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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-N-(2-fluoroethyl)-3-[(4-fluorophenyl)sulfanylmethyl]-3-[2-(3-morpholin-4-ylpropyl)hydrazinyl]-4-phenylsulfanylbutan-1-amine —— C26H38F2N4OS2
    (3R)-N-(2-fluoroethyl)-3-[(4-fluorophenyl)sulfanylmethyl]-3-[2-(3-morpholin-4-ylpropyl)hydrazinyl]-4-phenylsulfanylbutan-1-amine
    —— (2E)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-cyano-N-(4-hydroxyphenyl)prop-2-enamide —— C21H14N4O3S
    (2E)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-cyano-N-(4-hydroxyphenyl)prop-2-enamide
    —— (3R)-3-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde —— C20H22BrN6O3S+
    (3R)-3-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde
    —— 4-Prop-2-enylsulfinylbut-1-ene —— C7H12OS
    4-Prop-2-enylsulfinylbut-1-ene
    —— (E)-3-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]prop-2-enoic acid —— C14H10ClNO2S
    (E)-3-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]prop-2-enoic acid
    —— Ethane;1-methyl-3-(2,3,4-trimethylpentan-2-ylsulfanyl)benzene —— C17H30S
    Ethane;1-methyl-3-(2,3,4-trimethylpentan-2-ylsulfanyl)benzene
    —— 2-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]pyrrolidine-1-carboxylic acid —— C19H20BrN6O4S+
    2-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]pyrrolidine-1-carboxylic acid
    —— 3-[2-(2-chloro-4-fluorophenyl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine —— C21H20ClFN5O2S+
    3-[2-(2-chloro-4-fluorophenyl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine
    —— (2E)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-furan-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C16H13F2N3O2S2
    (2E)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-furan-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanylphenyl]methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C21H19ClN4OS2
    N-[(Z)-[4-(4-chlorophenyl)sulfanylphenyl]methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— 9-methyl-3-[(Z)-(4-oxo-3-pentyl-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C24H23N3O2S3
    9-methyl-3-[(Z)-(4-oxo-3-pentyl-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— N-(4-quinazolin-2-ylsulfanylphenyl)methanesulfonamide —— C15H13N3O2S2
    N-(4-quinazolin-2-ylsulfanylphenyl)methanesulfonamide
    —— (5E)-5-({5-[(4-chlorophenyl)sulfanyl]thiophen-2-yl}methylidene)-3-methyl-1,3-thiazolidine-2,4-dione —— C15H10ClNO2S3
    (5E)-5-({5-[(4-chlorophenyl)sulfanyl]thiophen-2-yl}methylidene)-3-methyl-1,3-thiazolidine-2,4-dione
    —— [4-[3-[[4-(Dimethylamino)phenyl]carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C33H35N3O3S
    [4-[3-[[4-(Dimethylamino)phenyl]carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 2-Cyano-3-(2-methylpropylimino)butanethioamide —— C9H15N3S
    2-Cyano-3-(2-methylpropylimino)butanethioamide
    —— 6-(phenylsulfanyl)imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-methyloxime —— C13H11N3OS2
    6-(phenylsulfanyl)imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-methyloxime
    —— 2-(2,2-Dimethylpropyl)-3-methylsulfanyl-1,2-oxazol-2-ium —— C9H16NOS+
    2-(2,2-Dimethylpropyl)-3-methylsulfanyl-1,2-oxazol-2-ium
    —— (5Z)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2-morpholin-4-yl-2-oxoethyl)-1,3-thiazolidine-2,4-dione —— C22H18ClN3O6S2
    (5Z)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2-morpholin-4-yl-2-oxoethyl)-1,3-thiazolidine-2,4-dione
    —— 2-(1H-1,2,4-triazol-5-ylsulfanylmethyl)phenol —— C9H9N3OS
    2-(1H-1,2,4-triazol-5-ylsulfanylmethyl)phenol
    —— 2-(methylthio)thiazole-5-carbonitrile —— C5H4N2S2
    2-(methylthio)thiazole-5-carbonitrile
    —— 5-Chloro-2-methyl-3-phenylsulfanyl-1-benzofuran —— C15H11ClOS
    5-Chloro-2-methyl-3-phenylsulfanyl-1-benzofuran
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-3-(trifluoromethyl)benzamide —— C20H13F3N4O2S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-3-(trifluoromethyl)benzamide
    —— Butylsulfonyl-[dimethyl(2-oxobutyl)-lambda4-sulfanyl]oxidanium —— C10H23O4S2+
    Butylsulfonyl-[dimethyl(2-oxobutyl)-lambda4-sulfanyl]oxidanium
    —— 3-[1-(3-Chloro-4-fluorophenyl)-2,2-dihydroxy-2lambda4,4,1-benzodithiazin-3-yl]butan-1-amine —— C17H20ClFN2O2S2
    3-[1-(3-Chloro-4-fluorophenyl)-2,2-dihydroxy-2lambda4,4,1-benzodithiazin-3-yl]butan-1-amine
    —— 2-[1-o-Tolylamino-eth-(E)-ylidene]-benzo[b]thiophen-3-one 126318-44-3 C17H15NOS
    2-[1-o-Tolylamino-eth-(E)-ylidene]-benzo[b]thiophen-3-one
