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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(5-methyl-1H-imidazol-2-yl)sulfanyl]pyrazine-2-carbonitrile —— C9H7N5S
    3-[(5-methyl-1H-imidazol-2-yl)sulfanyl]pyrazine-2-carbonitrile
    —— 4-[2-[6-amino-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-3-yl]ethyl]phenol —— C21H22N5O3S+
    4-[2-[6-amino-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-3-yl]ethyl]phenol
    —— Ethane;2-(4-phenylsulfanylphenyl)acetonitrile —— C16H17NS
    Ethane;2-(4-phenylsulfanylphenyl)acetonitrile
    —— N-[(4-methyl-5H-1,2,4-oxadiazol-3-yl)methyl]-2-phenylsulfanylacetamide —— C12H15N3O2S
    N-[(4-methyl-5H-1,2,4-oxadiazol-3-yl)methyl]-2-phenylsulfanylacetamide
    —— 1-[2-[2-(2-Hydroxyethylsulfanyl)ethylsulfanyl]ethoxysulfanyl]ethane-1,1-diol —— C8H18O4S3
    1-[2-[2-(2-Hydroxyethylsulfanyl)ethylsulfanyl]ethoxysulfanyl]ethane-1,1-diol
    —— 6-[2-(Methoxycarbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole —— C22H18N4O2S
    6-[2-(Methoxycarbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole
    —— 1-Hydroxy-3-methanethioylurea —— C2H4N2O2S
    1-Hydroxy-3-methanethioylurea
    —— 2-[4-[[7-(difluoromethoxy)-1,5-naphthyridin-4-yl]sulfanyl]phenyl]-4-phenyl-1H-phthalazin-1-amine —— C29H21F2N5OS
    2-[4-[[7-(difluoromethoxy)-1,5-naphthyridin-4-yl]sulfanyl]phenyl]-4-phenyl-1H-phthalazin-1-amine
    —— Ethyl 3-(4-methylphenyl)sulfanyl-2-[(4-methylphenyl)sulfanylmethyl]-4,5-dioxooxolane-2-carboxylate —— C22H22O5S2
    Ethyl 3-(4-methylphenyl)sulfanyl-2-[(4-methylphenyl)sulfanylmethyl]-4,5-dioxooxolane-2-carboxylate
    —— 2-Bromo-5-(3-phenylsulfanylpropyl)thiophene —— C13H13BrS2
    2-Bromo-5-(3-phenylsulfanylpropyl)thiophene
    —— 1-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-phenylurea —— C21H18N4O3S
    1-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-phenylurea
    —— Prop-2-enyl 2-(2-prop-2-enoxycarbonylsulfanylethylsulfanylcarbothioyloxy)ethylsulfanylformate —— C13H18O5S4
    Prop-2-enyl 2-(2-prop-2-enoxycarbonylsulfanylethylsulfanylcarbothioyloxy)ethylsulfanylformate
    —— 3-methyl-N-[(E)-2-methylsulfonylethenyl]butan-1-imine —— C8H15NO2S
    3-methyl-N-[(E)-2-methylsulfonylethenyl]butan-1-imine
    —— 1-methyl-4-[(E)-1-phenylprop-1-en-2-yl]sulfanylbenzene —— C16H16S
    1-methyl-4-[(E)-1-phenylprop-1-en-2-yl]sulfanylbenzene
    —— N-[7-(hydroxyamino)-7-oxoheptyl]-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide —— C28H29N5O3S
    N-[7-(hydroxyamino)-7-oxoheptyl]-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide
    —— N-methyl-2-[[3-[2-(4-methylpyridin-2-yl)ethenyl]-1H-indazol-6-yl]sulfanyl]benzamide —— C23H20N4OS
    N-methyl-2-[[3-[2-(4-methylpyridin-2-yl)ethenyl]-1H-indazol-6-yl]sulfanyl]benzamide
    —— 1-[5-(2-methylphenyl)-4-phenylsulfanylfuran-2-yl]ethyl N-tert-butylcarbamate —— C24H27NO3S
    1-[5-(2-methylphenyl)-4-phenylsulfanylfuran-2-yl]ethyl N-tert-butylcarbamate
    —— 6-[[6-amino-3-[2-(1-formylpiperidin-4-yl)ethyl]-7H-purin-3-ium-8-yl]sulfanyl]-2,3-dihydro-1,4-benzodioxine-7-carbonitrile —— C22H24N7O3S+
