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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R,5S)-5-[(1-methyltetrazol-5-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C8H12N4O3S
    (2R,5S)-5-[(1-methyltetrazol-5-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H13BrO3S
    (2R,5S)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid —— C12H14O3S
    (2R,5R)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(2,4-dimethylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C14H18O3S
    (2R,5S)-5-[(2,4-dimethylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C9H13N3O3S
    (2R,5S)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5R)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C9H12N2O4S
    (2S,5R)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5R)-5-[(1-methyltetrazol-5-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C8H12N4O3S
    (2S,5R)-5-[(1-methyltetrazol-5-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-[(5-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C11H14N2O3S
    (2R,5R)-5-[(5-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C9H13N3O3S
    (2S,5S)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(4-amino-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C8H12N4O3S
    (2R,5S)-5-[(4-amino-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— methyl 4-[[(2S)-2-(2-chlorophenyl)sulfanylpropanoyl]-methylamino]butanoate —— C15H20ClNO3S
    methyl 4-[[(2S)-2-(2-chlorophenyl)sulfanylpropanoyl]-methylamino]butanoate
    —— [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-[(5-methyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]acetate —— C17H21N3O4S2
    [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-[(5-methyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]acetate
    —— (1S,2R)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-(3-methylthiophen-2-yl)butan-2-amine —— C14H19N3S2
    (1S,2R)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-(3-methylthiophen-2-yl)butan-2-amine
    —— [(1R,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexyl]methanamine —— C12H19N3S
    [(1R,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexyl]methanamine
    —— (1S)-1-(2-aminophenyl)-2-(3-methylphenyl)sulfanylethanol —— C15H17NOS
    (1S)-1-(2-aminophenyl)-2-(3-methylphenyl)sulfanylethanol
    —— (1S,2R)-1-(4-bromothiophen-2-yl)-1-(4-methylpyrimidin-2-yl)sulfanylpropan-2-amine —— C12H14BrN3S2
    (1S,2R)-1-(4-bromothiophen-2-yl)-1-(4-methylpyrimidin-2-yl)sulfanylpropan-2-amine
    —— (2S)-2-(3-chlorophenyl)-2-(4-methylpyrimidin-2-yl)sulfanylethanamine —— C13H14ClN3S
    (2S)-2-(3-chlorophenyl)-2-(4-methylpyrimidin-2-yl)sulfanylethanamine
    —— (1S)-1-(2-aminophenyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanol —— C12H14N2OS2
    (1S)-1-(2-aminophenyl)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethanol
    —— (2S)-2-methyl-3-(4-methylpyrimidin-2-yl)sulfanylpropanoic acid —— C9H12N2O2S
    (2S)-2-methyl-3-(4-methylpyrimidin-2-yl)sulfanylpropanoic acid
    —— [(1S,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclopentyl]methanamine —— C11H17N3S
    [(1S,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclopentyl]methanamine
    —— (2R)-2-(4-methylpyrimidin-2-yl)sulfanyl-2-pyridin-2-ylpropanoic acid —— C13H13N3O2S
    (2R)-2-(4-methylpyrimidin-2-yl)sulfanyl-2-pyridin-2-ylpropanoic acid
    —— (1S)-1-[3-fluoro-4-(4-methylpyrimidin-2-yl)sulfanylphenyl]-N-methylethanamine —— C14H16FN3S
    (1S)-1-[3-fluoro-4-(4-methylpyrimidin-2-yl)sulfanylphenyl]-N-methylethanamine
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propyl]propanamide —— C18H27ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propyl]propanamide
    —— (1R)-1-(2-aminophenyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanol —— C10H12N4OS
    (1R)-1-(2-aminophenyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanol
    —— (1R)-1-(3-aminophenyl)-2-(5-methylpyrimidin-2-yl)sulfanylethanol —— C13H15N3OS
    (1R)-1-(3-aminophenyl)-2-(5-methylpyrimidin-2-yl)sulfanylethanol
    —— (2S)-1-(2-phenylsulfanylethyl)-2-[(2S)-pyrrolidin-2-yl]pyrrolidine —— C16H24N2S
    (2S)-1-(2-phenylsulfanylethyl)-2-[(2S)-pyrrolidin-2-yl]pyrrolidine
