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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(2,4-dinitrophenyl)sulfanyl]-5H-[1,2,4]triazino[5,6-b]indole —— C15H8N6O4S
    3-[(2,4-dinitrophenyl)sulfanyl]-5H-[1,2,4]triazino[5,6-b]indole
    —— (2S)-2-chloro-1-(5-propylsulfanylthiophen-2-yl)propan-1-one —— C10H13ClOS2
    (2S)-2-chloro-1-(5-propylsulfanylthiophen-2-yl)propan-1-one
    —— N-butyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide —— C23H26N4OS
    N-butyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]butanamide
    —— 3-(5-nitropyridin-2-yl)sulfanyl-5H-[1,2,4]triazino[5,6-b]indole —— C14H8N6O2S
    3-(5-nitropyridin-2-yl)sulfanyl-5H-[1,2,4]triazino[5,6-b]indole
    —— 5,6-Diethyl-3-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazine —— C15H19N3S
    5,6-Diethyl-3-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazine
    —— 2-(4-Methylpiperazin-1-yl)-1-(5-propylsulfanylthiophen-2-yl)ethanone —— C14H22N2OS2
    2-(4-Methylpiperazin-1-yl)-1-(5-propylsulfanylthiophen-2-yl)ethanone
    —— 2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-1-(5-propylsulfanylthiophen-2-yl)ethanone —— C15H23NO2S2
    2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-1-(5-propylsulfanylthiophen-2-yl)ethanone
    —— N,N-diethyl-2-[(8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl)sulfanyl]acetamide —— C17H26N4OS
    N,N-diethyl-2-[(8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl)sulfanyl]acetamide
    —— 2-[(3S)-3-methylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone —— C15H23NOS2
    2-[(3S)-3-methylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone
    —— 2-(4-Ethylpiperazin-1-yl)-1-(5-propylsulfanylthiophen-2-yl)ethanone —— C15H24N2OS2
    2-(4-Ethylpiperazin-1-yl)-1-(5-propylsulfanylthiophen-2-yl)ethanone
    —— 2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-1-(5-propylsulfanylthiophen-2-yl)ethanone —— C15H23NO2S2
    2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-1-(5-propylsulfanylthiophen-2-yl)ethanone
    —— 3-[(3S)-3-methylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)propan-1-one —— C16H25NOS2
    3-[(3S)-3-methylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)propan-1-one
    —— 1,4,5,8-Tetrakis(benzylthio)pyridazino(4,5-D)pyridazine —— C34H28N4S4
    1,4,5,8-Tetrakis(benzylthio)pyridazino(4,5-D)pyridazine
    —— 1-(5-ethylsulfanylthiophen-2-yl)-2-[(3R)-3-methylpiperidin-1-yl]ethanone —— C14H21NOS2
    1-(5-ethylsulfanylthiophen-2-yl)-2-[(3R)-3-methylpiperidin-1-yl]ethanone
    —— 2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-1-(5-ethylsulfanylthiophen-2-yl)ethanone —— C14H21NO2S2
    2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-1-(5-ethylsulfanylthiophen-2-yl)ethanone
    —— ethyl N-[2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetyl]carbamate —— C22H22N4O3S
    ethyl N-[2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetyl]carbamate
    —— 3-[(4-Bromophenyl)methylsulfanyl]-5,6-bis(4-methylphenyl)-1,2,4-triazine —— C24H20BrN3S
    3-[(4-Bromophenyl)methylsulfanyl]-5,6-bis(4-methylphenyl)-1,2,4-triazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide —— C25H30N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide
    —— 3-(4-Methylpiperazin-1-yl)-1-(5-propan-2-ylsulfanylthiophen-2-yl)propan-1-one —— C15H24N2OS2
    3-(4-Methylpiperazin-1-yl)-1-(5-propan-2-ylsulfanylthiophen-2-yl)propan-1-one
    —— 2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone —— C16H25NOS2
    2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone
    —— 2-(4-Ethylpiperazin-1-yl)-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone —— C15H24N2OS2
    2-(4-Ethylpiperazin-1-yl)-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(1-phenylethyl)acetamide —— C27H26N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(1-phenylethyl)acetamide
    —— 2-[(3R)-3-methylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone —— C15H23NOS2
    2-[(3R)-3-methylpiperidin-1-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone
    —— 1-(5-Ethylsulfanylthiophen-2-yl)-3-(4-methylpiperazin-1-yl)propan-1-one —— C14H22N2OS2
    1-(5-Ethylsulfanylthiophen-2-yl)-3-(4-methylpiperazin-1-yl)propan-1-one
    —— 2-[(3S)-3-methylpiperidin-1-yl]-1-(5-propylsulfanylthiophen-2-yl)ethanone —— C15H23NOS2
    2-[(3S)-3-methylpiperidin-1-yl]-1-(5-propylsulfanylthiophen-2-yl)ethanone
    —— 2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone —— C15H23NO2S2
    2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-1-(5-propan-2-ylsulfanylthiophen-2-yl)ethanone
