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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[(2S)-butan-2-yl]sulfanylpyridin-4-yl]methanamine —— C10H16N2S
    [2-[(2S)-butan-2-yl]sulfanylpyridin-4-yl]methanamine
    —— [(1R,2R)-2-pyrimidin-2-ylsulfanylcycloheptyl]methanamine —— C12H19N3S
    [(1R,2R)-2-pyrimidin-2-ylsulfanylcycloheptyl]methanamine
    —— [(1R,2R,4R)-4-ethyl-2-(1-methyltetrazol-5-yl)sulfanylcyclohexyl]methanamine —— C11H21N5S
    [(1R,2R,4R)-4-ethyl-2-(1-methyltetrazol-5-yl)sulfanylcyclohexyl]methanamine
    —— [(1R,2S)-2-propylsulfanylcyclopentyl]methanamine —— C9H19NS
    [(1R,2S)-2-propylsulfanylcyclopentyl]methanamine
    —— [(1R,2S)-2-(3,4-difluorophenyl)sulfanylcycloheptyl]methanamine —— C14H19F2NS
    [(1R,2S)-2-(3,4-difluorophenyl)sulfanylcycloheptyl]methanamine
    —— (2R)-3-(3,4-difluorophenyl)sulfanyl-2-methylpropan-1-amine —— C10H13F2NS
    (2R)-3-(3,4-difluorophenyl)sulfanyl-2-methylpropan-1-amine
    —— [(1S,2S)-2-propylsulfanylcycloheptyl]methanamine —— C11H23NS
    [(1S,2S)-2-propylsulfanylcycloheptyl]methanamine
    —— [(1R,2R,4S)-4-ethyl-2-(4-methylphenyl)sulfanylcyclohexyl]methanamine —— C16H25NS
    [(1R,2R,4S)-4-ethyl-2-(4-methylphenyl)sulfanylcyclohexyl]methanamine
    —— [(1R,2R,4S)-2-(2-bromophenyl)sulfanyl-4-methylcyclohexyl]methanamine —— C14H20BrNS
    [(1R,2R,4S)-2-(2-bromophenyl)sulfanyl-4-methylcyclohexyl]methanamine
    —— [(1R,2R)-2-(2-bromophenyl)sulfanylcycloheptyl]methanamine —— C14H20BrNS
    [(1R,2R)-2-(2-bromophenyl)sulfanylcycloheptyl]methanamine
    —— [(1R,2R,4S)-2-(2,4-difluorophenyl)sulfanyl-4-methylcyclohexyl]methanamine —— C14H19F2NS
    [(1R,2R,4S)-2-(2,4-difluorophenyl)sulfanyl-4-methylcyclohexyl]methanamine
    —— [(1S,2R)-2-(2,4-difluorophenyl)sulfanylcyclohexyl]methanamine —— C13H17F2NS
    [(1S,2R)-2-(2,4-difluorophenyl)sulfanylcyclohexyl]methanamine
    —— (2R)-3-ethylsulfanyl-2-methylpropan-1-amine —— C6H15NS
    (2R)-3-ethylsulfanyl-2-methylpropan-1-amine
    —— [(E)-4-amino-3-cyano-2-oxopent-3-enyl] 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C16H13ClN4O4S
    [(E)-4-amino-3-cyano-2-oxopent-3-enyl] 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-4-phenylbutan-2-ylideneamino]triazole-4-carboxamide —— C19H21N11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(Z)-4-phenylbutan-2-ylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(5-chlorothiophen-2-yl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C15H14ClN11O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(5-chlorothiophen-2-yl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-propan-2-ylthiourea —— C12H17N3S2
    1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-propan-2-ylthiourea
    —— ethyl (2S)-2-[1,4-dimethyl-5-[(3-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C19H24N2O3S
    ethyl (2S)-2-[1,4-dimethyl-5-[(3-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(Z)-(3,3,5-trimethylcyclohexylidene)amino]thiourea —— C17H23F2N3S2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(Z)-(3,3,5-trimethylcyclohexylidene)amino]thiourea
    —— ethyl (2R)-2-[1,4-dimethyl-5-[(3-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C19H24N2O3S
    ethyl (2R)-2-[1,4-dimethyl-5-[(3-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylpropanoate
    —— 2-[[5-methyl-4-[(1S)-1-pyridin-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H14N4O2S
    2-[[5-methyl-4-[(1S)-1-pyridin-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-methyl-4-[(1R)-1-pyridin-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H14N4O2S
    2-[[5-methyl-4-[(1R)-1-pyridin-3-ylethyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (6E)-5-imino-2-(4-methylphenyl)-6-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C24H18N4O2S2
    (6E)-5-imino-2-(4-methylphenyl)-6-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(furan-2-yl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(furan-2-yl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]acetamide —— C19H18N4O2S3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]acetamide
    —— (E)-N-(2-tert-butylsulfanylethyl)-3-phenylsulfanylprop-2-enamide —— C15H21NOS2
    (E)-N-(2-tert-butylsulfanylethyl)-3-phenylsulfanylprop-2-enamide
    —— (E)-N-[3-(2-ethylhexoxy)propyl]-3-phenylsulfanylprop-2-enamide —— C20H31NO2S
