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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1-Bromo-4,4-dimethyloct-2-en-3-yl)sulfinylmethyl-deuterio-tritioborane —— C11H22BBrOS
    (1-Bromo-4,4-dimethyloct-2-en-3-yl)sulfinylmethyl-deuterio-tritioborane
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide —— C16H18N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide
    —— 5-methoxy-6-(4-methoxyphenyl)sulfanyl-1H-pyrimidine-2-thione —— C12H12N2O2S2
    5-methoxy-6-(4-methoxyphenyl)sulfanyl-1H-pyrimidine-2-thione
    —— 2-[2-(1-Chloroethylsulfonyl)ethoxy]ethanamine —— C6H14ClNO3S
    2-[2-(1-Chloroethylsulfonyl)ethoxy]ethanamine
    —— 2,3-Bis(cyanomethylsulfanyl)propyl ethanimidothioate —— C9H13N3S3
    2,3-Bis(cyanomethylsulfanyl)propyl ethanimidothioate
    —— N-[1-(2-methylphenyl)-3-(4-methylphenylthio)-2-propenylidene]-4-methylaniline 1140914-95-9 C24H23NS
    N-[1-(2-methylphenyl)-3-(4-methylphenylthio)-2-propenylidene]-4-methylaniline
    —— 2-(4-chlorophenyl)sulfanyl-3-[(Z)-(phenylhydrazinylidene)methyl]pyrido[1,2-a]pyrimidin-4-one —— C21H15ClN4OS
    2-(4-chlorophenyl)sulfanyl-3-[(Z)-(phenylhydrazinylidene)methyl]pyrido[1,2-a]pyrimidin-4-one
    —— Methyl 5-(2-fluorophenyl)sulfanylpentanoate —— C12H15FO2S
    Methyl 5-(2-fluorophenyl)sulfanylpentanoate
    —— 3-(4-cyclohexyl-phenylsulfanyl)-4-fluoro-5-methoxy-benzo[b]thiophene-2-carboxylic acid (2H-tetrazol-5-yl)-amide —— C23H22FN5O2S2
    3-(4-cyclohexyl-phenylsulfanyl)-4-fluoro-5-methoxy-benzo[b]thiophene-2-carboxylic acid (2H-tetrazol-5-yl)-amide
    —— 4-(6-oxo-4a,5-dihydro-4H-pyridazino[3,4-b][1,4]thiazin-3-yl)-5H-pyridazino[3,4-b][1,4]thiazin-6-one —— C12H10N6O2S2
    4-(6-oxo-4a,5-dihydro-4H-pyridazino[3,4-b][1,4]thiazin-3-yl)-5H-pyridazino[3,4-b][1,4]thiazin-6-one
    —— 3-[6-Methyl-3-(2-propylpentylsulfonyl)cyclohexa-1,3-dien-1-yl]prop-2-en-1-amine —— C18H31NO2S
    3-[6-Methyl-3-(2-propylpentylsulfonyl)cyclohexa-1,3-dien-1-yl]prop-2-en-1-amine
    —— 4-[3-[3-[Ethylamino(formyl)amino]phenyl]sulfanylphenyl]sulfonyl-3-phenylbutanoic acid —— C25H26N2O5S2
    4-[3-[3-[Ethylamino(formyl)amino]phenyl]sulfanylphenyl]sulfonyl-3-phenylbutanoic acid
    —— N-(methylsulfonimidoyl)oxypropan-1-amine —— C4H12N2O2S
    N-(methylsulfonimidoyl)oxypropan-1-amine
    —— N-[5-ethynyl-2-(1H-indol-6-ylsulfanyl)phenyl]-7-propan-2-ylpyrido[2,3-d]pyrimidin-4-amine —— C26H21N5S
    N-[5-ethynyl-2-(1H-indol-6-ylsulfanyl)phenyl]-7-propan-2-ylpyrido[2,3-d]pyrimidin-4-amine
    —— 4-Methoxy-2-phenylsulfanylbutan-1-ol —— C11H16O2S
    4-Methoxy-2-phenylsulfanylbutan-1-ol
    —— 1-(amino-hydroxy-oxo-lambda6-sulfanylidene)-N,N-dimethylmethanamine —— C3H10N2O2S
    1-(amino-hydroxy-oxo-lambda6-sulfanylidene)-N,N-dimethylmethanamine
    —— N-methyl-N-[(Z)-(2-phenylsulfanylphenyl)methylideneamino]aniline —— C20H18N2S
    N-methyl-N-[(Z)-(2-phenylsulfanylphenyl)methylideneamino]aniline
    —— carbamimidoyl(propan-2-yl)carbamothioic S-acid —— C5H11N3OS