    —— 2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-(1-methoxypropan-2-yl)-2,5-dimethylpyrrol-3-yl]ethanone —— C27H28N4O2S
    2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-(1-methoxypropan-2-yl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— 2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-1-(5-ethylsulfanylthiophen-2-yl)ethanone —— C14H21NO2S2
    2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-1-(5-ethylsulfanylthiophen-2-yl)ethanone
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C21H19F3N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— 7-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C24H19N5OS2
    7-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-pentan-2-ylacetamide —— C22H24N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-pentan-2-ylacetamide
    —— 2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-(1-cyano-1,2-dimethylpropyl)acetamide —— C25H27N5OS
    2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-(1-cyano-1,2-dimethylpropyl)acetamide
    —— (E)-3-amino-2-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]but-2-enenitrile —— C21H17N5OS
    (E)-3-amino-2-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]but-2-enenitrile
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-propylacetamide —— C22H24N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-propylacetamide
    —— 2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-(butan-2-yl)acetamide —— C23H26N4OS
    2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-(butan-2-yl)acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(3-phenylpropyl)acetamide —— C28H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(3-phenylpropyl)acetamide
    —— 3-[2-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]ethylsulfanyl]-5,6-bis(furan-2-yl)-1,2,4-triazine —— C24H16N6O4S2
    3-[2-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]ethylsulfanyl]-5,6-bis(furan-2-yl)-1,2,4-triazine
    —— 4-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanylmethyl]-3,5-dimethyl-1,2-oxazole —— C23H22N4OS
    4-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanylmethyl]-3,5-dimethyl-1,2-oxazole
    —— N-(4-fluorophenyl)-N-{2-[6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl]vinyl}amine —— C15H17FN4S
    N-(4-fluorophenyl)-N-{2-[6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl]vinyl}amine
    —— 5-(4-((4-Chlorophenyl)thio)-4-phenyl-2-butenyl)-6-methyl-1,2,4-triazin-3-ylamine —— C20H19ClN4S
    5-(4-((4-Chlorophenyl)thio)-4-phenyl-2-butenyl)-6-methyl-1,2,4-triazin-3-ylamine
    —— Ethyl 5-[(4-bromophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate —— C19H16BrN3O2S
    Ethyl 5-[(4-bromophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate
    —— N-(2-(3-(Allylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline —— C15H15FN4S
    N-(2-(3-(Allylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline
    —— 2-[(4-Benzyl-1-phthalazinyl)sulfanyl]-1-pyridiniumolate —— C20H15N3OS
    2-[(4-Benzyl-1-phthalazinyl)sulfanyl]-1-pyridiniumolate
    —— N<sup>1</sup>-(1,3-dimethylbutyl)-N<sup>4</sup>-phenyl-2-(3-pyridazinylsulfanyl)-1,4-phenylenediamine —— C22H26N4S
    N<sup>1</sup>-(1,3-dimethylbutyl)-N<sup>4</sup>-phenyl-2-(3-pyridazinylsulfanyl)-1,4-phenylenediamine
    —— 3-((4-Chlorobenzyl)sulfanyl)-5-(2-(((3-fluorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine —— C20H18ClFN4OS
    3-((4-Chlorobenzyl)sulfanyl)-5-(2-(((3-fluorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine
    —— Ethyl 5-{[2-(methoxycarbonyl)phenyl]sulfanyl}-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate —— C21H19N3O4S
    Ethyl 5-{[2-(methoxycarbonyl)phenyl]sulfanyl}-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate
    —— Methyl 2-((6-((5-(methoxycarbonyl)-1-methyl-1H-imidazol-2-yl)sulfanyl)-3-pyridazinyl)sulfanyl)-1-methyl-1H-imidazole-5-carboxylate —— C16H16N6O4S2
    Methyl 2-((6-((5-(methoxycarbonyl)-1-methyl-1H-imidazol-2-yl)sulfanyl)-3-pyridazinyl)sulfanyl)-1-methyl-1H-imidazole-5-carboxylate
    —— 5-(2-(((3-Fluorobenzyl)oxy)amino)vinyl)-6-methyl-3-(methylsulfanyl)-1,2,4-triazine —— C14H15FN4OS
    5-(2-(((3-Fluorobenzyl)oxy)amino)vinyl)-6-methyl-3-(methylsulfanyl)-1,2,4-triazine
    —— Phenyl[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetic acid —— C17H13N3O2S
    Phenyl[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetic acid
    —— 4-Chloro-N-(2-(3-((4-chlorobenzyl)sulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)aniline —— C19H16Cl2N4S
    4-Chloro-N-(2-(3-((4-chlorobenzyl)sulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)aniline