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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2Z)-6,6-dimethyl-2-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-one —— C16H18N2OS2
    (2Z)-6,6-dimethyl-2-[(4-methylsulfanylphenyl)methylidene]-5,7-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-one
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2,4-dinitroaniline —— C19H12ClN5O6S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2,4-dinitroaniline
    —— (Z)-3-[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]-2-(4-chlorophenyl)sulfonylprop-2-enenitrile —— C21H12Cl2N2O4S2
    (Z)-3-[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]-2-(4-chlorophenyl)sulfonylprop-2-enenitrile
    —— 2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[2,2-dichloro-1-(2,2-dimethylpropanoylamino)ethenyl]sulfanylpyrimidin-4-yl]oxyethyl]propanamide —— C18H23Cl5N4O3S
    2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[2,2-dichloro-1-(2,2-dimethylpropanoylamino)ethenyl]sulfanylpyrimidin-4-yl]oxyethyl]propanamide
    —— methyl N-[(1R)-2,2,2-trichloro-1-[(1S)-2,2,2-trichloro-1-(methoxycarbonylamino)ethyl]sulfanylethyl]carbamate —— C8H10Cl6N2O4S
    methyl N-[(1R)-2,2,2-trichloro-1-[(1S)-2,2,2-trichloro-1-(methoxycarbonylamino)ethyl]sulfanylethyl]carbamate
    —— (2R)-1-[[(2R)-2-amino-4-methylpentyl]disulfanyl]-4-methylpentan-2-amine —— C12H28N2S2
    (2R)-1-[[(2R)-2-amino-4-methylpentyl]disulfanyl]-4-methylpentan-2-amine
    —— (2S)-5-methyl-2-[4-[(2S)-5-methyl-1,3-benzodithiol-2-yl]phenyl]-1,3-benzodithiole —— C22H18S4
    (2S)-5-methyl-2-[4-[(2S)-5-methyl-1,3-benzodithiol-2-yl]phenyl]-1,3-benzodithiole
    —— 2-[[3-(3,4-dimethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-[1,3]thiazolo[4,5-d]pyrimidin-5-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C26H26N4O3S3
    2-[[3-(3,4-dimethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-[1,3]thiazolo[4,5-d]pyrimidin-5-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— N-[(2R)-butan-2-yl]-2-[[3-(3,4-dimethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-[1,3]thiazolo[4,5-d]pyrimidin-5-yl]sulfanyl]acetamide —— C25H26N4O2S3
    N-[(2R)-butan-2-yl]-2-[[3-(3,4-dimethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-[1,3]thiazolo[4,5-d]pyrimidin-5-yl]sulfanyl]acetamide
    —— (2R)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(2-methoxyethyl)butanamide —— C24H28N4O2S
    (2R)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(2-methoxyethyl)butanamide
    —— (2R)-2-[[5,6-bis(3-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylbutanamide —— C24H24F2N4OS
    (2R)-2-[[5,6-bis(3-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylbutanamide
    —— (2S)-2-[[5,6-bis(3-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylbutanamide —— C24H24F2N4OS
    (2S)-2-[[5,6-bis(3-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylbutanamide
    —— (2R)-2-[[5,6-bis(4-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-butylbutanamide —— C23H24F2N4OS
    (2R)-2-[[5,6-bis(4-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-butylbutanamide
