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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-oxomethanesulfinothioamide —— CH3NOS2
    N-oxomethanesulfinothioamide
    —— 5-chloro-1-methyl-4-(methylsulphanyl)-3-(trifluoromethyl)-1H-pyrazole —— C6H6ClF3N2S
    5-chloro-1-methyl-4-(methylsulphanyl)-3-(trifluoromethyl)-1H-pyrazole
    —— 1-methyl-4-(methylsulphanyl)-3-(trifluoromethyl)-1H-pyrazole-5-amine —— C6H8F3N3S
    1-methyl-4-(methylsulphanyl)-3-(trifluoromethyl)-1H-pyrazole-5-amine
    —— 1-(4-methylsulfanyl-2-pyridyl) pyrrolidine-2,5-dione 1621685-20-8 C10H10N2O2S
    1-(4-methylsulfanyl-2-pyridyl) pyrrolidine-2,5-dione
    —— [1-[6-chloro-5-(4-chlorophenyl)sulfanyl-1H-benzimidazol-2-yl]pyrazol-4-yl] hydrogen carbonate —— C17H10Cl2N4O3S
    [1-[6-chloro-5-(4-chlorophenyl)sulfanyl-1H-benzimidazol-2-yl]pyrazol-4-yl] hydrogen carbonate
    —— Heptatriacontane-1,37-dithiol —— C37H76S2
    Heptatriacontane-1,37-dithiol
    —— [1-[6-chloro-5-(3-methoxyphenyl)sulfanyl-1H-benzimidazol-2-yl]pyrazol-4-yl] hydrogen carbonate —— C18H13ClN4O4S
    [1-[6-chloro-5-(3-methoxyphenyl)sulfanyl-1H-benzimidazol-2-yl]pyrazol-4-yl] hydrogen carbonate
    —— [1-[6-chloro-5-(4-methoxyphenyl)sulfanyl-1H-benzimidazol-2-yl]pyrazol-4-yl] hydrogen carbonate —— C18H13ClN4O4S
    [1-[6-chloro-5-(4-methoxyphenyl)sulfanyl-1H-benzimidazol-2-yl]pyrazol-4-yl] hydrogen carbonate
    —— 3-cyclobutyl-7-(6-methylpyridin-2-yl)sulfanyl-2,3a,4,9b-tetrahydro-1H-chromeno[3,4-b]pyrrole —— C21H24N2OS
    3-cyclobutyl-7-(6-methylpyridin-2-yl)sulfanyl-2,3a,4,9b-tetrahydro-1H-chromeno[3,4-b]pyrrole
    —— (1Z,3Z)-2-ethylpenta-1,3-diene-1-thiol —— C7H12S
    (1Z,3Z)-2-ethylpenta-1,3-diene-1-thiol
    —— methyl N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]carbamate —— C13H11ClN2O3S
    methyl N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]carbamate
    —— [Bis(hydroxymethyl)-methyl-lambda4-sulfanyl]methanol —— C4H12O3S
    [Bis(hydroxymethyl)-methyl-lambda4-sulfanyl]methanol
    —— (1Z,3E)-3-tert-butylpenta-1,3-diene-1-thiol —— C9H16S
    (1Z,3E)-3-tert-butylpenta-1,3-diene-1-thiol
    —— 1-Ethyl-2-methyl-4-(4-methylsulfanylphenyl)sulfanylbenzene —— C16H18S2
    1-Ethyl-2-methyl-4-(4-methylsulfanylphenyl)sulfanylbenzene
    —— 2-Methyl-1-(2-methylpropyl)-4-[4-(trifluoromethyl)phenyl]sulfanylbenzene —— C18H19F3S
    2-Methyl-1-(2-methylpropyl)-4-[4-(trifluoromethyl)phenyl]sulfanylbenzene
    —— methyl 7-[[(Z)-2-(methylamino)ethenyl]iminomethylsulfanyl]-5-(trifluoromethyl)-1,4-thiazonine-2-carboxylate —— C14H14F3N3O2S2
    methyl 7-[[(Z)-2-(methylamino)ethenyl]iminomethylsulfanyl]-5-(trifluoromethyl)-1,4-thiazonine-2-carboxylate
    —— tert-butyl N-[[2-(3-dimethylphosphoryl-2-oxopropyl)-1,3-dithian-2-yl]methyl]carbamate —— C15H28NO4PS2
    tert-butyl N-[[2-(3-dimethylphosphoryl-2-oxopropyl)-1,3-dithian-2-yl]methyl]carbamate
    —— Ethyl-(heptacontasulfanyl)-bis(sulfanylidene)-lambda6-sulfane —— C2H6S73
    Ethyl-(heptacontasulfanyl)-bis(sulfanylidene)-lambda6-sulfane
    —— 3-{(Z)-[3-(2-Furylmethyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-2-(phenylsulfanyl)-4H-pyrido[1,2-A]pyrimidin-4-one —— C23H15N3O3S3
    3-{(Z)-[3-(2-Furylmethyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-2-(phenylsulfanyl)-4H-pyrido[1,2-A]pyrimidin-4-one
    —— Ethyl 5-methyl-1-phenylsulfanylcyclohex-3-ene-1-carboxylate —— C16H20O2S
    Ethyl 5-methyl-1-phenylsulfanylcyclohex-3-ene-1-carboxylate
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(1-methylpyrrol-2-yl)methylideneamino]acetamide —— C18H19N5OS3
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(1-methylpyrrol-2-yl)methylideneamino]acetamide
    —— 3-(Iodoamino)propane-1-thiol —— C3H8INS
    3-(Iodoamino)propane-1-thiol
    —— Iodo-(2-methylpropyl)-sulfanylidene-lambda4-sulfane —— C4H9IS2
    Iodo-(2-methylpropyl)-sulfanylidene-lambda4-sulfane
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide —— C17H15N5OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide
    —— Disulfanyl-methyl-bis(methyldisulfanyl)azanium —— C3H10NS6+
    Disulfanyl-methyl-bis(methyldisulfanyl)azanium