    (E)-N-[3-(2-ethylhexoxy)propyl]-3-phenylsulfanylprop-2-enamide
    —— N'-[(1Z)-1-(4-chlorophenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C20H19ClN4OS3
    N'-[(1Z)-1-(4-chlorophenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 3-{[(4-chlorophenyl)methyl]sulfanyl}-5-[(E)-2-(dimethylamino)ethenyl]-1,2-thiazole-4-carbonitrile —— C15H14ClN3S2
    3-{[(4-chlorophenyl)methyl]sulfanyl}-5-[(E)-2-(dimethylamino)ethenyl]-1,2-thiazole-4-carbonitrile
    —— methyl N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]carbamate —— C14H14N2O3S
    methyl N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]carbamate
    —— methyl (6S,7R)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C13H14N4O2S
    methyl (6S,7R)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C21H21N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— (3R)-3-(2,5-difluorophenyl)sulfanyl-N'-hydroxypentanimidamide —— C11H14F2N2OS
    (3R)-3-(2,5-difluorophenyl)sulfanyl-N'-hydroxypentanimidamide
    —— 2-(2,5-difluorophenyl)sulfanyl-N'-hydroxypyridine-3-carboximidamide —— C12H9F2N3OS
    2-(2,5-difluorophenyl)sulfanyl-N'-hydroxypyridine-3-carboximidamide
    —— methyl (6R,7S)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C13H14N4O2S
    methyl (6R,7S)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— (7E)-3-[chloro(difluoro)methyl]-6-(2,4-difluorophenyl)-7-[(5-methylthiophen-2-yl)methylidene]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C17H9ClF4N4S2
    (7E)-3-[chloro(difluoro)methyl]-6-(2,4-difluorophenyl)-7-[(5-methylthiophen-2-yl)methylidene]-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— methyl (6S,7R)-6-(4-fluorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C13H13FN4O2S
    methyl (6S,7R)-6-(4-fluorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— (1S,2R)-2-(2,5-difluorophenyl)sulfanylcyclopentane-1-carbonitrile —— C12H11F2NS
    (1S,2R)-2-(2,5-difluorophenyl)sulfanylcyclopentane-1-carbonitrile
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide —— C21H20N4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide
    —— ethyl (Z)-2-cyano-3-[[5-(cyanomethylsulfanyl)-1,3,4-thiadiazol-2-yl]amino]prop-2-enoate —— C10H9N5O2S2
    ethyl (Z)-2-cyano-3-[[5-(cyanomethylsulfanyl)-1,3,4-thiadiazol-2-yl]amino]prop-2-enoate
    —— (1R)-1-[4-(2,5-difluorophenyl)sulfanylphenyl]-N-methylethanamine —— C15H15F2NS
    (1R)-1-[4-(2,5-difluorophenyl)sulfanylphenyl]-N-methylethanamine
    —— (7E)-7-[(2-bromophenyl)methylidene]-3-(difluoromethyl)-6-methyl-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C13H9BrF2N4S
    (7E)-7-[(2-bromophenyl)methylidene]-3-(difluoromethyl)-6-methyl-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S,7R)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylic acid —— C12H12N4O2S
    (6S,7R)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylic acid
    —— 3-(4-chlorophenyl)sulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]propanamide —— C15H15ClN2OS2
    3-(4-chlorophenyl)sulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]propanamide
    —— (NZ)-N-[1-[(4Z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-1-yl]ethylidene]hydroxylamine —— C13H18N2O2S2
    (NZ)-N-[1-[(4Z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-1-yl]ethylidene]hydroxylamine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-1-thiophen-2-ylethylideneamino]triazole-4-carboxamide —— C18H16N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-1-thiophen-2-ylethylideneamino]triazole-4-carboxamide
    —— [(E)-3-chloroallyl]thiourea —— C4H7ClN2S
    [(E)-3-chloroallyl]thiourea
    —— (7E)-3-(difluoromethyl)-6-methyl-7-(thiophen-2-ylmethylidene)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H8F2N4S2
    (7E)-3-(difluoromethyl)-6-methyl-7-(thiophen-2-ylmethylidene)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (11S)-3-(2-methylpropyl)-11-phenyl-7,10-dithia-1,2,4,5-tetrazatricyclo[6.3.0.02,6]undeca-3,5,8-triene —— C15H16N4S2
    (11S)-3-(2-methylpropyl)-11-phenyl-7,10-dithia-1,2,4,5-tetrazatricyclo[6.3.0.02,6]undeca-3,5,8-triene
    —— (2E)-5-amino-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-6,8-dicarbonitrile —— C24H18N4OS3
    (2E)-5-amino-7-(4-methylsulfanylphenyl)-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-7H-[1,3]thiazolo[3,2-a]pyridine-6,8-dicarbonitrile