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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3S,7R)-12-ethyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C9H14N4S
    (3S,7R)-12-ethyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (6R)-3-butyl-6-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H20N4S
    (6R)-3-butyl-6-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R)-6-tert-butyl-3-pentan-3-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C13H24N4S
    (6R)-6-tert-butyl-3-pentan-3-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (5aR,9aS)-3-ethyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C10H16N4S
    (5aR,9aS)-3-ethyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (6R)-6-tert-butyl-3-[(4-fluorophenyl)methyl]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H19FN4S
    (6R)-6-tert-butyl-3-[(4-fluorophenyl)methyl]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (5aS,9aS)-3-methyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C9H14N4S
    (5aS,9aS)-3-methyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (3R,7R)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C9H14N4OS
    (3R,7R)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3R,7S)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C7H10N4S
    (3R,7S)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3R,7R)-12-cyclohexyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C13H20N4S
    (3R,7R)-12-cyclohexyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (5aR,9aS)-3-(cyclohexylmethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C15H24N4S
    (5aR,9aS)-3-(cyclohexylmethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— 4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-morpholin-4-ylbutan-1-one —— C23H24N4O2S
    4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-morpholin-4-ylbutan-1-one
    —— (6S,7S)-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C6H10N4S
    (6S,7S)-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(4-Chlorophenyl)-6-phenyl-5-phenylsulfanyl-1,2,4-triazine —— C21H14ClN3S
    3-(4-Chlorophenyl)-6-phenyl-5-phenylsulfanyl-1,2,4-triazine
    —— (5aR,9aS)-3-(trifluoromethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C9H11F3N4S
    (5aR,9aS)-3-(trifluoromethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (6S)-6-methyl-3-(thiophen-2-ylmethyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C10H12N4S2
    (6S)-6-methyl-3-(thiophen-2-ylmethyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6R,7R)-3-[(4-fluorophenyl)methyl]-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C13H15FN4S
    (6R,7R)-3-[(4-fluorophenyl)methyl]-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S)-6-tert-butyl-3-ethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C10H18N4S
    (6S)-6-tert-butyl-3-ethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (3R,7S)-12-(cyclohexylmethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C14H22N4S
    (3R,7S)-12-(cyclohexylmethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (6R,7R)-6,7-dimethyl-3-(2-phenylethyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C14H18N4S
    (6R,7R)-6,7-dimethyl-3-(2-phenylethyl)-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(2-Chlorophenyl)-6-(4-chlorophenyl)-5-phenylsulfanyl-1,2,4-triazine —— C21H13Cl2N3S
    3-(2-Chlorophenyl)-6-(4-chlorophenyl)-5-phenylsulfanyl-1,2,4-triazine
    —— (3S,7S)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C9H14N4OS
    (3S,7S)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (5aS,9aS)-3-(thiophen-2-ylmethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C13H16N4S2
    (5aS,9aS)-3-(thiophen-2-ylmethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (5aS,9aR)-3-(methoxymethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C10H16N4OS
    (5aS,9aR)-3-(methoxymethyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (6S)-3-benzyl-6-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C14H18N4S
    (6S)-3-benzyl-6-propan-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(3-methylbutyl)acetamide —— C22H24N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(3-methylbutyl)acetamide
    —— (3S,7R)-12-(2-methylpropyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C11H18N4S
    (3S,7R)-12-(2-methylpropyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (6R)-6-tert-butyl-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C9H16N4S
    (6R)-6-tert-butyl-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S,7R)-3-(furan-2-yl)-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C10H12N4OS
    (6S,7R)-3-(furan-2-yl)-6,7-dimethyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-phenyl-5-phenylthio-6-(4-tolyl)-1,2,4-triazine —— C22H17N3S
    3-phenyl-5-phenylthio-6-(4-tolyl)-1,2,4-triazine
    —— (6S)-6-tert-butyl-3-thiophen-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C12H16N4S2
    (6S)-6-tert-butyl-3-thiophen-2-yl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 5-[(2,4-Dinitrophenyl)sulfanyl]-N-methyl-1H-1,2,3-triazole-4-carboxamide —— C10H8N6O5S
    5-[(2,4-Dinitrophenyl)sulfanyl]-N-methyl-1H-1,2,3-triazole-4-carboxamide
    —— (3R,7S)-12-tert-butyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C11H18N4S
    (3R,7S)-12-tert-butyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3S,7R)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C9H14N4OS
    (3S,7R)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (5aR,9aR)-3-propyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C11H18N4S
    (5aR,9aR)-3-propyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (3S,7S)-12-(2-methoxyethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C10H16N4OS
    (3S,7S)-12-(2-methoxyethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3R,7R)-12-butyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C11H18N4S
    (3R,7R)-12-butyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (5aR,9aR)-3-(2-methylpropyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C12H20N4S
    (5aR,9aR)-3-(2-methylpropyl)-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (5aS,9aR)-3-butyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C12H20N4S
    (5aS,9aR)-3-butyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (6S)-6-tert-butyl-3-[(2R)-oxolan-2-yl]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C12H20N4OS
    (6S)-6-tert-butyl-3-[(2R)-oxolan-2-yl]-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (3S,7R)-12-thiophen-2-yl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C11H12N4S2
    (3S,7R)-12-thiophen-2-yl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3R,7S)-12-ethyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C9H14N4S
    (3R,7S)-12-ethyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3R,7S)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C9H14N4OS
    (3R,7S)-12-(methoxymethyl)-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (5aR,9aS)-3-propyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C11H18N4S
    (5aR,9aS)-3-propyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (3S,7S)-12-pentan-3-yl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C12H20N4S
    (3S,7S)-12-pentan-3-yl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— N-[(2S)-butan-2-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C21H22N4OS
    N-[(2S)-butan-2-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— (5aS,9aS)-3-ethyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine —— C10H16N4S
    (5aS,9aS)-3-ethyl-5a,6,7,8,9,9a-hexahydro-5H-[1,2,4]triazolo[4,3-b][4,1,2]benzothiadiazine
    —— (3R,7R)-12-methyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C8H12N4S
    (3R,7R)-12-methyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— (3S,7S)-12-butyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene —— C11H18N4S
    (3S,7S)-12-butyl-8-thia-1,2,10,11-tetrazatricyclo[7.3.0.03,7]dodeca-9,11-diene
    —— N-[(2R)-butan-2-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C21H22N4OS
    N-[(2R)-butan-2-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— (6S)-6-tert-butyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C8H14N4S
    (6S)-6-tert-butyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine