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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-1-(4-acetylpiperazin-1-yl)-2-(4-hydroxyphenyl)sulfanylpropan-1-one —— C15H20N2O3S
    (2S)-1-(4-acetylpiperazin-1-yl)-2-(4-hydroxyphenyl)sulfanylpropan-1-one
    —— (2R)-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-2-propan-2-ylsulfonylpropanamide —— C15H23NO3S2
    (2R)-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-2-propan-2-ylsulfonylpropanamide
    —— 4-methyl-3-[2-[(1R,2S)-2-methylcyclohexyl]oxyethylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazole —— C13H20F3N3OS
    4-methyl-3-[2-[(1R,2S)-2-methylcyclohexyl]oxyethylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazole
    —— 4-methyl-3-[2-[(1S,2S)-2-methylcyclohexyl]oxyethylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazole —— C13H20F3N3OS
    4-methyl-3-[2-[(1S,2S)-2-methylcyclohexyl]oxyethylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazole
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C12H15F2NO2S
    2-(2,4-difluorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]acetamide
    —— 3-(2-fluorophenyl)sulfanyl-N-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]propanamide —— C14H16FN3O2S
    3-(2-fluorophenyl)sulfanyl-N-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]propanamide
    —— N'-(4-methylbenzylidene)-2-(2-pyridinylsulfanyl)acetohydrazide —— C15H15N3OS
    N'-(4-methylbenzylidene)-2-(2-pyridinylsulfanyl)acetohydrazide
    —— 3-(1-Benzylimidazol-2-yl)sulfanylpropanenitrile —— C13H13N3S
    3-(1-Benzylimidazol-2-yl)sulfanylpropanenitrile
    —— Substituted Cyclic Urea 33 —— C35H38N2O3S2
    Substituted Cyclic Urea 33
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C17H26N2OS
    (2R)-2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— N-ethyl-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide —— C14H20N2OS
    N-ethyl-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide
    —— N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide —— C15H22N2OS
    N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C17H26N2OS
    (2S)-2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— (2R)-N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C16H24N2OS
    (2R)-N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— 2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]acetamide —— C16H24N2OS
    2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]acetamide
    —— (2R)-N-ethyl-2-phenylsulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C15H22N2OS
    (2R)-N-ethyl-2-phenylsulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— (2S)-N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C16H24N2OS
    (2S)-N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— (2R)-N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C16H24N2OS
    (2R)-N-ethyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— N-methyl-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]acetamide —— C14H20N2OS
    N-methyl-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]acetamide
    —— 3-phenylsulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C16H24N2OS
    3-phenylsulfanyl-N-propan-2-yl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— N-methyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide —— C14H20N2OS
    N-methyl-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C17H26N2OS
    (2R)-2-(4-methylphenyl)sulfanyl-N-propan-2-yl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— N-methyl-3-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C15H22N2OS
    N-methyl-3-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— (2S)-N-ethyl-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C15H22N2OS
    (2S)-N-ethyl-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— (2R)-2-phenylsulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C13H18N2OS
    (2R)-2-phenylsulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C14H20N2OS
    (2R)-2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C14H20N2OS
    (2R)-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— 3-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C14H20N2OS
    3-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— (2S)-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C13H18N2OS
    (2S)-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— 2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide —— C13H18N2OS
    2-(4-methylphenyl)sulfanyl-N-[(3R)-pyrrolidin-3-yl]acetamide
    —— 3-(1-methyltetrazol-5-yl)sulfanyl-N-[(1S)-3-methyl-1-thiophen-2-ylbutyl]propanamide —— C14H21N5OS2
    3-(1-methyltetrazol-5-yl)sulfanyl-N-[(1S)-3-methyl-1-thiophen-2-ylbutyl]propanamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-(5-methylpyridin-2-yl)sulfanylacetamide —— C12H16N2O3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-(5-methylpyridin-2-yl)sulfanylacetamide
    —— 2-Amino-5-thio-substituted thiazole 38 —— C14H20N4O2S2
    2-Amino-5-thio-substituted thiazole 38
    —— 2-Amino-5-thio-substituted thiazole 34 —— C15H21N3O3S2
    2-Amino-5-thio-substituted thiazole 34
    —— 2-Amino-5-thio-substituted thiazole 37 —— C16H23N3O2S2
    2-Amino-5-thio-substituted thiazole 37
    —— (2R)-N-[(1S)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H22N4OS2
    (2R)-N-[(1S)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-Arylamino-pyrimidine deriv. 9c —— C18H23N5O2S
    2-Arylamino-pyrimidine deriv. 9c
    —— ethyl (2S)-2-[[4-(2-amino-2-oxoethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C13H16N4O3S2
    ethyl (2S)-2-[[4-(2-amino-2-oxoethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— (2S)-2-(3-chloropyridin-2-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide —— C16H18ClN3OS
    (2S)-2-(3-chloropyridin-2-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N,3-trimethylbutanamide —— C17H23N3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N,3-trimethylbutanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N,3-trimethylbutanamide —— C17H23N3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N,3-trimethylbutanamide
    —— 3-methylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C12H20N4OS
    3-methylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— 6,7-Dimethoxyquinoline deriv. 9 —— C18H12Cl2N2O2S
    6,7-Dimethoxyquinoline deriv. 9
    —— N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-pyridin-4-ylsulfanylacetamide —— C17H21N3OS
    N-[(2R)-2-(dimethylamino)-2-phenylethyl]-2-pyridin-4-ylsulfanylacetamide
    —— (2R)-2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-3-methylbutanamide —— C13H17N3OS
    (2R)-2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-3-methylbutanamide
    —— (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-methylbutanamide —— C15H20N4OS2
    (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-methylbutanamide
    —— (3S,5R)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C9H13N3O2S
    (3S,5R)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— (3R,5R)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C9H13N3O2S
    (3R,5R)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— methyl 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H26N4O2S
    methyl 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (1R)-1-[4-butyl-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C19H30N4S
    (1R)-1-[4-butyl-5-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine