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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-((4-Bromophenyl)sulfonyl)-3-(5-nitro-2-(2-pyridylthio)phenyl)prop-2-enenitrile —— C20H12BrN3O4S2
    2-((4-Bromophenyl)sulfonyl)-3-(5-nitro-2-(2-pyridylthio)phenyl)prop-2-enenitrile
    —— 3-(2-(4-Chlorophenylthio)-5-nitrophenyl)-2-((4-methylphenyl)sulfonyl)prop-2-enenitrile —— C22H15ClN2O4S2
    3-(2-(4-Chlorophenylthio)-5-nitrophenyl)-2-((4-methylphenyl)sulfonyl)prop-2-enenitrile
    —— 2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(2-fluorophenyl)methylideneamino]acetamide —— C19H18ClFN6OS
    2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(2-fluorophenyl)methylideneamino]acetamide
    —— 5-Methyl-1-phenyl-2-[(pyrimidin-2-ylsulfanyl)acetyl]pyrazolidin-3-one —— C16H16N4O2S
    5-Methyl-1-phenyl-2-[(pyrimidin-2-ylsulfanyl)acetyl]pyrazolidin-3-one
    —— 3-{(Z)-[3-(1,3-benzodioxol-5-ylmethyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-7-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C27H19N3O4S3
    3-{(Z)-[3-(1,3-benzodioxol-5-ylmethyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-7-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— (5E)-3-(2-ethylphenyl)-2-(2-ethylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C27H26N2OS2
    (5E)-3-(2-ethylphenyl)-2-(2-ethylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— 2-[(5-methoxy-4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]-3-nitropyridine —— C9H9N5O3S
    2-[(5-methoxy-4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]-3-nitropyridine
    —— 4-[(1-methyl-1H-tetrazol-5-yl)sulfanyl]benzene-1,3-diamine —— C8H10N6S
    4-[(1-methyl-1H-tetrazol-5-yl)sulfanyl]benzene-1,3-diamine
    —— (5Z)-3-(2-chloro-4-fluorobenzyl)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1,3-thiazolidine-2,4-dione —— C21H12Cl2FNO3S2
    (5Z)-3-(2-chloro-4-fluorobenzyl)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1,3-thiazolidine-2,4-dione
    —— (NZ)-N-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]cyclooctylidene]hydroxylamine —— C10H16N4OS2
    (NZ)-N-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]cyclooctylidene]hydroxylamine
    —— 4-Azidophenyl methyl sulfide —— C7H8N3S+
    4-Azidophenyl methyl sulfide
    —— (2Z)-6-(4-chlorobenzyl)-2-[4-(methylsulfanyl)benzylidene]-7H-[1,3]thiazolo[3,2-b][1,2,4]triazine-3,7(2H)-dione —— C20H14ClN3O2S2
    (2Z)-6-(4-chlorobenzyl)-2-[4-(methylsulfanyl)benzylidene]-7H-[1,3]thiazolo[3,2-b][1,2,4]triazine-3,7(2H)-dione
    —— 2,6-ditert-butyl-4-[2,3,5-trifluoro-6-[(2E)-2-[(3-fluorophenyl)methylidene]hydrazinyl]pyridin-4-yl]sulfanylphenol —— C26H27F4N3OS
    2,6-ditert-butyl-4-[2,3,5-trifluoro-6-[(2E)-2-[(3-fluorophenyl)methylidene]hydrazinyl]pyridin-4-yl]sulfanylphenol
    —— 5-[2-[(E)-2-(4-bromophenyl)-1-cyanoethenyl]-1,3-thiazol-4-yl]-6-methyl-2-methylsulfanylpyridine-3-carbonitrile —— C20H13BrN4S2
    5-[2-[(E)-2-(4-bromophenyl)-1-cyanoethenyl]-1,3-thiazol-4-yl]-6-methyl-2-methylsulfanylpyridine-3-carbonitrile
    —— (NZ)-N-[(4Z)-8-(4-methylphenyl)sulfanylcyclooct-4-en-1-ylidene]hydroxylamine —— C15H19NOS
    (NZ)-N-[(4Z)-8-(4-methylphenyl)sulfanylcyclooct-4-en-1-ylidene]hydroxylamine
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C15H15BrN4OS
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 2-((4-Chlorophenyl)sulfonyl)-3-(2-(4-methylphenylthio)-5-nitrophenyl)prop-2-enenitrile —— C22H15ClN2O4S2
    2-((4-Chlorophenyl)sulfonyl)-3-(2-(4-methylphenylthio)-5-nitrophenyl)prop-2-enenitrile
    —— Phenylthioacetic acid, 2,2,3,3,4,4,4-heptafluorobutyl ester —— C12H9F7O2S
    Phenylthioacetic acid, 2,2,3,3,4,4,4-heptafluorobutyl ester
    —— 3-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one —— C23H17ClN4O3S2
    3-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one
    —— 5-[(4-aminobenzyl)sulfanyl]-1H-1,2,4-triazol-3-amine —— C9H11N5S
    5-[(4-aminobenzyl)sulfanyl]-1H-1,2,4-triazol-3-amine
    —— (E)-methyl 2-((7-benzylidene-3-cyano-4-(thiophen-3-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)thio)acetate —— C23H18N2O2S2
    (E)-methyl 2-((7-benzylidene-3-cyano-4-(thiophen-3-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)thio)acetate
    —— (Z)-1-(2-fluorophenyl)-N-(3-methylsulfanyl-1,2,4-triazol-4-yl)methanimine —— C10H9FN4S
    (Z)-1-(2-fluorophenyl)-N-(3-methylsulfanyl-1,2,4-triazol-4-yl)methanimine
