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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[(S)-cyclopentylmethylsulfinyl]propanoic acid —— C9H16O3S
    (2S)-2-[(S)-cyclopentylmethylsulfinyl]propanoic acid
    —— 1-(2-phenylsulfanylethyl)-3-[(3R)-4,4,4-trifluoro-3-hydroxy-3-(1-methylimidazol-2-yl)butyl]urea —— C17H21F3N4O2S
    1-(2-phenylsulfanylethyl)-3-[(3R)-4,4,4-trifluoro-3-hydroxy-3-(1-methylimidazol-2-yl)butyl]urea
    —— (2R)-N-(cyclobutylmethyl)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide —— C10H15N3OS2
    (2R)-N-(cyclobutylmethyl)-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide
    —— (2S)-2-(cyclopentylmethylsulfonyl)propanoic acid —— C9H16O4S
    (2S)-2-(cyclopentylmethylsulfonyl)propanoic acid
    —— (2R)-2-(4-bromophenyl)sulfanyl-N'-pyrimidin-2-ylpropanehydrazide —— C13H13BrN4OS
    (2R)-2-(4-bromophenyl)sulfanyl-N'-pyrimidin-2-ylpropanehydrazide
    —— 5-[(1S)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-N-propyl-1,3,4-thiadiazol-2-amine —— C11H17N5OS2
    5-[(1S)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-N-propyl-1,3,4-thiadiazol-2-amine
    —— 3-[[(2S)-oxolan-2-yl]methylsulfanyl]-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole —— C12H15N3OS2
    3-[[(2S)-oxolan-2-yl]methylsulfanyl]-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole
    —— 2-(1,3,4-thiadiazol-2-ylsulfanyl)-N-[(1S)-1-thiophen-2-ylpropyl]acetamide —— C11H13N3OS3
    2-(1,3,4-thiadiazol-2-ylsulfanyl)-N-[(1S)-1-thiophen-2-ylpropyl]acetamide
    —— 2-[[5-[(3R)-oxolan-3-yl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C8H11N3O3S
    2-[[5-[(3R)-oxolan-3-yl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N'-pyrimidin-2-ylpropanehydrazide —— C13H13ClN4OS
    (2R)-2-(2-chlorophenyl)sulfanyl-N'-pyrimidin-2-ylpropanehydrazide
    —— 2-[[5-[(Z)-2-(furan-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-(furan-2-yl)ethyl]acetamide —— C16H16N4O3S
    2-[[5-[(Z)-2-(furan-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-(furan-2-yl)ethyl]acetamide
    —— (2S)-N,N-dimethyl-2-[[5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C14H18N4O2S
    (2S)-N,N-dimethyl-2-[[5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one —— C15H21ClN2OS
    (2S)-2-(2-chlorophenyl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— (1S)-2-(2-amino-6-chloropyrimidin-4-yl)sulfanyl-1-phenylethanol —— C12H12ClN3OS
    (1S)-2-(2-amino-6-chloropyrimidin-4-yl)sulfanyl-1-phenylethanol
    —— (2S)-2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(2S)-pentan-2-yl]propanamide —— C14H25N3O2S
    (2S)-2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(2S)-pentan-2-yl]propanamide
    —— (2S)-2-imidazol-1-yl-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]propanamide —— C15H19N3OS
    (2S)-2-imidazol-1-yl-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]propanamide
    —— 2-[[5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanol —— C11H13N3O2S
    2-[[5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanol
    —— 3-(2-methoxyethylsulfanyl)-5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazole —— C12H15N3O2S
    3-(2-methoxyethylsulfanyl)-5-[(Z)-2-(5-methylfuran-2-yl)ethenyl]-1H-1,2,4-triazole
    —— (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-cyclohexylpropanamide —— C18H23N3O2S
    (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-cyclohexylpropanamide
    —— methyl (2S)-2-(3,4-difluorophenyl)sulfanylpropanoate —— C10H10F2O2S
    methyl (2S)-2-(3,4-difluorophenyl)sulfanylpropanoate
    —— (2R)-2-(3-chloropyridin-2-yl)sulfanyl-N-prop-2-enylpropanamide —— C11H13ClN2OS
    (2R)-2-(3-chloropyridin-2-yl)sulfanyl-N-prop-2-enylpropanamide
    —— (3S,5R)-5-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]oxolan-2-one —— C11H10N2O3S2
    (3S,5R)-5-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]oxolan-2-one
    —— (3R,5S)-5-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]oxolan-2-one —— C11H10N2O3S2
    (3R,5S)-5-methyl-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]oxolan-2-one
    —— N-[(2R)-3-(3,5-dimethylpyrazol-1-yl)-2-methylpropyl]-3-(4-methylphenyl)sulfanylpropanamide —— C19H27N3OS
    N-[(2R)-3-(3,5-dimethylpyrazol-1-yl)-2-methylpropyl]-3-(4-methylphenyl)sulfanylpropanamide
    —— (3R,5R)-5-methyl-3-(1-oxidopyridin-1-ium-2-yl)sulfanyloxolan-2-one —— C10H11NO3S
    (3R,5R)-5-methyl-3-(1-oxidopyridin-1-ium-2-yl)sulfanyloxolan-2-one
