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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(6-chloropyridazin-3-yl)sulfanyl-N-(2-methylpropyl)propanamide —— C11H16ClN3OS
    (2S)-2-(6-chloropyridazin-3-yl)sulfanyl-N-(2-methylpropyl)propanamide
    —— (2R)-2-(6-chloropyridazin-3-yl)sulfanyl-N-(2-methylpropyl)propanamide —— C11H16ClN3OS
    (2R)-2-(6-chloropyridazin-3-yl)sulfanyl-N-(2-methylpropyl)propanamide
    —— 5-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-3-propyl-1,2,4-oxadiazole —— C17H26N6O2S
    5-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-3-propyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C9H13N5OS
    5-[(1R)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— 4-[5-[(6-chloropyridin-3-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C17H22ClN5O2S
    4-[5-[(6-chloropyridin-3-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H20N4O2S
    N-[(1S,2S)-2-methylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[2-(1-methylpyrazol-4-yl)ethyl]-3-(2-phenylsulfanylethyl)urea —— C15H20N4OS
    1-[2-(1-methylpyrazol-4-yl)ethyl]-3-(2-phenylsulfanylethyl)urea
    —— N-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-methylpropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H31N5O2S
    N-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-methylpropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-methyl-5-[(1R)-1-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C7H9N5OS
    3-methyl-5-[(1R)-1-(1H-1,2,4-triazol-5-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— N-[2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-methylpropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H31N5O2S
    N-[2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-methylpropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [(1S)-1-(3-pyridin-3-yl-1,2,4-oxadiazol-5-yl)ethyl] (2R)-2-phenylsulfanylpropanoate —— C18H17N3O3S
    [(1S)-1-(3-pyridin-3-yl-1,2,4-oxadiazol-5-yl)ethyl] (2R)-2-phenylsulfanylpropanoate
    —— (4S)-4-[(2R)-2-[(4'R,5'S)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]-2-methoxyethyl]-4-methylhex-5-en-3-one —— C23H36O2S2
    (4S)-4-[(2R)-2-[(4'R,5'S)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]-2-methoxyethyl]-4-methylhex-5-en-3-one
    —— [(4'S,5'R)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]methyl N-[(1S)-1-phenylethyl]carbamate —— C23H31NO2S2
    [(4'S,5'R)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]methyl N-[(1S)-1-phenylethyl]carbamate
    —— (2R,5S)-2-ethenyl-2-methyl-5-phenylsulfanyloxolane —— C13H16OS
    (2R,5S)-2-ethenyl-2-methyl-5-phenylsulfanyloxolane
    —— (1S,5R,6R,7E)-5,11,11-trimethyl-6-phenylsulfanylbicyclo[6.2.1]undec-7-en-3-one —— C20H26OS
    (1S,5R,6R,7E)-5,11,11-trimethyl-6-phenylsulfanylbicyclo[6.2.1]undec-7-en-3-one
    —— methyl (1R,3R,4R)-2-oxo-3-phenylsulfanyl-4-propan-2-ylcyclopentane-1-carboxylate —— C16H20O3S
    methyl (1R,3R,4R)-2-oxo-3-phenylsulfanyl-4-propan-2-ylcyclopentane-1-carboxylate
    —— (5S)-5-[2-(methoxymethoxy)ethyl]-2,2-bis[(E)-5-phenylsulfanylpent-3-enyl]cyclopentan-1-one —— C31H40O3S2
    (5S)-5-[2-(methoxymethoxy)ethyl]-2,2-bis[(E)-5-phenylsulfanylpent-3-enyl]cyclopentan-1-one
    —— [(4'R,5'S)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]methyl N-[(1S)-1-phenylethyl]carbamate —— C23H31NO2S2
    [(4'R,5'S)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]methyl N-[(1S)-1-phenylethyl]carbamate
    —— (5R)-5-[2-(methoxymethoxy)ethyl]-2,2-bis[(E)-5-phenylsulfanylpent-3-enyl]cyclopentan-1-one —— C31H40O3S2
    (5R)-5-[2-(methoxymethoxy)ethyl]-2,2-bis[(E)-5-phenylsulfanylpent-3-enyl]cyclopentan-1-one
    —— (6S,7S)-7-[(1R,3S)-3-(2-ethyl-1,3-dithiolan-2-yl)-1-methoxy-3-methylpent-4-enyl]-6,7-dimethyl-3,4,5,6-tetrahydro-2H-inden-1-one —— C23H36O2S2
    (6S,7S)-7-[(1R,3S)-3-(2-ethyl-1,3-dithiolan-2-yl)-1-methoxy-3-methylpent-4-enyl]-6,7-dimethyl-3,4,5,6-tetrahydro-2H-inden-1-one
    —— (E,2S,5S)-2-ethenyl-7-phenylsulfanyl-5-propan-2-ylhept-6-enenitrile —— C18H23NS
    (E,2S,5S)-2-ethenyl-7-phenylsulfanyl-5-propan-2-ylhept-6-enenitrile
    —— (2R)-2-[(E)-5-phenylsulfanylpent-3-enyl]cyclopentan-1-one —— C16H20OS
    (2R)-2-[(E)-5-phenylsulfanylpent-3-enyl]cyclopentan-1-one
    —— methyl (1S,3S,4R)-2-oxo-3-phenylsulfanyl-4-propan-2-ylcyclopentane-1-carboxylate —— C16H20O3S
    methyl (1S,3S,4R)-2-oxo-3-phenylsulfanyl-4-propan-2-ylcyclopentane-1-carboxylate
    —— (6R,7R)-7-[(1R,3S)-3-(2-ethyl-1,3-dithiolan-2-yl)-1-methoxy-3-methylpent-4-enyl]-6,7-dimethyl-3,4,5,6-tetrahydro-2H-inden-1-one —— C23H36O2S2
    (6R,7R)-7-[(1R,3S)-3-(2-ethyl-1,3-dithiolan-2-yl)-1-methoxy-3-methylpent-4-enyl]-6,7-dimethyl-3,4,5,6-tetrahydro-2H-inden-1-one
    —— (1R,3S)-1-[(4'S,5'S)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]-3-(1,3-dithiolan-2-yl)-3-methylpent-4-en-1-ol —— C22H34OS4
    (1R,3S)-1-[(4'S,5'S)-4',5'-dimethylspiro[1,3-dithiolane-2,3'-2,5,6,7-tetrahydro-1H-indene]-4'-yl]-3-(1,3-dithiolan-2-yl)-3-methylpent-4-en-1-ol
    —— (2R)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]butanenitrile —— C22H15N3OS3
    (2R)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]butanenitrile
    —— 2-[[5-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C12H17N5O2S3
    2-[[5-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— ethyl (2R)-2-(3-methylphenyl)sulfanylpropanoate —— C12H16O2S
    ethyl (2R)-2-(3-methylphenyl)sulfanylpropanoate
    —— (1S,2S)-2-(2-methylsulfonylethyl)cycloheptan-1-amine —— C10H21NO2S
    (1S,2S)-2-(2-methylsulfonylethyl)cycloheptan-1-amine
    —— (1R,2R)-2-(2-methylsulfonylethyl)cycloheptan-1-amine —— C10H21NO2S
    (1R,2R)-2-(2-methylsulfonylethyl)cycloheptan-1-amine
    —— (2S,3R)-N-ethyl-4,7-difluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H13F2NS
    (2S,3R)-N-ethyl-4,7-difluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3R)-2-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C9H11NS
    (2S,3R)-2-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3S)-4,7-difluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H11F2NS
    (2S,3S)-4,7-difluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2R,3R)-N,2,7-trimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H15NS
    (2R,3R)-N,2,7-trimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3S)-N-ethyl-7-fluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H14FNS
    (2S,3S)-N-ethyl-7-fluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3R)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H12FNS
    (2S,3R)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2R,3S)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H12FNS
    (2R,3S)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3S)-2,5-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H13NS
    (2S,3S)-2,5-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3R)-7-chloro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C9H10ClNS
    (2S,3R)-7-chloro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3S)-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H13NS
    (2S,3S)-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3R)-2,4,7-trimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H15NS
    (2S,3R)-2,4,7-trimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S)-2-(4-amino-2,6-difluorophenyl)sulfanylpropanoic acid —— C9H9F2NO2S
    (2S)-2-(4-amino-2,6-difluorophenyl)sulfanylpropanoic acid
    —— (2S,3S)-N-ethyl-4,7-difluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H13F2NS
    (2S,3S)-N-ethyl-4,7-difluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2R,3S)-5,7-difluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C9H9F2NS
    (2R,3S)-5,7-difluoro-2-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2R,3R)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H12FNS
    (2R,3R)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3R)-5-chloro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H12ClNS
    (2S,3R)-5-chloro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— ethyl (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoate —— C9H13NO2S2
    ethyl (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoate
    —— (2R,3R)-2,4,7-trimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H15NS
    (2R,3R)-2,4,7-trimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3S)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H12FNS
    (2S,3S)-5-fluoro-N,2-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (2S,3R)-N,2,5-trimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H15NS
    (2S,3R)-N,2,5-trimethyl-2,3-dihydro-1-benzothiophen-3-amine