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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5Z,10S)-10-phenylsulfanylcyclodec-5-en-1-one —— C16H20OS
    (5Z,10S)-10-phenylsulfanylcyclodec-5-en-1-one
    —— [(Z)-[2-(4-methoxyphenyl)sulfanylphenyl]methylideneamino]urea —— C15H15N3O2S
    [(Z)-[2-(4-methoxyphenyl)sulfanylphenyl]methylideneamino]urea
    —— (NZ)-N-[[2-(3,4-dimethoxyphenyl)sulfanylphenyl]methylidene]hydroxylamine —— C15H15NO3S
    (NZ)-N-[[2-(3,4-dimethoxyphenyl)sulfanylphenyl]methylidene]hydroxylamine
    —— (3R)-N-(4-methylsulfanylphenyl)thian-3-amine —— C12H17NS2
    (3R)-N-(4-methylsulfanylphenyl)thian-3-amine
    —— 1-[(2R)-2-(cyclohexylmethyl)pyrrolidin-1-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylethanone —— C19H29N3OS
    1-[(2R)-2-(cyclohexylmethyl)pyrrolidin-1-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylethanone
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide —— C16H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-phenylethylideneamino]acetamide
    —— (3S)-N-(3-methylsulfanylphenyl)thian-3-amine —— C12H17NS2
    (3S)-N-(3-methylsulfanylphenyl)thian-3-amine
    —— [(Z)-[2-(3-methoxyphenyl)sulfanylphenyl]methylideneamino]urea —— C15H15N3O2S
    [(Z)-[2-(3-methoxyphenyl)sulfanylphenyl]methylideneamino]urea
    —— (3R)-N-(3-methylsulfanylphenyl)thian-3-amine —— C12H17NS2
    (3R)-N-(3-methylsulfanylphenyl)thian-3-amine
    —— [[2-[(3-Methoxyphenyl)thio]benzylidene]amino]urea —— C15H15N3O2S
    [[2-[(3-Methoxyphenyl)thio]benzylidene]amino]urea
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-fluorophenyl)methylideneamino]acetamide —— C15H12ClFN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-fluorophenyl)methylideneamino]acetamide
    —— N-[(Z)-benzylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H13ClN2OS
    N-[(Z)-benzylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— N-[(Z)-(3-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H12Cl2N2OS
    N-[(Z)-(3-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— [(Z)-[2-(2-methoxyphenyl)sulfanylphenyl]methylideneamino]urea —— C15H15N3O2S
    [(Z)-[2-(2-methoxyphenyl)sulfanylphenyl]methylideneamino]urea
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-1-[4-[(3R)-1,1-dioxothiolan-3-yl]piperazin-1-yl]ethanone —— C17H23BrN2O3S2
    2-(4-bromo-2-methylphenyl)sulfanyl-1-[4-[(3R)-1,1-dioxothiolan-3-yl]piperazin-1-yl]ethanone
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylphenyl)methylideneamino]acetamide —— C16H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-methylphenyl)methylideneamino]acetamide
    —— (2Z)-2-[(3-chloroanilino)methylidene]-1-benzothiophen-3-one —— C15H10ClNOS
    (2Z)-2-[(3-chloroanilino)methylidene]-1-benzothiophen-3-one
    —— (2E)-2-[(2-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    (2E)-2-[(2-methylanilino)methylidene]-1-benzothiophen-3-one
    —— (2S)-2-bromo-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]butanamide —— C13H18BrNOS
    (2S)-2-bromo-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]butanamide
    —— (2R)-2-bromo-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]butanamide —— C12H13BrN4OS
    (2R)-2-bromo-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]butanamide
    —— (2R)-2-bromo-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]butanamide —— C13H18BrNOS
    (2R)-2-bromo-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]butanamide
    —— (2S)-2-bromo-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]butanamide —— C12H13BrN4OS
    (2S)-2-bromo-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]butanamide
    —— (2S)-2-bromo-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]butanamide —— C13H18BrNOS
    (2S)-2-bromo-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]butanamide
    —— 2-methoxy-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C12H17NO2S
    2-methoxy-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— (2Z)-2-[(1,2,4-triazol-4-ylamino)methylidene]-1-benzothiophen-3-one —— C11H8N4OS
    (2Z)-2-[(1,2,4-triazol-4-ylamino)methylidene]-1-benzothiophen-3-one
