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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1R,2R)-2-tert-butylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C17H26N2OS
    N-[(1R,2R)-2-tert-butylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(1S,2S)-2-tert-butylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C17H26N2OS
    N-[(1S,2S)-2-tert-butylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(1R,2S)-2-tert-butylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C17H26N2OS
    N-[(1R,2S)-2-tert-butylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— (2R)-N-[(1S,2S)-2-methylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H21N3OS3
    (2R)-N-[(1S,2S)-2-methylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14FN3OS3
    N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-cyclopentyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C11H17N3OS3
    (2R)-N-cyclopentyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-cyclohexyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C12H19N3OS3
    (2R)-N-cyclohexyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H21N3OS3
    (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(2R)-3-methylbutan-2-yl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C10H17N3OS3
    N-[(2R)-3-methylbutan-2-yl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-cyclohexyl-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H24N4O2S2
    (2S)-N-cyclohexyl-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-(cyclohexylmethyl)-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H21N3OS3
    (2R)-N-(cyclohexylmethyl)-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-(2-fluorophenyl)sulfanylpropanamide —— C17H17F2NOS
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-(2-fluorophenyl)sulfanylpropanamide
    —— N-[(2R)-1-methoxypropan-2-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H20N4O2S
    N-[(2R)-1-methoxypropan-2-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-N-cyclopentyl-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C13H22N4O2S2
    (2S)-N-cyclopentyl-2-[[5-(2-methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H20N4OS
    (2S)-N-benzyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-1-(1-adamantyl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one —— C18H23NO2S
    (2S)-1-(1-adamantyl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylpropan-1-one
    —— (2R)-N-(cyclohexylmethyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H23N3OS3
    (2R)-N-(cyclohexylmethyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C18H22N4OS
    (2S)-N-benzyl-2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(2-fluorophenyl)sulfanylpropanamide —— C15H19FN2OS
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(2-fluorophenyl)sulfanylpropanamide
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2-fluorophenyl)sulfanylpropanamide —— C15H19FN2OS
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2-fluorophenyl)sulfanylpropanamide
    —— 2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C14H22N4O2S
    2-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— (2Z)-2-(4-methylpiperazin-1-yl)imino-1-(4-phenylsulfanylphenyl)ethanone;hydrochloride —— C19H22ClN3OS
    (2Z)-2-(4-methylpiperazin-1-yl)imino-1-(4-phenylsulfanylphenyl)ethanone;hydrochloride
    —— (2Z)-1-(4-phenylsulfanylphenyl)-2-piperidin-1-yliminoethanone —— C19H20N2OS
    (2Z)-1-(4-phenylsulfanylphenyl)-2-piperidin-1-yliminoethanone
    —— (2Z)-2-(dimethylhydrazinylidene)-1-(4-phenylsulfanylphenyl)ethanone —— C16H16N2OS
    (2Z)-2-(dimethylhydrazinylidene)-1-(4-phenylsulfanylphenyl)ethanone
    —— (1R)-N-methyl-1-(4-methylsulfanylphenyl)-N-[(2S)-pentan-2-yl]ethane-1,2-diamine —— C15H26N2S
    (1R)-N-methyl-1-(4-methylsulfanylphenyl)-N-[(2S)-pentan-2-yl]ethane-1,2-diamine
    —— (2R)-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]heptan-2-amine —— C16H27NS