    —— [(1S,2S)-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexyl]methanamine —— C12H19N3S
    [(1S,2S)-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexyl]methanamine
    —— (2R)-2-(2-chlorophenyl)-2-(4-methylpyrimidin-2-yl)sulfanylethanamine —— C13H14ClN3S
    (2R)-2-(2-chlorophenyl)-2-(4-methylpyrimidin-2-yl)sulfanylethanamine
    —— [(1R,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclopentyl]methanamine —— C11H17N3S
    [(1R,2R)-2-(4-methylpyrimidin-2-yl)sulfanylcyclopentyl]methanamine
    —— (1R,2R)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-(5-methylthiophen-2-yl)propan-2-amine —— C13H17N3S2
    (1R,2R)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-(5-methylthiophen-2-yl)propan-2-amine
    —— (1R,2R)-1-(1-methylpyrazol-4-yl)-1-(4-methylpyrimidin-2-yl)sulfanylpropan-2-amine —— C12H17N5S
    (1R,2R)-1-(1-methylpyrazol-4-yl)-1-(4-methylpyrimidin-2-yl)sulfanylpropan-2-amine
    —— N'-hydroxy-6-(4-methylpyrimidin-2-yl)sulfanylpyridine-3-carboximidamide —— C11H11N5OS
    N'-hydroxy-6-(4-methylpyrimidin-2-yl)sulfanylpyridine-3-carboximidamide
    —— (1S)-1-(2-aminophenyl)-2-(4-bromophenyl)sulfanylethanol —— C14H14BrNOS
    (1S)-1-(2-aminophenyl)-2-(4-bromophenyl)sulfanylethanol
    —— (1R)-1-(3-aminophenyl)-2-(1-methylimidazol-2-yl)sulfanylethanol —— C12H15N3OS
    (1R)-1-(3-aminophenyl)-2-(1-methylimidazol-2-yl)sulfanylethanol
    —— 6-amino-2-[(2S)-2-(4-aminophenyl)-2-hydroxyethyl]sulfanyl-1H-pyrimidin-4-one —— C12H14N4O2S
    6-amino-2-[(2S)-2-(4-aminophenyl)-2-hydroxyethyl]sulfanyl-1H-pyrimidin-4-one
    —— (1S)-2-(4-methylpyrimidin-2-yl)sulfanyl-1-phenylethanol —— C13H14N2OS
    (1S)-2-(4-methylpyrimidin-2-yl)sulfanyl-1-phenylethanol
    —— (2S)-2-amino-3-(4-methylpyrimidin-2-yl)sulfanylpropanenitrile —— C8H10N4S
    (2S)-2-amino-3-(4-methylpyrimidin-2-yl)sulfanylpropanenitrile
    —— (2R)-2-methyl-3-(4-methylpyrimidin-2-yl)sulfanyl-2-(propan-2-ylamino)propanenitrile —— C12H18N4S
    (2R)-2-methyl-3-(4-methylpyrimidin-2-yl)sulfanyl-2-(propan-2-ylamino)propanenitrile
    —— (1R)-1-(4-aminophenyl)-2-(3,4-difluorophenyl)sulfanylethanol —— C14H13F2NOS
    (1R)-1-(4-aminophenyl)-2-(3,4-difluorophenyl)sulfanylethanol
    —— (2R)-2-(3-chlorophenyl)-2-(4-methylpyrimidin-2-yl)sulfanylethanamine —— C13H14ClN3S
    (2R)-2-(3-chlorophenyl)-2-(4-methylpyrimidin-2-yl)sulfanylethanamine
    —— (1S,2S)-1-(4-bromothiophen-2-yl)-1-(4-methylpyrimidin-2-yl)sulfanylbutan-2-amine —— C13H16BrN3S2
    (1S,2S)-1-(4-bromothiophen-2-yl)-1-(4-methylpyrimidin-2-yl)sulfanylbutan-2-amine
    —— (1R)-1-(4-aminophenyl)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanol —— C11H13N3OS2
    (1R)-1-(4-aminophenyl)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanol
    —— (1S)-1-(4-aminophenyl)-2-(2,5-difluorophenyl)sulfanylethanol —— C14H13F2NOS
    (1S)-1-(4-aminophenyl)-2-(2,5-difluorophenyl)sulfanylethanol
    —— (1R)-1-(2-aminophenyl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanol —— C11H13N3O2S
    (1R)-1-(2-aminophenyl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanol
    —— (1S,2S)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-(3-methylthiophen-2-yl)butan-2-amine —— C14H19N3S2
    (1S,2S)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-(3-methylthiophen-2-yl)butan-2-amine
    —— (1S)-1-(2-aminophenyl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanol —— C11H13N3O2S
    (1S)-1-(2-aminophenyl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanol
    —— (1R)-1-(4-aminophenyl)-2-(2,5-dimethylphenyl)sulfanylethanol —— C16H19NOS
    (1R)-1-(4-aminophenyl)-2-(2,5-dimethylphenyl)sulfanylethanol
    —— [(1R,2R,4S)-4-methyl-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexyl]methanamine —— C13H21N3S
    [(1R,2R,4S)-4-methyl-2-(4-methylpyrimidin-2-yl)sulfanylcyclohexyl]methanamine
    —— (1R,2S)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-thiophen-2-ylpropan-2-amine —— C12H15N3S2
    (1R,2S)-1-(4-methylpyrimidin-2-yl)sulfanyl-1-thiophen-2-ylpropan-2-amine
    —— (1R)-1-(3-aminophenyl)-2-(3,4-dimethylphenyl)sulfanylethanol —— C16H19NOS
    (1R)-1-(3-aminophenyl)-2-(3,4-dimethylphenyl)sulfanylethanol