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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2S)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]azanium —— C15H18NOS+
    [(2S)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]azanium
    —— 2-[2-(4-Chlorophenyl)sulfanyl-4-nitrophenyl]acetate —— C14H9ClNO4S-
    2-[2-(4-Chlorophenyl)sulfanyl-4-nitrophenyl]acetate
    —— 2-(4-Propan-2-ylsulfanylphenyl)acetate —— C11H13O2S-
    2-(4-Propan-2-ylsulfanylphenyl)acetate
    —— [2-(4-Methylphenyl)sulfanylphenyl]-(4-methylpiperazin-4-ium-1-yl)methanone —— C19H23N2OS+
    [2-(4-Methylphenyl)sulfanylphenyl]-(4-methylpiperazin-4-ium-1-yl)methanone
    —— {3-[(10S)-2,9-dithiatricyclo[9.4.0.0^{3,8}]pentadeca-1(15),3,5,7,11,13-hexaen-10-yl]propyl}dimethylazanium —— C18H22NS2+
    {3-[(10S)-2,9-dithiatricyclo[9.4.0.0^{3,8}]pentadeca-1(15),3,5,7,11,13-hexaen-10-yl]propyl}dimethylazanium
    —— Methyl-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azanium —— C18H18NS+
    Methyl-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azanium
    —— [(2R)-1-[2-(2-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-dimethylazanium —— C17H22NOS+
    [(2R)-1-[2-(2-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-dimethylazanium
    —— 1-[(2-Phenylsulfanylphenyl)methyl]pyrrolidin-1-ium —— C17H20NS+
    1-[(2-Phenylsulfanylphenyl)methyl]pyrrolidin-1-ium
    —— 2-[4-(4-Chlorophenyl)sulfanyl-2-methylsulfanylpyrimidin-5-yl]acetate —— C13H10ClN2O2S2-
    2-[4-(4-Chlorophenyl)sulfanyl-2-methylsulfanylpyrimidin-5-yl]acetate
    —— [2-(2,4-Dichlorophenyl)sulfanyl-4-fluorophenyl]methyl-dimethylazanium —— C15H15Cl2FNS+
    [2-(2,4-Dichlorophenyl)sulfanyl-4-fluorophenyl]methyl-dimethylazanium
    —— 4-[(6S)-8-methoxy-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C20H24NO2S+
    4-[(6S)-8-methoxy-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— N-[[2-(1,3-benzodioxol-5-ylsulfanyl)phenyl]methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine —— C17H18N3O2S+
    N-[[2-(1,3-benzodioxol-5-ylsulfanyl)phenyl]methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine
    —— 4-[(6S)-8-chloro-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C19H21ClNOS+
    4-[(6S)-8-chloro-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— 2-(5-Chloro-2-phenylsulfanylphenyl)acetate —— C14H10ClO2S-
    2-(5-Chloro-2-phenylsulfanylphenyl)acetate
    —— 3-(4-Chlorophenyl)sulfanylbenzoate —— C13H8ClO2S-
    3-(4-Chlorophenyl)sulfanylbenzoate
    —— 2-[5-Fluoro-2-(4-propan-2-ylphenyl)sulfanylphenyl]acetate —— C17H16FO2S-
    2-[5-Fluoro-2-(4-propan-2-ylphenyl)sulfanylphenyl]acetate
    —— 1-Methyl-4-[(2-phenylsulfanylphenyl)methyl]piperazine-1,4-diium —— C18H24N2S+2
    1-Methyl-4-[(2-phenylsulfanylphenyl)methyl]piperazine-1,4-diium
    —— [4-(3-Methoxyphenyl)sulfanylphenyl]methyl-dimethylazanium —— C16H20NOS+
    [4-(3-Methoxyphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— [2-(2-Bromophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17BrNS+
    [2-(2-Bromophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— [3-(2-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17ClNS+
    [3-(2-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— 2-[2-(2-Methylphenyl)sulfanylphenyl]acetate —— C15H13O2S-
    2-[2-(2-Methylphenyl)sulfanylphenyl]acetate
    —— [4-(3-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H18NOS+
    [4-(3-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— [2-(4-Hydroxyphenyl)sulfanylphenyl]methylazanium —— C13H14NOS+
    [2-(4-Hydroxyphenyl)sulfanylphenyl]methylazanium
    —— 2-Methylsulfanyl-5-phenylsulfanylpyrimidine-4-carboxylate —— C12H9N2O2S2-
    2-Methylsulfanyl-5-phenylsulfanylpyrimidine-4-carboxylate
    —— [2-(3-Hydroxyphenyl)sulfanylphenyl]methyl-methylazanium —— C14H16NOS+
