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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,4,6-tris(((2-vinyloxy)ethyl)thio)pyrimidine —— C16H22N2O3S3
    2,4,6-tris(((2-vinyloxy)ethyl)thio)pyrimidine
    —— carbamothioic S-acid;N,N-dimethylmethanamine;propylcarbamothioic S-acid —— C8H21N3O2S2
    carbamothioic S-acid;N,N-dimethylmethanamine;propylcarbamothioic S-acid
    —— N-methoxy-3-[2-[3-(methoxyamino)-3-oxopropyl]sulfanylpyrimidin-4-yl]sulfanylpropanamide —— C12H18N4O4S2
    N-methoxy-3-[2-[3-(methoxyamino)-3-oxopropyl]sulfanylpyrimidin-4-yl]sulfanylpropanamide
    —— 2,4,6-tris(((3-vinyloxy)butyl)thio)pyrimidine —— C22H34N2O3S3
    2,4,6-tris(((3-vinyloxy)butyl)thio)pyrimidine
    —— 2,4,6-Tris(ethenoxymethylsulfanyl)pyrimidine —— C13H16N2O3S3
    2,4,6-Tris(ethenoxymethylsulfanyl)pyrimidine
    —— 2,3-Bis(ethenoxymethylsulfanyl)pyridine —— C11H13NO2S2
    2,3-Bis(ethenoxymethylsulfanyl)pyridine
    —— 2,6-bis((2-(vinyloxy)ethyl)thio)pyridine —— C13H17NO2S2
    2,6-bis((2-(vinyloxy)ethyl)thio)pyridine
    —— carbamothioic S-acid;N,N-dimethylmethanamine;hexylcarbamothioic S-acid —— C11H27N3O2S2
    carbamothioic S-acid;N,N-dimethylmethanamine;hexylcarbamothioic S-acid
    —— N-[2-[6-amino-8-[[6-(dimethylamino)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]ethyl]-2-methylpropanamide —— C20H25N7O3S
    N-[2-[6-amino-8-[[6-(dimethylamino)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]ethyl]-2-methylpropanamide
    —— N-methoxy-6-[2-[6-(methoxyamino)-6-oxohexyl]sulfanylpyridin-4-yl]sulfanylhexanamide —— C19H31N3O4S2
    N-methoxy-6-[2-[6-(methoxyamino)-6-oxohexyl]sulfanylpyridin-4-yl]sulfanylhexanamide
    —— 3-[6-amino-8-[[6-(5-methylfuran-2-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]-N-cyclopropylpropanamide —— C23H22N6O4S
    3-[6-amino-8-[[6-(5-methylfuran-2-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]-N-cyclopropylpropanamide
    —— N-[2-[6-amino-8-[[6-(5-methylfuran-2-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]ethyl]cyclopropanecarboxamide —— C23H22N6O4S
    N-[2-[6-amino-8-[[6-(5-methylfuran-2-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]ethyl]cyclopropanecarboxamide
    —— (3-Methylcyclopentyl)methylsulfanylbenzene —— C13H18S
    (3-Methylcyclopentyl)methylsulfanylbenzene
    —— N-methoxy-6-[6-[6-(methoxyamino)-6-oxohexyl]sulfanylpyrimidin-4-yl]sulfanylhexanamide —— C18H30N4O4S2
    N-methoxy-6-[6-[6-(methoxyamino)-6-oxohexyl]sulfanylpyrimidin-4-yl]sulfanylhexanamide
    —— 3-[6-Amino-8-[(6-ethynyl-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]propane-1-sulfonamide —— C17H16N6O4S2
    3-[6-Amino-8-[(6-ethynyl-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]propane-1-sulfonamide
    —— Triethyl-[(3-methylcyclopentyl)methyl]-lambda4-sulfane —— C13H28S
    Triethyl-[(3-methylcyclopentyl)methyl]-lambda4-sulfane
    —— 3-[6-amino-8-[(6-ethynyl-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]-N-methylpropane-1-sulfonamide —— C18H18N6O4S2
    3-[6-amino-8-[(6-ethynyl-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]-N-methylpropane-1-sulfonamide
    —— N'-[(Z)-{4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-nitrophenyl}methylidene]-3-nitrobenzohydrazide —— C18H14N6O5S
    N'-[(Z)-{4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-nitrophenyl}methylidene]-3-nitrobenzohydrazide
    —— (E)-1-amino-2-(prop-1-enylideneamino)but-1-ene-1-thiol —— C7H12N2S
    (E)-1-amino-2-(prop-1-enylideneamino)but-1-ene-1-thiol
    —— N-[(Z)-(3-bromophenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H12BrN3OS
    N-[(Z)-(3-bromophenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— 3-(1-benzyl-5-benzylsulfanylpyrazol-4-yl)-4-[(4-bromophenyl)methyl]-2H-tetrazole —— C25H23BrN6S
    3-(1-benzyl-5-benzylsulfanylpyrazol-4-yl)-4-[(4-bromophenyl)methyl]-2H-tetrazole
    —— 5-[5-benzylsulfanyl-1-(2-methylpropyl)pyrazol-4-yl]-2H-tetrazole —— C15H18N6S
    5-[5-benzylsulfanyl-1-(2-methylpropyl)pyrazol-4-yl]-2H-tetrazole
    —— 5-(5-Benzylsulfanyl-1-ethylpyrazol-4-yl)-1-[(3-methylphenyl)methyl]-2,3-dihydrotetrazole —— C21H24N6S
    5-(5-Benzylsulfanyl-1-ethylpyrazol-4-yl)-1-[(3-methylphenyl)methyl]-2,3-dihydrotetrazole
    —— 3-[(Z)-hydroxyiminomethyl]-2-phenylsulfanylpyrido[1,2-a]pyrimidin-4-one —— C15H11N3O2S
    3-[(Z)-hydroxyiminomethyl]-2-phenylsulfanylpyrido[1,2-a]pyrimidin-4-one
    —— Cyclohexyl(2-methylsulfonylethoxy)carbamic acid —— C10H19NO5S
    Cyclohexyl(2-methylsulfonylethoxy)carbamic acid
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(2-fluorophenyl)methylideneamino]acetamide —— C18H15FN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(2-fluorophenyl)methylideneamino]acetamide
