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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[(1-methylpyrazol-4-yl)methyl]-N-propan-2-ylpropanamide —— C17H25N5O2S
    3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[(1-methylpyrazol-4-yl)methyl]-N-propan-2-ylpropanamide
    —— (E)-1-(2-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15ClN4S
    (E)-1-(2-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (E)-N-(4-fluorobenzylidene)-3-((4-methylbenzyl)thio)-4H-1,2,4-triazol-4-amine —— C17H15FN4S
    (E)-N-(4-fluorobenzylidene)-3-((4-methylbenzyl)thio)-4H-1,2,4-triazol-4-amine
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(3-methylphenyl)methylideneamino]acetamide —— C19H17ClN4OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(3-methylphenyl)methylideneamino]acetamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[(1-methylpyrazol-4-yl)methyl]-N-propan-2-ylpropanamide —— C17H22ClN3OS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[(1-methylpyrazol-4-yl)methyl]-N-propan-2-ylpropanamide
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-chlorophenyl)methanimine —— C16H13ClN4S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-chlorophenyl)methanimine
    —— (E)-1-(4-bromophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15BrN4S
    (E)-1-(4-bromophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (E)-3-(benzylthio)-N-(3-bromobenzylidene)-4H-1,2,4-triazol-4-amine —— C16H13BrN4S
    (E)-3-(benzylthio)-N-(3-bromobenzylidene)-4H-1,2,4-triazol-4-amine
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1-methylpyrazol-4-yl)methyl]-N-propan-2-ylpropanamide —— C17H22ClN3OS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1-methylpyrazol-4-yl)methyl]-N-propan-2-ylpropanamide
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-pyridin-2-ylmethanimine —— C15H13N5S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-pyridin-2-ylmethanimine
    —— (E)-3-(benzylthio)-N-(2-chloro-6-fluorobenzylidene)-4H-1,2,4-triazol-4-amine —— C16H12ClFN4S
    (E)-3-(benzylthio)-N-(2-chloro-6-fluorobenzylidene)-4H-1,2,4-triazol-4-amine
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-fluorophenyl)methanimine —— C16H13FN4S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-fluorophenyl)methanimine
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-chlorophenyl)methanimine —— C16H13ClN4S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-chlorophenyl)methanimine
    —— (2E)-2-[(piperidin-1-ylamino)methylidene]-1-benzothiophen-3-one —— C14H16N2OS
    (2E)-2-[(piperidin-1-ylamino)methylidene]-1-benzothiophen-3-one
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(E)-(2-bromophenyl)methylidene]acetohydrazide —— C18H15BrN4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(E)-(2-bromophenyl)methylidene]acetohydrazide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(4-fluorophenyl)methylideneamino]acetamide —— C18H14ClFN4OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(4-fluorophenyl)methylideneamino]acetamide
    —— 3-(benzylsulfanyl)-N-[(E)-(2-fluorophenyl)methylidene]-4H-1,2,4-triazol-4-amine —— C16H13FN4S
    3-(benzylsulfanyl)-N-[(E)-(2-fluorophenyl)methylidene]-4H-1,2,4-triazol-4-amine
    —— N'-[(E)-(4-chlorophenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C19H17ClN4OS3
    N'-[(E)-(4-chlorophenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 2-((5-(Benzylthio)-1,3,4-thiadiazol-2-yl)thio)-N'-(4-chlorobenzylidene)acetohydrazide 315201-05-9 C18H15ClN4OS3
    2-((5-(Benzylthio)-1,3,4-thiadiazol-2-yl)thio)-N'-(4-chlorobenzylidene)acetohydrazide
    —— (Hydroxyimino)(5-methyl-2-methylthio(3-thienyl))methane —— C7H9NOS2
    (Hydroxyimino)(5-methyl-2-methylthio(3-thienyl))methane
    —— 3-[(4-bromobenzyl)sulfanyl]-5-methyl-N-[(E)-phenylmethylidene]-4H-1,2,4-triazol-4-amine —— C17H15BrN4S
    3-[(4-bromobenzyl)sulfanyl]-5-methyl-N-[(E)-phenylmethylidene]-4H-1,2,4-triazol-4-amine
    —— N-[(1S)-2-ethyl-1-thiophen-2-ylbutyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C14H19N3OS3
    N-[(1S)-2-ethyl-1-thiophen-2-ylbutyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(1-methylpyrrol-2-yl)methylideneamino]acetamide —— C17H16ClN5OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(1-methylpyrrol-2-yl)methylideneamino]acetamide
    —— N-(5-{2-[(2E)-2-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)hydrazinyl]-2-oxoethyl}-1,3,4-thiadiazol-2-yl)-2-methylbenzamide —— C23H18ClN5O3S2
    N-(5-{2-[(2E)-2-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)hydrazinyl]-2-oxoethyl}-1,3,4-thiadiazol-2-yl)-2-methylbenzamide
    —— (2R)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-propylsulfonylpropanamide —— C18H23N3O3S2
    (2R)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-propylsulfonylpropanamide
    —— 2-(5-bromopyridin-2-yl)sulfanyl-N-[(4-ethyl-1,2,4-triazol-3-yl)methyl]benzamide —— C17H16BrN5OS
    2-(5-bromopyridin-2-yl)sulfanyl-N-[(4-ethyl-1,2,4-triazol-3-yl)methyl]benzamide
    —— (2E)-N-ethyl-2-{2-[({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetyl]hydrazinylidene}ethanethioamide —— C16H19N5OS4
    (2E)-N-ethyl-2-{2-[({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetyl]hydrazinylidene}ethanethioamide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(5-methylthiophen-2-yl)methylideneamino]acetamide —— C17H15ClN4OS4
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(5-methylthiophen-2-yl)methylideneamino]acetamide
    —— 2-(5-bromopyridin-2-yl)sulfanyl-N-[(2S)-1-imidazol-1-ylpropan-2-yl]benzamide —— C18H17BrN4OS
    2-(5-bromopyridin-2-yl)sulfanyl-N-[(2S)-1-imidazol-1-ylpropan-2-yl]benzamide
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(3-chlorophenyl)methylidene]acetohydrazide —— C18H14Cl2N4OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(3-chlorophenyl)methylidene]acetohydrazide
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(5-methylfuran-2-yl)methylidene]acetohydrazide —— C17H15ClN4O2S3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(5-methylfuran-2-yl)methylidene]acetohydrazide
    —— (2S)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-propylsulfonylpropanamide —— C18H23N3O3S2
    (2S)-N-[4-(4,6-dimethylpyrimidin-2-yl)sulfanylphenyl]-2-propylsulfonylpropanamide
    —— N'-[(E)-(1-ethyl-3,5-dimethyl-1H-pyrazol-4-yl)methylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide —— C15H19N5OS
    N'-[(E)-(1-ethyl-3,5-dimethyl-1H-pyrazol-4-yl)methylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide
    —— N-[(3-bromo-5-fluorophenyl)methyl]-2-pyridin-4-ylsulfanylacetamide —— C14H12BrFN2OS
    N-[(3-bromo-5-fluorophenyl)methyl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-thiophen-2-ylpropyl]acetamide —— C17H20N4O2S2
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-thiophen-2-ylpropyl]acetamide
    —— 2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide —— C20H20N4OS3
    2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylpropyl]acetamide —— C17H20N4O2S2
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylpropyl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-thiophen-2-ylpropyl]acetamide —— C17H16ClN3O2S2
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-thiophen-2-ylpropyl]acetamide
    —— (4,6-Dimethyl-pyrimidin-2-ylsulfanyl)-acetic acid [(Z)-2-methyl-3-phenyl-prop-2-en-(E)-ylidene]-hydrazide —— C18H20N4OS
    (4,6-Dimethyl-pyrimidin-2-ylsulfanyl)-acetic acid [(Z)-2-methyl-3-phenyl-prop-2-en-(E)-ylidene]-hydrazide
    —— N'-(2-BR-3-PH-2-Propenylidene)2-((4,6-dimethyl-2-pyrimidinyl)thio)acetohydrazide —— C17H17BrN4OS
    N'-(2-BR-3-PH-2-Propenylidene)2-((4,6-dimethyl-2-pyrimidinyl)thio)acetohydrazide
    —— 2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(2E)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide —— C18H20N4OS
    2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(2E)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(4-methylphenyl)methanimine —— C17H15ClN4S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(4-methylphenyl)methanimine
    —— (2S)-N-[(Z)-1-(4-bromophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanamide —— C17H19BrN4OS
    (2S)-N-[(Z)-1-(4-bromophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanamide
    —— N-[(E)-{4-bromo-5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]-4H-1,2,4-triazol-4-amine —— C14H11BrN4OS
    N-[(E)-{4-bromo-5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene]-4H-1,2,4-triazol-4-amine
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]propanamide —— C23H26N6OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]propanamide
    —— N-[(E)-{4-[(4-chlorophenyl)sulfanyl]phenyl}methylidene]-4H-1,2,4-triazol-4-amine —— C15H11ClN4S
    N-[(E)-{4-[(4-chlorophenyl)sulfanyl]phenyl}methylidene]-4H-1,2,4-triazol-4-amine
    —— 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-N-[[(2R)-1,4-dioxan-2-yl]methyl]benzamide —— C20H21N3O3S2
    2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-N-[[(2R)-1,4-dioxan-2-yl]methyl]benzamide
    —— (2Z)-2-[1-(3-methylanilino)ethylidene]-1-benzothiophen-3-one —— C17H15NOS
    (2Z)-2-[1-(3-methylanilino)ethylidene]-1-benzothiophen-3-one
    —— (2E)-2-[1-(3-chloroanilino)ethylidene]-1-benzothiophen-3-one —— C16H12ClNOS
    (2E)-2-[1-(3-chloroanilino)ethylidene]-1-benzothiophen-3-one
    —— (E)-1-(2-methoxy-5-methylsulfanylthiophen-3-yl)-N-(1,2,4-triazol-4-yl)methanimine —— C9H10N4OS2
    (E)-1-(2-methoxy-5-methylsulfanylthiophen-3-yl)-N-(1,2,4-triazol-4-yl)methanimine