    [2-(3-Hydroxyphenyl)sulfanylphenyl]methyl-methylazanium
    —— [2-(2-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H18NOS+
    [2-(2-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— dimethyl-[(3S)-3-(2-methylphenyl)sulfanyl-3-phenylpropyl]azanium —— C18H24NS+
    dimethyl-[(3S)-3-(2-methylphenyl)sulfanyl-3-phenylpropyl]azanium
    —— dimethyl-[(2S)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium —— C17H22NS+
    dimethyl-[(2S)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium
    —— [(3S)-3-[2-(4-chlorophenyl)sulfanylphenyl]-3-cyanopropyl]-dimethylazanium —— C18H20ClN2S+
    [(3S)-3-[2-(4-chlorophenyl)sulfanylphenyl]-3-cyanopropyl]-dimethylazanium
    —— [(2R)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium —— C15H18NS+
    [(2R)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium
    —— [2-(2,5-Dihydroxyphenyl)sulfanylphenyl]methyl-methylazanium —— C14H16NO2S+
    [2-(2,5-Dihydroxyphenyl)sulfanylphenyl]methyl-methylazanium
    —— 2-[2-(4-Chlorophenyl)sulfanylphenyl]acetate —— C14H10ClO2S-
    2-[2-(4-Chlorophenyl)sulfanylphenyl]acetate
    —— [2-(2,4-Dihydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H18NO2S+
    [2-(2,4-Dihydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— dimethyl-[(2R)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium —— C17H22NS+
    dimethyl-[(2R)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium
    —— N-[[2-(2-fluorophenyl)sulfanylphenyl]methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine —— C16H17FN3S+
    N-[[2-(2-fluorophenyl)sulfanylphenyl]methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine
    —— 1-[3-[(6S)-6H-benzo[c][1,5]benzoxathiepin-6-yl]propyl]piperidin-1-ium —— C21H26NOS+
    1-[3-[(6S)-6H-benzo[c][1,5]benzoxathiepin-6-yl]propyl]piperidin-1-ium
    —— [(2S)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium —— C15H18NS+
    [(2S)-1-(2-phenylsulfanylphenyl)propan-2-yl]azanium
    —— N-[(2-naphthalen-1-ylsulfanylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine —— C20H20N3S+
    N-[(2-naphthalen-1-ylsulfanylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine
    —— dimethyl-[(3R)-3-(2-methylphenyl)sulfanyl-3-phenylpropyl]azanium —— C18H24NS+
    dimethyl-[(3R)-3-(2-methylphenyl)sulfanyl-3-phenylpropyl]azanium
    —— 2-(3,5-Dichloro-2-phenylsulfanylphenyl)acetate —— C14H9Cl2O2S-
    2-(3,5-Dichloro-2-phenylsulfanylphenyl)acetate
    —— [2-(4-Hydroxyphenyl)sulfanylphenyl]methyl-methylazanium —— C14H16NOS+
    [2-(4-Hydroxyphenyl)sulfanylphenyl]methyl-methylazanium
    —— 2-(2-Phenylsulfanylphenyl)ethylazanium —— C14H16NS+
    2-(2-Phenylsulfanylphenyl)ethylazanium
    —— 2-[5-Nitro-2-(4-propan-2-ylphenyl)sulfanylphenyl]acetate —— C17H16NO4S-
    2-[5-Nitro-2-(4-propan-2-ylphenyl)sulfanylphenyl]acetate
    —— 2-[2-[3-(Trifluoromethyl)phenyl]sulfanylphenyl]acetate —— C15H10F3O2S-
    2-[2-[3-(Trifluoromethyl)phenyl]sulfanylphenyl]acetate
    —— 4-[(6S)-3-chloro-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C19H21ClNOS+
    4-[(6S)-3-chloro-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— Dimethyl-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azanium —— C19H20NS+
    Dimethyl-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azanium
    —— [2-(4-Methoxyphenyl)sulfanylphenyl]methyl-dipropylazanium —— C20H28NOS+
    [2-(4-Methoxyphenyl)sulfanylphenyl]methyl-dipropylazanium
    —— 2-[2-(2-Chlorophenyl)sulfanylphenyl]acetate —— C14H10ClO2S-
    2-[2-(2-Chlorophenyl)sulfanylphenyl]acetate
    —— [2-(2-Fluorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17FNS+
    [2-(2-Fluorophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— [2-(2-Methoxyphenyl)sulfanylphenyl]methyl-dipropylazanium —— C20H28NOS+
    [2-(2-Methoxyphenyl)sulfanylphenyl]methyl-dipropylazanium