    —— N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-(5-oxo-1,2-dihydropyrazol-3-yl)acetamide —— C13H14N4O2S
    N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-(5-oxo-1,2-dihydropyrazol-3-yl)acetamide
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-fluorophenyl)methylideneamino]acetamide —— C18H15FN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-fluorophenyl)methylideneamino]acetamide
    —— N-[(Z)-benzylideneamino]-2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C18H16N4OS3
    N-[(Z)-benzylideneamino]-2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-3-[2-fluoro-4-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol —— C13H17FN2O2S
    (2R)-3-[2-fluoro-4-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol
    —— (2S)-3-[2-fluoro-4-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol —— C13H17FN2O2S
    (2S)-3-[2-fluoro-4-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol
    —— (2R)-3-[3-fluoro-2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol —— C13H17FN2O2S
    (2R)-3-[3-fluoro-2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol
    —— (2S)-3-[3-fluoro-2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol —— C13H17FN2O2S
    (2S)-3-[3-fluoro-2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol
    —— N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C15H14ClFN4OS
    N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (2E,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-2-methylpropylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C15H17F2N3OS2
    (2E,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-2-methylpropylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2Z,5S)-2-[(Z)-benzylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one —— C18H15F2N3OS2
    (2Z,5S)-2-[(Z)-benzylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one
    —— (2E,5R)-2-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one —— C18H19F2N3OS2
    (2E,5R)-2-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one
    —— (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-[4-(dimethylamino)phenyl]methylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C20H20F2N4OS2
    (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-[4-(dimethylamino)phenyl]methylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2E,5S)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-4-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C17H14F2N4OS2
    (2E,5S)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-4-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-(4-fluorophenyl)methylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C18H14F3N3OS2
    (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-(4-fluorophenyl)methylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2E,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C17H14F2N4OS2
    (2E,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2Z,5S)-5-[[3-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C17H14F2N4OS2
    (2Z,5S)-5-[[3-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2S)-3-[2-(4,5-dihydro-1H-imidazol-2-yl)-3-fluorophenyl]sulfanylpropane-1,2-diol —— C12H15FN2O2S
    (2S)-3-[2-(4,5-dihydro-1H-imidazol-2-yl)-3-fluorophenyl]sulfanylpropane-1,2-diol
    —— (2R)-3-[2-(4,5-dihydro-1H-imidazol-2-yl)-3-fluorophenyl]sulfanylpropane-1,2-diol —— C12H15FN2O2S
    (2R)-3-[2-(4,5-dihydro-1H-imidazol-2-yl)-3-fluorophenyl]sulfanylpropane-1,2-diol
    —— (2S)-3-[4-(4,5-dihydro-1H-imidazol-2-yl)-2-fluorophenyl]sulfanylpropane-1,2-diol —— C12H15FN2O2S
    (2S)-3-[4-(4,5-dihydro-1H-imidazol-2-yl)-2-fluorophenyl]sulfanylpropane-1,2-diol
    —— (2R)-3-[4-(4,5-dihydro-1H-imidazol-2-yl)-2-fluorophenyl]sulfanylpropane-1,2-diol —— C12H15FN2O2S
    (2R)-3-[4-(4,5-dihydro-1H-imidazol-2-yl)-2-fluorophenyl]sulfanylpropane-1,2-diol
    —— (2S)-3-[3-(1,4,5,6-tetrahydropyrimidin-2-yl)pyridin-2-yl]sulfanylpropane-1,2-diol —— C12H17N3O2S
    (2S)-3-[3-(1,4,5,6-tetrahydropyrimidin-2-yl)pyridin-2-yl]sulfanylpropane-1,2-diol
    —— (2R)-3-[2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol —— C13H18N2O2S
    (2R)-3-[2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol
    —— (2S)-3-[2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol —— C13H18N2O2S
    (2S)-3-[2-(1,4,5,6-tetrahydropyrimidin-2-yl)phenyl]sulfanylpropane-1,2-diol
    —— (2R)-3-[3-(1,4,5,6-tetrahydropyrimidin-2-yl)pyridin-2-yl]sulfanylpropane-1,2-diol —— C12H17N3O2S
    (2R)-3-[3-(1,4,5,6-tetrahydropyrimidin-2-yl)pyridin-2-yl]sulfanylpropane-1,2-diol