    —— 2-(4-bromophenyl)sulfanyl-N-[(2S)-3-(3,5-dimethylpyrazol-1-yl)-2-methylpropyl]acetamide —— C17H22BrN3OS
    2-(4-bromophenyl)sulfanyl-N-[(2S)-3-(3,5-dimethylpyrazol-1-yl)-2-methylpropyl]acetamide
    —— (3R,5S)-5-methyl-3-(1-oxidopyridin-1-ium-2-yl)sulfanyloxolan-2-one —— C10H11NO3S
    (3R,5S)-5-methyl-3-(1-oxidopyridin-1-ium-2-yl)sulfanyloxolan-2-one
    —— (2R)-N-(2-methylpropyl)-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide —— C13H17F3N2OS
    (2R)-N-(2-methylpropyl)-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide
    —— 2-(1,3,4-thiadiazol-2-ylsulfanyl)-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone —— C12H13N3OS3
    2-(1,3,4-thiadiazol-2-ylsulfanyl)-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone
    —— (2R)-N,N,3-trimethyl-2-(1-methyltetrazol-5-yl)sulfanylbutanamide —— C9H17N5OS
    (2R)-N,N,3-trimethyl-2-(1-methyltetrazol-5-yl)sulfanylbutanamide
    —— (2R)-N-(2-phenylethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide —— C13H16N4OS
    (2R)-N-(2-phenylethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide
    —— (2S)-N-(2-methylpropyl)-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide —— C13H17F3N2OS
    (2S)-N-(2-methylpropyl)-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide
    —— (2R)-2-(4-bromophenyl)sulfanyl-N-[3-(3,5-dimethylpyrazol-1-yl)propyl]propanamide —— C17H22BrN3OS
    (2R)-2-(4-bromophenyl)sulfanyl-N-[3-(3,5-dimethylpyrazol-1-yl)propyl]propanamide
    —— methyl (2R)-2-[1-(2-thiophen-2-ylethyl)tetrazol-5-yl]sulfanylpropanoate —— C11H14N4O2S2
    methyl (2R)-2-[1-(2-thiophen-2-ylethyl)tetrazol-5-yl]sulfanylpropanoate
    —— (2R)-N-[(1R)-1-(5-chlorothiophen-2-yl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide —— C11H12ClN3OS3
    (2R)-N-[(1R)-1-(5-chlorothiophen-2-yl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)propanamide
    —— (3R,5S)-3-(2,6-dimethylpyrimidin-4-yl)sulfanyl-5-methyloxolan-2-one —— C11H14N2O2S
    (3R,5S)-3-(2,6-dimethylpyrimidin-4-yl)sulfanyl-5-methyloxolan-2-one
    —— (3S,5R)-3-(2,6-dimethylpyrimidin-4-yl)sulfanyl-5-methyloxolan-2-one —— C11H14N2O2S
    (3S,5R)-3-(2,6-dimethylpyrimidin-4-yl)sulfanyl-5-methyloxolan-2-one
    —— methyl (2R)-2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C13H19N3O4S2
    methyl (2R)-2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— 5-[(1S)-1-[(4-cyclopropyl-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C16H24N6OS
    5-[(1S)-1-[(4-cyclopropyl-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propan-2-yl-1,2,4-oxadiazole —— C14H17N5O2S
    5-[(1R)-1-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propan-2-yl-1,2,4-oxadiazole
    —— 3-methyl-5-[(1S)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C10H15N5OS
    3-methyl-5-[(1S)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— ethyl 2-[2-[(3S)-2-oxooxolan-3-yl]sulfanyl-1,3-thiazol-4-yl]acetate —— C11H13NO4S2
    ethyl 2-[2-[(3S)-2-oxooxolan-3-yl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— N-[(1R)-1-(5-methylfuran-2-yl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C13H17N3O2S
    N-[(1R)-1-(5-methylfuran-2-yl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]-2-(pyridin-4-ylmethylsulfanyl)acetamide —— C17H20N2OS2
    N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]-2-(pyridin-4-ylmethylsulfanyl)acetamide
    —— N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-2-(pyridin-2-ylmethylsulfanyl)acetamide —— C17H20N2OS2
    N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-2-(pyridin-2-ylmethylsulfanyl)acetamide
    —— methyl (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C13H22N4O3S
    methyl (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— N-[(1S)-1-(5-methylfuran-2-yl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C13H17N3O2S
    N-[(1S)-1-(5-methylfuran-2-yl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— 3-methyl-5-[(1R)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C10H15N5OS
    3-methyl-5-[(1R)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— (2S)-2-(4-bromophenyl)sulfanyl-N-[3-[[(2R)-oxolan-2-yl]methoxy]propyl]propanamide —— C17H24BrNO3S
    (2S)-2-(4-bromophenyl)sulfanyl-N-[3-[[(2R)-oxolan-2-yl]methoxy]propyl]propanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N'-[2-[(3R)-1,1-dioxothiolan-3-yl]acetyl]propanehydrazide —— C15H19ClN2O4S2
    (2R)-2-(2-chlorophenyl)sulfanyl-N'-[2-[(3R)-1,1-dioxothiolan-3-yl]acetyl]propanehydrazide