    —— (3E)-6-hexyl-3-[4-(4-phenylsulfanylphenyl)-3H-1,3-thiazol-2-ylidene]chromene-2,7-dione —— C30H27NO3S2
    (3E)-6-hexyl-3-[4-(4-phenylsulfanylphenyl)-3H-1,3-thiazol-2-ylidene]chromene-2,7-dione
    —— 3-[4-Bromo-2-(fluoromethyl)phenyl]sulfanylpropanamide —— C10H11BrFNOS
    3-[4-Bromo-2-(fluoromethyl)phenyl]sulfanylpropanamide
    —— 3-(4-Aminophenyl)sulfanyl-5-methyloxolan-2-one —— C11H13NO2S
    3-(4-Aminophenyl)sulfanyl-5-methyloxolan-2-one
    —— 3-(4-Aminophenyl)sulfanyl-4,4-dimethyloxolan-2-one —— C12H15NO2S
    3-(4-Aminophenyl)sulfanyl-4,4-dimethyloxolan-2-one
    —— 4-(4-aminophenyl)sulfanyl-1-N,1-N-dimethyl-3-N-(7-methyl-1,8-naphthyridin-4-yl)benzene-1,3-diamine —— C23H23N5S
    4-(4-aminophenyl)sulfanyl-1-N,1-N-dimethyl-3-N-(7-methyl-1,8-naphthyridin-4-yl)benzene-1,3-diamine
    —— 4-Methyl-2,3-dihydro-[1,3]thiazolo[4,5-c]pyridine —— C7H8N2S
    4-Methyl-2,3-dihydro-[1,3]thiazolo[4,5-c]pyridine
    —— [(Z)-but-2-en-2-yl]-methylcarbamothioic S-acid —— C6H11NOS
    [(Z)-but-2-en-2-yl]-methylcarbamothioic S-acid
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]pentanamide —— C19H18N4O3S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]pentanamide
    —— 3-cyanobut-1-en-2-yl N-ethenylethanimidothioate —— C9H12N2S
    3-cyanobut-1-en-2-yl N-ethenylethanimidothioate
    —— 2,4-dichloro-N-[(Z)-[5-[(4,5-diphenyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methylideneamino]benzamide —— C26H17Cl2N5O2S
    2,4-dichloro-N-[(Z)-[5-[(4,5-diphenyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methylideneamino]benzamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-methyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide —— C14H14N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-methyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide
    —— N-[(Z)-(3-nitro-4-quinolin-5-ylsulfanylphenyl)methylideneamino]pentanamide —— C21H20N4O3S
    N-[(Z)-(3-nitro-4-quinolin-5-ylsulfanylphenyl)methylideneamino]pentanamide
    —— (2,4,5-Trimethylpyridin-3-yl) methanimidothioate —— C9H12N2S
    (2,4,5-Trimethylpyridin-3-yl) methanimidothioate
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]octanamide —— C20H24N4O2S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]octanamide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-naphthalen-1-ylacetamide —— C24H17N3O2S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-naphthalen-1-ylacetamide
    —— 5-[(2-Bromophenyl)sulfanylmethyl]-1,3-oxazolidin-2-one —— C10H10BrNO2S
    5-[(2-Bromophenyl)sulfanylmethyl]-1,3-oxazolidin-2-one
    —— N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]pyridine-4-carboxamide —— C20H12N6O5S2
    N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]pyridine-4-carboxamide
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-methoxyacetamide —— C17H14N4O4S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-methoxyacetamide
    —— (Z)-1-[4-bromo-3-(methylthio)thiophen-2-yl]-2,2,2-trifluoroethanone O-methylsulfonyl oxime —— C8H7BrF3NO3S3
    (Z)-1-[4-bromo-3-(methylthio)thiophen-2-yl]-2,2,2-trifluoroethanone O-methylsulfonyl oxime
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-4-fluorobenzamide —— C21H13FN4O3S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-4-fluorobenzamide
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]pyridine-2-carboxamide —— C20H13N5O3S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]pyridine-2-carboxamide
    —— Methyl 4-(1-amino-2-thiophen-2-ylsulfanylethyl)cyclohexane-1-carboxylate —— C14H21NO2S2
    Methyl 4-(1-amino-2-thiophen-2-ylsulfanylethyl)cyclohexane-1-carboxylate
    —— (Z)-[(3-bromo-1,2,4-thiadiazol-5-yl)sulfanylmethylsulfanyl-methylsulfanylmethylidene]cyanamide —— C6H5BrN4S4
    (Z)-[(3-bromo-1,2,4-thiadiazol-5-yl)sulfanylmethylsulfanyl-methylsulfanylmethylidene]cyanamide
    —— (2Z)-5,6-dihydro-4H-pyrrolo[2,1-b][1,3,6]thiadiazocine —— C8H10N2S
    (2Z)-5,6-dihydro-4H-pyrrolo[2,1-b][1,3,6]thiadiazocine
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-3-bromobenzamide —— C19H13BrN4O2S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-3-bromobenzamide