    —— (7E)-3-(difluoromethyl)-6-(2,4-difluorophenyl)-7-(thiophen-2-ylmethylidene)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C16H8F4N4S2
    (7E)-3-(difluoromethyl)-6-(2,4-difluorophenyl)-7-(thiophen-2-ylmethylidene)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (7E)-3-(difluoromethyl)-6-(2,4-difluorophenyl)-7-(pyridin-2-ylmethylidene)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C17H9F4N5S
    (7E)-3-(difluoromethyl)-6-(2,4-difluorophenyl)-7-(pyridin-2-ylmethylidene)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— propan-2-yl (2Z,5S)-7-methyl-2-[(4-methylphenyl)methylidene]-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H26N2O3S2
    propan-2-yl (2Z,5S)-7-methyl-2-[(4-methylphenyl)methylidene]-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— methyl (2Z,5R)-2-[(3-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C23H19ClN2O3S2
    methyl (2Z,5R)-2-[(3-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 3-(2-methylsulfanylphenyl)-4,5-dihydro-2H-pyrrolo[3,2-d][1,2]oxazole —— C12H12N2OS
    3-(2-methylsulfanylphenyl)-4,5-dihydro-2H-pyrrolo[3,2-d][1,2]oxazole
    —— prop-2-enyl (2Z,5R)-7-methyl-2-[(4-methylphenyl)methylidene]-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H24N2O3S2
    prop-2-enyl (2Z,5R)-7-methyl-2-[(4-methylphenyl)methylidene]-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— methyl (2Z,5R)-2-[(2-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C23H19ClN2O3S2
    methyl (2Z,5R)-2-[(2-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (3S)-3-(4-fluorophenyl)sulfanylpiperidine —— C11H14FNS
    (3S)-3-(4-fluorophenyl)sulfanylpiperidine
    —— (5Z)-3-(2-chlorophenyl)-5-[[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C22H12Cl2N2O3S3
    (5Z)-3-(2-chlorophenyl)-5-[[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5Z)-3-benzyl-5-[[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H15ClN2O3S3
    (5Z)-3-benzyl-5-[[2-(4-chlorophenyl)sulfanyl-5-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (4R)-2-amino-7,7-dimethyl-4-(5-methyl-2-methylsulfanylthiophen-3-yl)-5-oxo-1-pyridin-3-yl-6,8-dihydro-4H-quinoline-3-carbonitrile —— C23H24N4OS2
    (4R)-2-amino-7,7-dimethyl-4-(5-methyl-2-methylsulfanylthiophen-3-yl)-5-oxo-1-pyridin-3-yl-6,8-dihydro-4H-quinoline-3-carbonitrile
    —— 1-chloro-4-[(2S)-2-chloro-1,1,2-trifluoroethyl]sulfanylbenzene —— C8H5Cl2F3S
    1-chloro-4-[(2S)-2-chloro-1,1,2-trifluoroethyl]sulfanylbenzene
    —— (2R)-2-(3-chlorophenyl)-3,1-benzoxathiin-4-one —— C14H9ClO2S
    (2R)-2-(3-chlorophenyl)-3,1-benzoxathiin-4-one
    —— 2,2-dichloro-N-[(2S)-1-hydroxy-3-(methylsulfanylmethylsulfanyl)propan-2-yl]acetamide —— C7H13Cl2NO2S2
    2,2-dichloro-N-[(2S)-1-hydroxy-3-(methylsulfanylmethylsulfanyl)propan-2-yl]acetamide
    —— (3S)-N-methyl-3-(2-methylphenyl)sulfanyl-3-phenylpropan-1-amine —— C17H21NS
    (3S)-N-methyl-3-(2-methylphenyl)sulfanyl-3-phenylpropan-1-amine
    —— potassium;5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole-2-thiolate —— C9H6ClKN2S3
    potassium;5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole-2-thiolate