    —— (5R)-5-[(3S)-3-hydroxy-4-(3-methylphenyl)but-1-enyl]-1-[2-[[5-(hydroxymethyl)-1,3-thiazol-2-yl]sulfanyl]ethyl]pyrrolidin-2-one —— C21H26N2O3S2
    (5R)-5-[(3S)-3-hydroxy-4-(3-methylphenyl)but-1-enyl]-1-[2-[[5-(hydroxymethyl)-1,3-thiazol-2-yl]sulfanyl]ethyl]pyrrolidin-2-one
    —— 7-(1-Tert-butylcyclopropyl)-5-methyl-1-(2-propylcyclohexyl)-7-sulfanylideneheptan-3-one —— C24H42OS
    7-(1-Tert-butylcyclopropyl)-5-methyl-1-(2-propylcyclohexyl)-7-sulfanylideneheptan-3-one
    —— Methanamine;1-methyl-3,5-bis(methylsulfanyl)benzene —— C11H22N2S2
    Methanamine;1-methyl-3,5-bis(methylsulfanyl)benzene
    —— ethane;propane;10H-pyrazino[2,3-b][1,4]benzothiazine —— C15H21N3S
    ethane;propane;10H-pyrazino[2,3-b][1,4]benzothiazine
    —— (E)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-(6-methyl-1H-benzimidazol-2-yl)prop-2-enenitrile —— C22H15N5OS
    (E)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-2-(6-methyl-1H-benzimidazol-2-yl)prop-2-enenitrile
    —— N-methylsulfanyl-6-propylidenecyclohexa-2,4-dien-1-imine —— C10H13NS
    N-methylsulfanyl-6-propylidenecyclohexa-2,4-dien-1-imine
    —— 4-[2-[(2E)-2-benzylidenehydrazinyl]-3,5,6-trifluoropyridin-4-yl]sulfanyl-2,6-ditert-butylphenol —— C26H28F3N3OS
    4-[2-[(2E)-2-benzylidenehydrazinyl]-3,5,6-trifluoropyridin-4-yl]sulfanyl-2,6-ditert-butylphenol
    —— ethyl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C25H24N2O3S3
    ethyl (2Z)-7-methyl-5-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-methylbenzamide —— C21H16ClN3O3S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-methylbenzamide
    —— 3-Methylnona-2,4,6,8-tetraene-1-thiol —— C10H14S
    3-Methylnona-2,4,6,8-tetraene-1-thiol
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-(2-naphthalen-2-ylethyl)-7H-purin-3-ium-6-amine —— C24H19BrN5O2S+
    8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-3-(2-naphthalen-2-ylethyl)-7H-purin-3-ium-6-amine
    —— 1-[3-(6,7-dihydro-1H-benzimidazol-2-ylsulfanyl)phenyl]imino-4,7-diimino-5-phenyliminoheptan-3-one —— C26H24N6OS
    1-[3-(6,7-dihydro-1H-benzimidazol-2-ylsulfanyl)phenyl]imino-4,7-diimino-5-phenyliminoheptan-3-one
    —— methyl (2Z)-2-[[5-(2-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C27H21ClN2O4S2
    methyl (2Z)-2-[[5-(2-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-2-(furan-2-ylmethylidene)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C22H20N2O4S2
    ethyl (2Z)-2-(furan-2-ylmethylidene)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— methyl (2Z)-2-[(3-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C23H19ClN2O3S2
    methyl (2Z)-2-[(3-chlorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (5Z)-3-(3-chlorophenyl)-5-[4-(methylsulfanyl)benzylidene]-2-thioxo-1,3-thiazolidin-4-one —— C17H12ClNOS3
    (5Z)-3-(3-chlorophenyl)-5-[4-(methylsulfanyl)benzylidene]-2-thioxo-1,3-thiazolidin-4-one
    —— 5-Methylbicyclo[4.2.2]decane-2-thiol —— C11H20S
    5-Methylbicyclo[4.2.2]decane-2-thiol
    —— 3-{(Z)-[3-(3-ethoxypropyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-7-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C24H23N3O3S3
    3-{(Z)-[3-(3-ethoxypropyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-7-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— [5-(Cyclopropylmethyl)-2-(cyclopropylmethylsulfonyl)cyclohexyl]methanamine —— C15H27NO2S
    [5-(Cyclopropylmethyl)-2-(cyclopropylmethylsulfonyl)cyclohexyl]methanamine
    —— [4-[4-[(2-Nitrophenyl)carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C31H29N3O5S
    [4-[4-[(2-Nitrophenyl)carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— Benzenesulfonyl(methylsulfonyl)azanide;benzenesulfonyl(octylsulfonyl)azanide;1,2,4-trimethyl-5-(4-methylphenyl)sulfanylbenzene —— C53H66N2O8S6-2
    Benzenesulfonyl(methylsulfonyl)azanide;benzenesulfonyl(octylsulfonyl)azanide;1,2,4-trimethyl-5-(4-methylphenyl)sulfanylbenzene
    —— (Sulfinoamino)methylsulfonylethane —— C3H9NO4S2
    (Sulfinoamino)methylsulfonylethane
    —— 3-Ethyliminopropanethioamide —— C5H10N2S
    3-Ethyliminopropanethioamide
    —— Ethyl 2-(3-bromobenzylidene)-7-methyl-5-(4-(methylthio)phenyl)-3-oxo-3,5-dihydro-2H-thiazolo[3,2-a]pyrimidine-6-carboxylate 609796-18-1 C24H21BrN2O3S2
    Ethyl 2-(3-bromobenzylidene)-7-methyl-5-(4-(methylthio)phenyl)-3-oxo-3,5-dihydro-2H-thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 5-Ethylsulfonyl-2-propylidenehexa-3,5-dienoyl chloride —— C11H15ClO3S
    5-Ethylsulfonyl-2-propylidenehexa-3,5-dienoyl chloride