    6-[[6-amino-3-[2-(1-formylpiperidin-4-yl)ethyl]-7H-purin-3-ium-8-yl]sulfanyl]-2,3-dihydro-1,4-benzodioxine-7-carbonitrile
    —— 1-[4-[(2,5-Dihydroxy-3-propylsulfanylpyrrol-1-yl)methyl]cyclohexyl]ethanone —— C16H25NO3S
    1-[4-[(2,5-Dihydroxy-3-propylsulfanylpyrrol-1-yl)methyl]cyclohexyl]ethanone
    —— 1-[C-(2-imino-3,3-dimethylbutyl)-N-(4-methylphenyl)carbonimidoyl]-3-[5-[6-imino-1-[3-(2-morpholin-4-ylethoxy)benzenecarboximidoyl]pyridin-3-yl]sulfanylpyridin-2-yl]urea —— C38H45N9O3S
    1-[C-(2-imino-3,3-dimethylbutyl)-N-(4-methylphenyl)carbonimidoyl]-3-[5-[6-imino-1-[3-(2-morpholin-4-ylethoxy)benzenecarboximidoyl]pyridin-3-yl]sulfanylpyridin-2-yl]urea
    —— 3-[5-[1-(3,4-Dimethoxyphenyl)-2-pyridin-4-ylethyl]pyridin-2-yl]sulfanylbenzenesulfonamide;ethane —— C30H37N3O4S2
    3-[5-[1-(3,4-Dimethoxyphenyl)-2-pyridin-4-ylethyl]pyridin-2-yl]sulfanylbenzenesulfonamide;ethane
    —— 3-Amino-1-[3-(cyclohexylmethylsulfanyl)phenyl]butane-1,3-diol —— C17H27NO2S
    3-Amino-1-[3-(cyclohexylmethylsulfanyl)phenyl]butane-1,3-diol
    —— 2-[3-[3-[Hexylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl]butanoic acid —— C31H38N2O3S
    2-[3-[3-[Hexylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl]butanoic acid
    —— 2-[1,3-Bis(oxiran-2-ylmethoxy)cyclohexyl]-3-[(oxiran-2-ylmethyldisulfanyl)methyl]oxirane —— C18H28O6S2
    2-[1,3-Bis(oxiran-2-ylmethoxy)cyclohexyl]-3-[(oxiran-2-ylmethyldisulfanyl)methyl]oxirane
    —— 2-(1-adamantyl)-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]acetamide —— C23H25N5O3S
    2-(1-adamantyl)-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]acetamide
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-[(4-bromophenyl)methylsulfanyl]acetamide —— C21H17BrN4O2S2
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-[(4-bromophenyl)methylsulfanyl]acetamide
    —— 2-[4-Methyl-2-(piperidin-4-ylamino)phenyl]sulfanylethanol —— C14H22N2OS
    2-[4-Methyl-2-(piperidin-4-ylamino)phenyl]sulfanylethanol
    —— Fluoromethoxymethanethiol —— C2H5FOS
    Fluoromethoxymethanethiol
    —— 2-Ethylsulfanylicosa-4,8,11,14,17-pentaen-1-ol —— C22H36OS
    2-Ethylsulfanylicosa-4,8,11,14,17-pentaen-1-ol
    —— (2,5-Dihydroxypyrrol-1-yl) 6-[2-[6-(2,5-dihydroxypyrrol-1-yl)oxy-5,5-dimethyl-6-oxohexyl]-1,3-dithian-2-yl]-2,2-dimethylhexanoate —— C28H42N2O8S2
    (2,5-Dihydroxypyrrol-1-yl) 6-[2-[6-(2,5-dihydroxypyrrol-1-yl)oxy-5,5-dimethyl-6-oxohexyl]-1,3-dithian-2-yl]-2,2-dimethylhexanoate
    —— 3-Aminopropyl-(methylsulfanylmethoxy)-oxophosphanium —— C5H13NO2PS+
    3-Aminopropyl-(methylsulfanylmethoxy)-oxophosphanium
    —— 2-Prop-2-enylsulfanylethyl hydrogen sulfite —— C5H10O3S2
    2-Prop-2-enylsulfanylethyl hydrogen sulfite
    —— 6-(Cyclopropylmethylsulfanyl)-2-[1-(cyclopropylmethylsulfanyl)ethyl]-5-[2-(cyclopropylmethylsulfanyl)ethyl]-1,4-dithiepane;2-[3-(cyclopropylmethylsulfanyl)-1-ethenylsulfanylbutan-2-yl]sulfanylethylsulfanylmethylcyclopropane —— C37H64S9