    —— (2Z)-2-[[(5-bromopyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one —— C14H9BrN2OS
    (2Z)-2-[[(5-bromopyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one
    —— N-[(Z)-benzylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H13N3OS
    N-[(Z)-benzylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— (NZ)-N-[(2-methylsulfanylphenyl)methylidene]hydroxylamine —— C8H9NOS
    (NZ)-N-[(2-methylsulfanylphenyl)methylidene]hydroxylamine
    —— (Z)-1-(2-methoxy-5-methylsulfanylthiophen-3-yl)-N-(1,2,4-triazol-4-yl)methanimine —— C9H10N4OS2
    (Z)-1-(2-methoxy-5-methylsulfanylthiophen-3-yl)-N-(1,2,4-triazol-4-yl)methanimine
    —— (Z)-1-(5-methyl-2-methylsulfanylthiophen-3-yl)-N-(1,2,4-triazol-4-yl)methanimine —— C9H10N4S2
    (Z)-1-(5-methyl-2-methylsulfanylthiophen-3-yl)-N-(1,2,4-triazol-4-yl)methanimine
    —— 2-pyrimidin-2-ylsulfanyl-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C11H10N4OS2
    2-pyrimidin-2-ylsulfanyl-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— 2-[1-[(1S)-1-thiophen-3-ylethyl]tetrazol-5-yl]sulfanylacetic acid —— C9H10N4O2S2
    2-[1-[(1S)-1-thiophen-3-ylethyl]tetrazol-5-yl]sulfanylacetic acid
    —— 2-[[4-[(1R)-1-thiophen-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C10H11N3O2S2
    2-[[4-[(1R)-1-thiophen-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(1S)-1-thiophen-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C10H11N3O2S2
    2-[[4-[(1S)-1-thiophen-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[1-[(1R)-1-thiophen-3-ylethyl]tetrazol-5-yl]sulfanylacetic acid —— C9H10N4O2S2
    2-[1-[(1R)-1-thiophen-3-ylethyl]tetrazol-5-yl]sulfanylacetic acid
    —— N-(2-furylmethylene)-N-[3-(methylsulfanyl)-4H-1,2,4-triazol-4-yl]amine —— C8H8N4OS
    N-(2-furylmethylene)-N-[3-(methylsulfanyl)-4H-1,2,4-triazol-4-yl]amine
    —— N-[3-(benzylthio)-4H-1,2,4-triazol-4-yl]-N-{(Z)-[4-(dimethylamino)phenyl]methylidene}amine —— C18H19N5S
    N-[3-(benzylthio)-4H-1,2,4-triazol-4-yl]-N-{(Z)-[4-(dimethylamino)phenyl]methylidene}amine
    —— 3-(Benzylthio)-N-(2-furylmethylene)-4H-1,2,4-triazol-4-amine —— C14H12N4OS
    3-(Benzylthio)-N-(2-furylmethylene)-4H-1,2,4-triazol-4-amine
    —— N-hexyl-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C15H26N4O3S
    N-hexyl-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2R)-heptan-2-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H26N4OS
    N-[(2R)-heptan-2-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2S)-heptan-2-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N4OS2
    N-[(2S)-heptan-2-yl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C19H26N4OS
    N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (1R,6S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]bicyclo[4.1.0]heptane-7-carboxamide —— C16H20N2OS
    (1R,6S)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]bicyclo[4.1.0]heptane-7-carboxamide
    —— (4S)-N-(2-phenylsulfanylethyl)-4,5,6,7-tetrahydro-1-benzothiophen-4-amine —— C16H19NS2
    (4S)-N-(2-phenylsulfanylethyl)-4,5,6,7-tetrahydro-1-benzothiophen-4-amine
    —— (4R)-N-(2-phenylsulfanylethyl)-4,5,6,7-tetrahydro-1-benzothiophen-4-amine —— C16H19NS2
    (4R)-N-(2-phenylsulfanylethyl)-4,5,6,7-tetrahydro-1-benzothiophen-4-amine
    —— 2-(2-methyl-1,3-dioxolan-2-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C14H18N2O3S
    2-(2-methyl-1,3-dioxolan-2-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-(2-methyl-1,3-dioxolan-2-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}acetohydrazide —— C14H18N2O3S
    2-(2-methyl-1,3-dioxolan-2-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}acetohydrazide
    —— 4-[(E)-benzylideneamino]-6-tert-butyl-3-methylsulfanyl-1,2,4-triazin-5-one 57057-63-3 C15H18N4OS
    4-[(E)-benzylideneamino]-6-tert-butyl-3-methylsulfanyl-1,2,4-triazin-5-one
    —— N-[(Z)-pyridin-4-ylmethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide —— C12H11N5OS
    N-[(Z)-pyridin-4-ylmethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(Z)-(4-methylphenyl)methylideneamino]-3-phenylsulfanylpropanamide —— C17H18N2OS
    N-[(Z)-(4-methylphenyl)methylideneamino]-3-phenylsulfanylpropanamide