    —— (2Z)-2-[[5-(2,4,5-trichlorophenyl)furan-2-yl]methylidene]-1-benzothiophen-3-one —— C19H9Cl3O2S
    (2Z)-2-[[5-(2,4,5-trichlorophenyl)furan-2-yl]methylidene]-1-benzothiophen-3-one
    —— N-[(Z)-(2-methylsulfanylthiophen-3-yl)methylideneamino]acetamide —— C8H10N2OS2
    N-[(Z)-(2-methylsulfanylthiophen-3-yl)methylideneamino]acetamide
    —— ethyl (2Z)-2-[[5-(3-bromophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C28H23BrN2O4S2
    ethyl (2Z)-2-[[5-(3-bromophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (5E)-3-benzyl-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H15ClN2O3S3
    (5E)-3-benzyl-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 2-{[(1-methyl-1H-imidazol-2-yl)sulfanyl]methyl}phenol —— C11H12N2OS
    2-{[(1-methyl-1H-imidazol-2-yl)sulfanyl]methyl}phenol
    —— [(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]urea —— C14H11ClN4O3S
    [(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]urea
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide —— C14H15N5OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide
    —— Ethane, 2,2'-[oxybis(methylenesulfonyl)]bis[1-methoxy- —— C8H18O7S2
    Ethane, 2,2'-[oxybis(methylenesulfonyl)]bis[1-methoxy-
    —— Methyl methoxy[(2-sulfanylethyl)sulfanyl]acetate —— C6H12O3S2
    Methyl methoxy[(2-sulfanylethyl)sulfanyl]acetate
    —— 6-[(6-oxo-2-phenyl-1,6-dihydropyrimidin-4-yl)sulfanyl]-2-phenylpyrimidin-4(1H)-one —— C20H14N4O2S
    6-[(6-oxo-2-phenyl-1,6-dihydropyrimidin-4-yl)sulfanyl]-2-phenylpyrimidin-4(1H)-one
    —— 2-((4-Chlorophenyl)sulfonyl)-3-(2-(4-chlorophenylthio)-5-nitrophenyl)prop-2-enenitrile —— C21H12Cl2N2O4S2
    2-((4-Chlorophenyl)sulfonyl)-3-(2-(4-chlorophenylthio)-5-nitrophenyl)prop-2-enenitrile
    —— 2-(6-methyl-2-methylsulfanylpyrimidin-4-yl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide —— C16H18N4OS2
    2-(6-methyl-2-methylsulfanylpyrimidin-4-yl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-methylbenzamide —— C21H16ClN3O3S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-methylbenzamide
    —— 1-Isothiocyanato-3-(methyldisulfanyl)propane —— C5H9NS3
    1-Isothiocyanato-3-(methyldisulfanyl)propane
    —— N-[(Z)-(2-bromophenyl)methylideneamino]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H12BrN5OS
    N-[(Z)-(2-bromophenyl)methylideneamino]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1,3,3,4,4-Pentafluoro-2-[(heptafluorocyclobutyl)disulfanyl]cyclobutene —— C8F12S2
    1,3,3,4,4-Pentafluoro-2-[(heptafluorocyclobutyl)disulfanyl]cyclobutene
    —— 2-(4,6-dimethoxypyrimidin-2-yl)sulfanyl-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]acetamide —— C17H21N5O3S
    2-(4,6-dimethoxypyrimidin-2-yl)sulfanyl-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]acetamide
    —— 2-hydroxy-N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide —— C21H17N3O4S
    2-hydroxy-N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide
    —— ethyl (2Z)-5-(4-bromophenyl)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21BrN2O3S2
    ethyl (2Z)-5-(4-bromophenyl)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-amine —— C21H16N4O2S2
    N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-amine
    —— Dimethyl diselenenyl sulfide —— C2H6SSe2
    Dimethyl diselenenyl sulfide
    —— 4-benzylsulfanyl-pyrido[3,2-<i>c</i>]pyridazine 68432-44-0 C14H11N3S
    4-benzylsulfanyl-pyrido[3,2-<i>c</i>]pyridazine
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-phenylimino-1,3-thiazolidin-4-one —— C22H14ClN3O3S2
    (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-phenylimino-1,3-thiazolidin-4-one
    —— 2-[(5E)-2-(cyanomethyl)-5-(cyanomethylidene)-4,4-dimethyl-1,3-dithiolan-2-yl]propan-2-yl carbamate —— C13H17N3O2S2
    2-[(5E)-2-(cyanomethyl)-5-(cyanomethylidene)-4,4-dimethyl-1,3-dithiolan-2-yl]propan-2-yl carbamate
    —— 4,6-Dimethyl-2-[(1,2-oxazol-3-ylmethyl)sulfanyl]pyridine-3-carbonitrile —— C12H11N3OS
    4,6-Dimethyl-2-[(1,2-oxazol-3-ylmethyl)sulfanyl]pyridine-3-carbonitrile
    —— 1-(2,2-Dimethoxyethyl)-1,3-dimethylthiourea —— C7H16N2O2S
    1-(2,2-Dimethoxyethyl)-1,3-dimethylthiourea
    —— 5-methyl-2-phenyl-4-<i>p</i>-tolylsulfanyl-1,2-dihydro-pyrazol-3-one 56634-81-2 C17H16N2OS
    5-methyl-2-phenyl-4-<i>p</i>-tolylsulfanyl-1,2-dihydro-pyrazol-3-one
    —— 1, 1'-Thiobis(2-methyl-4-tert-butyldimethylsilyloxy-5-tert-butylbenzene) —— C34H58O2SSi2
    1, 1'-Thiobis(2-methyl-4-tert-butyldimethylsilyloxy-5-tert-butylbenzene)