile
    —— N-[(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]-4-methoxycyclohexane-1-carboxamide —— C19H26N4O2S
    N-[(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]-4-methoxycyclohexane-1-carboxamide
    —— N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]cyclopentanecarboxamide —— C13H22N4OS
    N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]cyclopentanecarboxamide
    —— N-[(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]cyclopentanecarboxamide —— C17H22N4OS
    N-[(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]cyclopentanecarboxamide
    —— N-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]-4-methoxycyclohexane-1-carboxamide —— C15H26N4O2S
    N-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]-4-methoxycyclohexane-1-carboxamide
    —— N-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]cyclopentanecarboxamide —— C11H18N4OS
    N-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]cyclopentanecarboxamide
    —— 1-Benzyl-3-[2-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]urea —— C14H19N5OS
    1-Benzyl-3-[2-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]urea
    —— 1-[(5-Methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)methyl]-3-propylurea —— C11H21N5OS
    1-[(5-Methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)methyl]-3-propylurea
    —— N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]-2-pyridin-2-ylacetamide —— C14H19N5OS
    N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]-2-pyridin-2-ylacetamide
    —— 3-[[2-[4-Methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methyl]pyridine —— C19H28N6S
    3-[[2-[4-Methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methyl]pyridine
    —— N-[2-[4-methyl-5-(pyridin-3-ylmethylsulfanyl)-1,2,4-triazol-3-yl]ethyl]methanesulfonamide —— C12H17N5O2S2
    N-[2-[4-methyl-5-(pyridin-3-ylmethylsulfanyl)-1,2,4-triazol-3-yl]ethyl]methanesulfonamide
    —— 1-Benzyl-3-[(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]urea —— C14H19N5OS
    1-Benzyl-3-[(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]urea
    —— 1-Benzyl-3-[(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)methyl]urea —— C15H21N5OS
    1-Benzyl-3-[(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)methyl]urea
    —— N-[2-[4-methyl-5-(pyridin-3-ylmethylsulfanyl)-1,2,4-triazol-3-yl]ethyl]oxolane-2-carboxamide —— C16H21N5O2S
    N-[2-[4-methyl-5-(pyridin-3-ylmethylsulfanyl)-1,2,4-triazol-3-yl]ethyl]oxolane-2-carboxamide
    —— N-[(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]cyclopentanecarboxamide —— C12H20N4OS
    N-[(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl]cyclopentanecarboxamide
    —— 3-[[5-[1-(2-Methylpropyl)piperidin-3-yl]-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine —— C20H31N5S
    3-[[5-[1-(2-Methylpropyl)piperidin-3-yl]-4-propan-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine