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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3-bromoimidazo[1,2-b]pyridazin-6-yl)sulfanyl-N-[3-[tert-butyl(dimethyl)silyl]oxypropyl]acetamide —— C17H27BrN4O2SSi
    2-(3-bromoimidazo[1,2-b]pyridazin-6-yl)sulfanyl-N-[3-[tert-butyl(dimethyl)silyl]oxypropyl]acetamide
    —— (E)-10-butylsulfanyl-7-methyldec-6-en-2-yne —— C15H26S
    (E)-10-butylsulfanyl-7-methyldec-6-en-2-yne
    —— 1,4,8-Trimethyl-3-methylidenephenothiazine —— C16H15NS
    1,4,8-Trimethyl-3-methylidenephenothiazine
    —— 1,4,7-Trimethyl-3-methylidenephenothiazine —— C16H15NS
    1,4,7-Trimethyl-3-methylidenephenothiazine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-fluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C20H17FN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-fluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-pyridin-4-ylmethylideneamino]triazole-4-carboxamide —— C15H14N12O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-pyridin-4-ylmethylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-thiophen-2-ylmethylideneamino]triazole-4-carboxamide —— C18H16N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-thiophen-2-ylmethylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chlorophenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C16H14ClN11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chlorophenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(2-fluorophenyl)methylideneamino]triazole-4-carboxamide —— C19H14ClFN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(2-fluorophenyl)methylideneamino]triazole-4-carboxamide
    —— 2-(3-Methylbutyl)-2-(2-methylpropyl)-1,3-dithiolane —— C12H24S2
    2-(3-Methylbutyl)-2-(2-methylpropyl)-1,3-dithiolane
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(3-fluorophenyl)methylideneamino]triazole-4-carboxamide —— C19H14ClFN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-(3-fluorophenyl)methylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(3-chlorophenyl)methylideneamino]-5-[(4-chlorophenyl)sulfanylmethyl]triazole-4-carboxamide —— C19H14Cl2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(3-chlorophenyl)methylideneamino]-5-[(4-chlorophenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C19H18N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-2-ylmethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-2-ylmethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylphenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C21H20N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylphenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-fluorophenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C16H14FN11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-fluorophenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chlorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C20H17ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chlorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-thiophen-2-ylmethylideneamino]triazole-4-carboxamide —— C14H13N11O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-thiophen-2-ylmethylideneamino]triazole-4-carboxamide
    —— 4-Methylsulfinylbut-1-en-2-amine —— C5H11NOS
    4-Methylsulfinylbut-1-en-2-amine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-furan-2-ylmethylideneamino]triazole-4-carboxamide —— C17H13ClN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-furan-2-ylmethylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C18H20N12O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C22H23N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C16H13ClFN11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— [3-(4-amino-1,2,5-oxadiazol-3-yl)-5-[[(Z)-(4-methylsulfanylphenyl)methylideneamino]carbamoyl]triazol-4-yl]methyl-cyclohexyl-methylazanium —— C21H28N9O2S+
    [3-(4-amino-1,2,5-oxadiazol-3-yl)-5-[[(Z)-(4-methylsulfanylphenyl)methylideneamino]carbamoyl]triazol-4-yl]methyl-cyclohexyl-methylazanium
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[[cyclohexyl(methyl)amino]methyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide —— C21H27N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[[cyclohexyl(methyl)amino]methyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-thiophen-2-yltriazole-4-carboxamide —— C17H14N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-thiophen-2-yltriazole-4-carboxamide
    —— 5-(furan-2-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-pyrazole-3-carboxamide —— C16H14N4O2S
    5-(furan-2-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-pyrazole-3-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C17H17N11O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-3-ylmethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C14H13N11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-3-ylmethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C20H16ClFN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C15H15N11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 4-(1-Methylpyridin-1-ium-4-yl)-2-propan-2-ylsulfanyl-1,3-thiazole —— C12H15N2S2+
    4-(1-Methylpyridin-1-ium-4-yl)-2-propan-2-ylsulfanyl-1,3-thiazole
    —— (5Z,9S,10S,13Z)-12-(1-methoxyethenylamino)-9,10-dimethyl-11-methylidene-13-[2-(methyltrisulfanyl)ethylidene]bicyclo[7.3.1]trideca-1(12),5-dien-3,7-diyn-2-ol —— C22H25NO2S3
    (5Z,9S,10S,13Z)-12-(1-methoxyethenylamino)-9,10-dimethyl-11-methylidene-13-[2-(methyltrisulfanyl)ethylidene]bicyclo[7.3.1]trideca-1(12),5-dien-3,7-diyn-2-ol
    —— Iodo-(methyldisulfanyl)methane —— C2H5IS2
    Iodo-(methyldisulfanyl)methane
    —— 2-Methylsulfanyl-5-[6-(trifluoromethyl)pyridin-2-yl]pyrimidine —— C11H8F3N3S
    2-Methylsulfanyl-5-[6-(trifluoromethyl)pyridin-2-yl]pyrimidine
    —— Difluoroboranyl difluoro(methylsulfinyl)methanesulfinate —— C2H3BF4O3S2
    Difluoroboranyl difluoro(methylsulfinyl)methanesulfinate
    —— Hexasulfanyl ethanedithioate —— C2H4S8
    Hexasulfanyl ethanedithioate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-pyridin-3-ylmethylideneamino]triazole-4-carboxamide —— C18H15N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-pyridin-3-ylmethylideneamino]triazole-4-carboxamide
    —— 1-Methoxybutane-1-thiol —— C5H12OS
    1-Methoxybutane-1-thiol
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-thiophen-2-ylmethylideneamino]triazole-4-carboxamide —— C17H14N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-thiophen-2-ylmethylideneamino]triazole-4-carboxamide
    —— 3,5-dimethyl-4-(3-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridin-5-yl)isoxazole —— C18H15N3OS
    3,5-dimethyl-4-(3-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridin-5-yl)isoxazole
    —— (1,1,1-Trifluoro-4-methylsulfonylbutan-2-yl)carbamic acid —— C6H10F3NO4S
    (1,1,1-Trifluoro-4-methylsulfonylbutan-2-yl)carbamic acid
    —— Methyl 4-(hydroxymethylsulfonyl)cyclohexane-1-carboxylate —— C9H16O5S
    Methyl 4-(hydroxymethylsulfonyl)cyclohexane-1-carboxylate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C20H18N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— [3-(Aminomethylsulfanyl)-2-methylphenyl]sulfanylmethanamine —— C9H14N2S2
    [3-(Aminomethylsulfanyl)-2-methylphenyl]sulfanylmethanamine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-fluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H15FN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-fluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 1-Phosphorosooctane-2-thiol —— C8H17OPS
    1-Phosphorosooctane-2-thiol
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-benzylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H16N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-benzylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H14ClFN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-thiophen-3-ylmethylideneamino]triazole-4-carboxamide —— C17H14N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-thiophen-3-ylmethylideneamino]triazole-4-carboxamide