    —— iodozinc(1+);methylsulfanylbenzene —— C7H7ISZn
    iodozinc(1+);methylsulfanylbenzene
    —— (1R,8R)-N,N-dimethyl-9,9-dioxo-9lambda6-thiabicyclo[6.2.0]decan-1-amine —— C11H21NO2S
    (1R,8R)-N,N-dimethyl-9,9-dioxo-9lambda6-thiabicyclo[6.2.0]decan-1-amine
    —— (1S,7S)-N,N-dimethyl-8,8-dioxo-8lambda6-thiabicyclo[5.2.0]nonan-1-amine —— C10H19NO2S
    (1S,7S)-N,N-dimethyl-8,8-dioxo-8lambda6-thiabicyclo[5.2.0]nonan-1-amine
    —— (1R,7R)-N,N-dimethyl-8,8-dioxo-8lambda6-thiabicyclo[5.2.0]nonan-1-amine —— C10H19NO2S
    (1R,7R)-N,N-dimethyl-8,8-dioxo-8lambda6-thiabicyclo[5.2.0]nonan-1-amine
    —— (2R)-2-chloro-2-[(S)-chloro(phenyl)methyl]-5-methyl-1-benzothiophen-3-one —— C16H12Cl2OS
    (2R)-2-chloro-2-[(S)-chloro(phenyl)methyl]-5-methyl-1-benzothiophen-3-one
    —— [(2S)-1-hydroxy-3-(methylsulfanylmethylsulfanyl)propan-2-yl]urea —— C6H14N2O2S2
    [(2S)-1-hydroxy-3-(methylsulfanylmethylsulfanyl)propan-2-yl]urea
    —— 2-[(R)-ethylsulfonyl(methylsulfonyl)methyl]sulfonylpropane —— C7H16O6S3
    2-[(R)-ethylsulfonyl(methylsulfonyl)methyl]sulfonylpropane
    —— 2-[(R)-1,3-dithian-2-yl(hydroxy)methyl]-1,3-dithiane-2-carbaldehyde —— C10H16O2S4
    2-[(R)-1,3-dithian-2-yl(hydroxy)methyl]-1,3-dithiane-2-carbaldehyde
    —— 1-[(2R,3R)-3-(2,2-dimethylpropanoyl)-1,1-dioxothiiran-2-yl]-2,2-dimethylpropan-1-one —— C12H20O4S
    1-[(2R,3R)-3-(2,2-dimethylpropanoyl)-1,1-dioxothiiran-2-yl]-2,2-dimethylpropan-1-one
    —— ethyl (4aR)-spiro[1,2,3,4,5,6-hexahydronaphthalene-7,2'-1,3-dithiolane]-4a-carboxylate —— C15H22O2S2
    ethyl (4aR)-spiro[1,2,3,4,5,6-hexahydronaphthalene-7,2'-1,3-dithiolane]-4a-carboxylate
    —— 2-[(2R,3R)-2-ethyl-3-(2-hydroxyethylsulfanyl)hexyl]sulfanylethanol —— C12H26O2S2
    2-[(2R,3R)-2-ethyl-3-(2-hydroxyethylsulfanyl)hexyl]sulfanylethanol
    —— (1S,2S)-1-ethylsulfonyl-2-[(2-methylpropan-2-yl)oxy]cyclobutane —— C10H20O3S
    (1S,2S)-1-ethylsulfonyl-2-[(2-methylpropan-2-yl)oxy]cyclobutane
    —— (2S)-2-(4-hydroxyphenyl)-3,1-benzoxathiin-4-one —— C14H10O3S
    (2S)-2-(4-hydroxyphenyl)-3,1-benzoxathiin-4-one
    —— (1R,2S)-1-ethylsulfonyl-2-[(2-methylpropan-2-yl)oxy]cyclobutane —— C10H20O3S
    (1R,2S)-1-ethylsulfonyl-2-[(2-methylpropan-2-yl)oxy]cyclobutane
    —— 1-chloro-4-[(1R,2R)-2-chlorocyclopentyl]sulfanylbenzene —— C11H12Cl2S
    1-chloro-4-[(1R,2R)-2-chlorocyclopentyl]sulfanylbenzene
    —— (2S)-2-(3-chlorophenyl)-3,1-benzoxathiin-4-one —— C14H9ClO2S
    (2S)-2-(3-chlorophenyl)-3,1-benzoxathiin-4-one
    —— (2R)-1,1-bis(ethylsulfonyl)-2-methyloctane —— C13H28O4S2
    (2R)-1,1-bis(ethylsulfonyl)-2-methyloctane
    —— (2E)-2-[hydroxy(phenyl)methylidene]-1-benzothiophen-3-one —— C15H10O2S
    (2E)-2-[hydroxy(phenyl)methylidene]-1-benzothiophen-3-one
    —— 3-(Methylthio)phenylZinc bromide —— C7H7BrSZn
    3-(Methylthio)phenylZinc bromide
    —— cis-2-Phenyl-5-oxo-cyclohexancarbonsaeure-aethylenthioketal 31730-02-6 C15H18O2S2
    cis-2-Phenyl-5-oxo-cyclohexancarbonsaeure-aethylenthioketal
    —— (7R,8R)-8-phenyl-1,4-dithiaspiro[4.5]decane-7-carboxylic acid —— C15H18O2S2
    (7R,8R)-8-phenyl-1,4-dithiaspiro[4.5]decane-7-carboxylic acid