    (2R)-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]heptan-2-amine
    —— (1S)-N-methyl-1-(4-methylsulfanylphenyl)-N-pentan-3-ylethane-1,2-diamine —— C15H26N2S
    (1S)-N-methyl-1-(4-methylsulfanylphenyl)-N-pentan-3-ylethane-1,2-diamine
    —— (1R)-N-methyl-N-[(2S)-3-methylbutan-2-yl]-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C15H26N2S
    (1R)-N-methyl-N-[(2S)-3-methylbutan-2-yl]-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— (1S,2S)-2-amino-1-(4-methylsulfanylphenyl)butan-1-ol —— C11H17NOS
    (1S,2S)-2-amino-1-(4-methylsulfanylphenyl)butan-1-ol
    —— [(Z)-but-2-en-2-yl]sulfanium;bromide —— C4H9BrS
    [(Z)-but-2-en-2-yl]sulfanium;bromide
    —— 2-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-6-methylpyrimidin-4-amine —— C13H14FN3S
    2-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-6-methylpyrimidin-4-amine
    —— (1S,2S)-2-amino-1-[4-(trifluoromethylsulfanyl)phenyl]butan-1-ol —— C11H14F3NOS
    (1S,2S)-2-amino-1-[4-(trifluoromethylsulfanyl)phenyl]butan-1-ol
    —— (1R,2R)-2-amino-1-(4-methylsulfanylphenyl)butan-1-ol —— C11H17NOS
    (1R,2R)-2-amino-1-(4-methylsulfanylphenyl)butan-1-ol
    —— (1R,2S)-2-amino-1-[4-(trifluoromethylsulfanyl)phenyl]butan-1-ol —— C11H14F3NOS
    (1R,2S)-2-amino-1-[4-(trifluoromethylsulfanyl)phenyl]butan-1-ol
    —— Ethylamine, 2,2'-dithiobis[n-[(2-benzylthio)ethyl]-, dihydrochloride —— C20H30Cl2N2S4
    Ethylamine, 2,2'-dithiobis[n-[(2-benzylthio)ethyl]-, dihydrochloride
    —— N.N'-Diacetyl-N.N'-bis-<5-benzylmercapto-1.3.4-thiodiazolyl-(2)>-hydrazin 102599-00-8 C22H20N6O2S4
    N.N'-Diacetyl-N.N'-bis-<5-benzylmercapto-1.3.4-thiodiazolyl-(2)>-hydrazin
    —— 1,3,6-Trimethyl-1,4-dihydro-pyrazolo[3,4-b][1,4]thiazin-5-one 13568-77-9 C8H11N3OS
    1,3,6-Trimethyl-1,4-dihydro-pyrazolo[3,4-b][1,4]thiazin-5-one
    —— (S)-(4-methylsulfanylphenyl)-(1,2,4-oxadiazol-3-yl)methanamine —— C10H11N3OS
    (S)-(4-methylsulfanylphenyl)-(1,2,4-oxadiazol-3-yl)methanamine
    —— (R)-(4-methylsulfanylphenyl)-(5-propyl-1,2,4-oxadiazol-3-yl)methanamine —— C13H17N3OS
    (R)-(4-methylsulfanylphenyl)-(5-propyl-1,2,4-oxadiazol-3-yl)methanamine
    —— 1,4-Butanedisulfonic acid, 1,4-dithio-, s,s'-bis(2-aminoethyl ester), dihydrobromide —— C8H22Br2N2O4S4
    1,4-Butanedisulfonic acid, 1,4-dithio-, s,s'-bis(2-aminoethyl ester), dihydrobromide
    —— 2-(2-Chloro-3,3,4,4,5,5-hexafluorocyclopenten-1-yl)sulfanylaniline —— C11H6ClF6NS
    2-(2-Chloro-3,3,4,4,5,5-hexafluorocyclopenten-1-yl)sulfanylaniline
    —— (R)-(4-methylsulfanylphenyl)-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)methanamine —— C13H17N3OS
    (R)-(4-methylsulfanylphenyl)-(5-propan-2-yl-1,2,4-oxadiazol-3-yl)methanamine
    —— 2-[2-Hydroxy-5-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-4-(2,4,4-trimethylpentan-2-yl)phenol;nickel —— C28H42NiO2S
    2-[2-Hydroxy-5-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-4-(2,4,4-trimethylpentan-2-yl)phenol;nickel
    —— (2S)-2-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylpropanoic acid —— C8H11N3O4S
    (2S)-2-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylpropanoic acid
    —— 2-[[(1S)-1-(4-methylsulfanylphenyl)ethyl]amino]ethanesulfonamide —— C11H18N2O2S2
    2-[[(1S)-1-(4-methylsulfanylphenyl)ethyl]amino]ethanesulfonamide
    —— 5-[(2S)-butan-2-yl]sulfanyl-1,3-dimethylpyrazol-4-amine —— C9H17N3S
    5-[(2S)-butan-2-yl]sulfanyl-1,3-dimethylpyrazol-4-amine
    —— 3-Mercaptononanol —— C9H20OS
    3-Mercaptononanol
    —— 3-Mercaptooctanol —— C8H18OS
    3-Mercaptooctanol
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H18ClN3OS
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (3R)-5-methyl-3-[(4-methylphenyl)sulfanylmethyl]-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-7-one —— C15H16N2OS2
    (3R)-5-methyl-3-[(4-methylphenyl)sulfanylmethyl]-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-7-one