    carbamimidoyl(propan-2-yl)carbamothioic S-acid
    —— 2-(2,2-Dimethylcyclopropyl)ethanethiol —— C7H14S
    2-(2,2-Dimethylcyclopropyl)ethanethiol
    —— 3-(2-butylphenyl)sulfanyl-6-methylsulfonyl-1H-indole —— C19H21NO2S2
    3-(2-butylphenyl)sulfanyl-6-methylsulfonyl-1H-indole
    —— N-(cyclopentylmethyl)-N-ethyl-3-methylbutanethioamide —— C13H25NS
    N-(cyclopentylmethyl)-N-ethyl-3-methylbutanethioamide
    —— 4-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-ol —— C20H16N6O2S
    4-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-5,6,7,8-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-ol
    —— Ethane;1-nitro-4-phenylsulfanylbenzene —— C16H21NO2S
    Ethane;1-nitro-4-phenylsulfanylbenzene
    —— N'-methyl-N-[(E)-2-methylsulfanylprop-1-enyl]methanimidamide —— C6H12N2S
    N'-methyl-N-[(E)-2-methylsulfanylprop-1-enyl]methanimidamide
    —— 2-Methylsulfanyl-5-piperidin-1-ylpyrazine —— C10H15N3S
    2-Methylsulfanyl-5-piperidin-1-ylpyrazine
    —— 4-[5-[(5-Chloro-1,3-benzoxazol-2-yl)sulfanyl]furan-2-yl]-1,4,4a,6,7,8-hexahydropyrazolo[3,4-b]quinolin-5-one —— C21H15ClN4O3S
    4-[5-[(5-Chloro-1,3-benzoxazol-2-yl)sulfanyl]furan-2-yl]-1,4,4a,6,7,8-hexahydropyrazolo[3,4-b]quinolin-5-one
    —— Ethane;methyl 2-[3-(1-ethylpyrrolidin-3-yl)sulfanylphenyl]acetate —— C19H33NO2S
    Ethane;methyl 2-[3-(1-ethylpyrrolidin-3-yl)sulfanylphenyl]acetate
    —— phenyl 3-phenoxy-N-(4-phenylsulfanylphenyl)prop-2-enimidate —— C27H21NO2S
    phenyl 3-phenoxy-N-(4-phenylsulfanylphenyl)prop-2-enimidate
    —— [(2R)-2-(3-chlorophenyl)-2-hydroxyethyl] N-tert-butyl-N-[(2R)-1-[4-(3-chloro-2-formylphenyl)sulfanylphenyl]propan-2-yl]carbamate —— C29H31Cl2NO4S
    [(2R)-2-(3-chlorophenyl)-2-hydroxyethyl] N-tert-butyl-N-[(2R)-1-[4-(3-chloro-2-formylphenyl)sulfanylphenyl]propan-2-yl]carbamate
    —— 1-Ethylsulfonylethane;methyl 4-formylbicyclo[2.2.2]octane-1-carboxylate —— C15H26O5S
    1-Ethylsulfonylethane;methyl 4-formylbicyclo[2.2.2]octane-1-carboxylate
    —— 4-(Methylaminomethyl)hexanethial —— C8H17NS
    4-(Methylaminomethyl)hexanethial
    —— N-[2,5-dihydroxy-4-[[4-[2-(methylamino)-2-oxoethyl]-1,3-thiazol-2-yl]sulfanyl]phenyl]-2-methylsulfanylpropanamide;2-(2-hexyldecyl)benzene-1,4-diol;(4-hydroxyphenyl) 4-[1-[2-(4-butan-2-yloxyphenyl)hydrazinyl]-1-oxododecan-2-yl]oxybenzenesulfinate;2-methyl-N-(2-sulfanylidene-1,3-dihydrobenzimidazol-5-yl)hexanamide —— C86H122N8O13S5
    N-[2,5-dihydroxy-4-[[4-[2-(methylamino)-2-oxoethyl]-1,3-thiazol-2-yl]sulfanyl]phenyl]-2-methylsulfanylpropanamide;2-(2-hexyldecyl)benzene-1,4-diol;(4-hydroxyphenyl) 4-[1-[2-(4-butan-2-yloxyphenyl)hydrazinyl]-1-oxododecan-2-yl]oxybenzenesulfinate;2-methyl-N-(2-sulfanylidene-1,3-dihydrobenzimidazol-5-yl)hexanamide
    —— N-(pyridin-4-ylmethyl)-8H-pyrimido[5,4-b][1,4]thiazine-6-carboxamide —— C13H11N5OS
    N-(pyridin-4-ylmethyl)-8H-pyrimido[5,4-b][1,4]thiazine-6-carboxamide
    —— 1-Butan-2-yloxy-4-methylsulfonylcyclohexa-1,4-diene —— C11H18O3S