    6-(Cyclopropylmethylsulfanyl)-2-[1-(cyclopropylmethylsulfanyl)ethyl]-5-[2-(cyclopropylmethylsulfanyl)ethyl]-1,4-dithiepane;2-[3-(cyclopropylmethylsulfanyl)-1-ethenylsulfanylbutan-2-yl]sulfanylethylsulfanylmethylcyclopropane
    —— 2-nitro-N'-{(Z)-[5-(pyridin-2-ylsulfanyl)furan-2-yl]methylidene}benzohydrazide —— C17H12N4O4S
    2-nitro-N'-{(Z)-[5-(pyridin-2-ylsulfanyl)furan-2-yl]methylidene}benzohydrazide
    —— [2-Methylidene-3-(phenylsulfanylmethyl)but-3-enyl]sulfanylbenzene —— C18H18S2
    [2-Methylidene-3-(phenylsulfanylmethyl)but-3-enyl]sulfanylbenzene
    —— (NE)-N-[1-(3-methylsulfanylthiophen-2-yl)ethylidene]hydroxylamine —— C7H9NOS2
    (NE)-N-[1-(3-methylsulfanylthiophen-2-yl)ethylidene]hydroxylamine
    —— [2-(1,4-Dithian-2-ylsulfanylmethyl)-1,3-dithiolan-2-yl]methanethiol —— C9H16S6
    [2-(1,4-Dithian-2-ylsulfanylmethyl)-1,3-dithiolan-2-yl]methanethiol
    —— 4,6-Dichloro-2-[(2,3-difluorophenyl)methylsulfanyl]-5-(nitrosomethyl)pyrimidine —— C12H7Cl2F2N3OS
    4,6-Dichloro-2-[(2,3-difluorophenyl)methylsulfanyl]-5-(nitrosomethyl)pyrimidine
    —— 4-(4-Chlorobutylsulfanyl)-4-fluorobutane-1-thiol —— C8H16ClFS2
    4-(4-Chlorobutylsulfanyl)-4-fluorobutane-1-thiol
    —— 1-(Disulfanyl)-1-(disulfanylmethyl)cyclobutane —— C5H10S4
    1-(Disulfanyl)-1-(disulfanylmethyl)cyclobutane
    —— 4-(2-Sulfanylpropylsulfanyl)cyclohexane-1-thiol —— C9H18S3
    4-(2-Sulfanylpropylsulfanyl)cyclohexane-1-thiol
    —— 6-[2-[(Methylideneamino)methyl]pent-4-enylsulfanyl]hexan-1-ol —— C13H25NOS
    6-[2-[(Methylideneamino)methyl]pent-4-enylsulfanyl]hexan-1-ol
    —— 2-[(2,5-dihydroxy-1H-pyrrol-3-yl)sulfanyl]pyridine-3-carboxylic acid —— C10H8N2O4S
    2-[(2,5-dihydroxy-1H-pyrrol-3-yl)sulfanyl]pyridine-3-carboxylic acid
    —— 1-Sulfosulfonylpropane —— C3H8O5S2
    1-Sulfosulfonylpropane
    —— 4-(3-Ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)butan-2-one —— C10H15NO3S
    4-(3-Ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)butan-2-one
    —— 2-[4-[(7-methoxy-1,5-naphthyridin-4-yl)sulfanyl]phenyl]-4-(4-methoxypiperidin-1-yl)-1H-phthalazin-1-amine —— C29H30N6O2S
    2-[4-[(7-methoxy-1,5-naphthyridin-4-yl)sulfanyl]phenyl]-4-(4-methoxypiperidin-1-yl)-1H-phthalazin-1-amine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(furan-2-yl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C19H18N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(furan-2-yl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]-2-(2-methylphenoxy)acetamide —— C20H19N5O4S
    N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]-2-(2-methylphenoxy)acetamide
    —— tert-butyl (1R)-2-((2-(dimethylamino)ethyl)(methyl)amino)-1-((phenylthio)methyl)ethylcarbamate 406233-99-6 C19H33N3O2S
    tert-butyl (1R)-2-((2-(dimethylamino)ethyl)(methyl)amino)-1-((phenylthio)methyl)ethylcarbamate
    —— 4-methyl-5-[4-methyl-5-[3-[(1S,5R)-1-(2-methylpyrimidin-5-yl)-3-azabicyclo[3.1.0]hexan-3-yl]propylsulfanyl]-1,2,4-triazol-3-yl]-1,3-oxazole —— C20H25N7OS
    4-methyl-5-[4-methyl-5-[3-[(1S,5R)-1-(2-methylpyrimidin-5-yl)-3-azabicyclo[3.1.0]hexan-3-yl]propylsulfanyl]-1,2,4-triazol-3-yl]-1,3-oxazole