    1-Butan-2-yloxy-4-methylsulfonylcyclohexa-1,4-diene
    —— 1-[5-chloro-4-(chlorodiazenyl)-2-(2-nitrophenyl)sulfanylphenyl]-N,N-dimethylmethanamine —— C15H14Cl2N4O2S
    1-[5-chloro-4-(chlorodiazenyl)-2-(2-nitrophenyl)sulfanylphenyl]-N,N-dimethylmethanamine
    —— N,N-dimethyl-2H-1,3-benzothiaborol-3-amine —— C9H12BNS
    N,N-dimethyl-2H-1,3-benzothiaborol-3-amine
    —— 4-Ethylsulfanyl-1,1,1-trifluorobutane —— C6H11F3S
    4-Ethylsulfanyl-1,1,1-trifluorobutane
    —— 2-{[(7E)-3-cyano-4-(furan-2-yl)-7-(furan-2-ylmethylidene)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl}acetamide —— C20H15N3O3S
    2-{[(7E)-3-cyano-4-(furan-2-yl)-7-(furan-2-ylmethylidene)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl}acetamide
    —— 2-Heptadecylsulfanylthiophene —— C21H38S2
    2-Heptadecylsulfanylthiophene
    —— 3,3-Dimethyl-1-[5-(1H-1,2,4-triazol-1-ylmethyl)-1,3,4-thiadiazol-2-\ ylsulfanyl]butan-2-one —— C11H15N5OS2
    3,3-Dimethyl-1-[5-(1H-1,2,4-triazol-1-ylmethyl)-1,3,4-thiadiazol-2-\ ylsulfanyl]butan-2-one
    —— 4-Methyl-1-(4-sulfanylidenecyclohex-2-en-1-yl)hexan-3-one —— C13H20OS
    4-Methyl-1-(4-sulfanylidenecyclohex-2-en-1-yl)hexan-3-one
    —— N-methyl-2-[[3-(2-phenylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide —— C23H19N3OS
    N-methyl-2-[[3-(2-phenylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide
    —— 6-(4-Fluoro-2-methylphenyl)sulfanyl-3-propan-2-yl-[1,2,4]triazolo[4,3-a]pyridine —— C16H16FN3S
    6-(4-Fluoro-2-methylphenyl)sulfanyl-3-propan-2-yl-[1,2,4]triazolo[4,3-a]pyridine
    —— 1-[4-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidin-1-yl]-2-hydroxyethanone —— C21H24BrN6O4S+
    1-[4-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidin-1-yl]-2-hydroxyethanone
    —— N-(5-fluoro-1,3-thiazol-2-yl)-2-[(3R)-oxolan-3-yl]oxyimino-2-(4-pyridin-2-ylsulfanylphenyl)acetamide —— C20H17FN4O3S2
    N-(5-fluoro-1,3-thiazol-2-yl)-2-[(3R)-oxolan-3-yl]oxyimino-2-(4-pyridin-2-ylsulfanylphenyl)acetamide
    —— 4-(Cyclohexa-1,3-dien-1-ylmethyl)cyclohex-3-ene-1-thione —— C13H16S
    4-(Cyclohexa-1,3-dien-1-ylmethyl)cyclohex-3-ene-1-thione
    —— 1-ethyl-8-(4-methoxyphenyl)sulfanyl-3-methyl-4,7-dihydro-2H-pyrazolo[4,3-e][1,4]diazepine —— C16H20N4OS
    1-ethyl-8-(4-methoxyphenyl)sulfanyl-3-methyl-4,7-dihydro-2H-pyrazolo[4,3-e][1,4]diazepine
    —— 3,17-Difluoro-5-methylsulfanyl-8-propan-2-yl-12-oxa-4,6,8-triazatricyclo[11.4.0.02,7]heptadeca-1(13),2(7),3,5,14,16-hexaene —— C17H19F2N3OS
    3,17-Difluoro-5-methylsulfanyl-8-propan-2-yl-12-oxa-4,6,8-triazatricyclo[11.4.0.02,7]heptadeca-1(13),2(7),3,5,14,16-hexaene
    —— 4-[2-[6-amino-8-[(5-methoxy-1,3-benzoxazol-7-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde —— C21H24N7O3S+
    4-[2-[6-amino-8-[(5-methoxy-1,3-benzoxazol-7-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde
    —— 4-Iminobut-2-ynyl carbamimidothioate —— C5H7N3S
    4-Iminobut-2-ynyl carbamimidothioate