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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Hydroxy-3-[[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]amino]-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid —— C13H12BN3O5S2
    2-Hydroxy-3-[[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]amino]-3,4-dihydro-1,2-benzoxaborinine-8-carboxylic acid
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-bromophenyl)methylideneamino]propanamide —— C22H23BrN6OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-bromophenyl)methylideneamino]propanamide
    —— (2S)-N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H25ClN6OS
    (2S)-N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-bromophenyl)methylideneamino]propanamide —— C22H23BrN6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-bromophenyl)methylideneamino]propanamide
    —— (2R)-N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H25ClN6OS
    (2R)-N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 4-[(Z)-1,3-diaminoprop-2-enylidene]cyclohexa-2,5-diene-1-thione —— C9H10N2S
    4-[(Z)-1,3-diaminoprop-2-enylidene]cyclohexa-2,5-diene-1-thione
    —— 5-hydroperoxy-N-methyl-2-methylsulfanylpyrimidin-4-amine —— C6H9N3O2S
    5-hydroperoxy-N-methyl-2-methylsulfanylpyrimidin-4-amine
    —— 3-(3,5,7,9,11,13,15-Heptamethyl-2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1-yl)propane-1-thiol —— C10H28O12SSi8
    3-(3,5,7,9,11,13,15-Heptamethyl-2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1-yl)propane-1-thiol
    —— cyclooctylcarbamothioic S-acid —— C9H17NOS
    cyclooctylcarbamothioic S-acid
    —— 2-[[5-[(1R)-1-(3-chloroanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide —— C24H30ClN7OS
    2-[[5-[(1R)-1-(3-chloroanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide
    —— 2-[[5-[(1S)-1-(3-chloroanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide —— C24H30ClN7OS
    2-[[5-[(1S)-1-(3-chloroanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide
    —— 2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide —— C23H28ClN7OS
    2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]acetamide
    —— 1-Fluoro-4-[4-fluoro-3-(trifluoromethyl)phenyl]sulfanyl-2-(trifluoromethyl)benzene —— C14H6F8S
    1-Fluoro-4-[4-fluoro-3-(trifluoromethyl)phenyl]sulfanyl-2-(trifluoromethyl)benzene
    —— 2-[(5,6-Diaminopyrimidin-4-yl)sulfanyl]-5-nitrobenzonitrile —— C11H8N6O2S
    2-[(5,6-Diaminopyrimidin-4-yl)sulfanyl]-5-nitrobenzonitrile
    —— N,N-dichloro-2-propylsulfanylpyrimidin-5-amine —— C7H9Cl2N3S
    N,N-dichloro-2-propylsulfanylpyrimidin-5-amine
    —— 2-(1-Methylpyrazol-4-yl)-4-propan-2-yl-4,5-dihydro-1,3-thiazole —— C10H15N3S
    2-(1-Methylpyrazol-4-yl)-4-propan-2-yl-4,5-dihydro-1,3-thiazole
    —— N,N'-Bis-(4-methylsulfanyl-benzylidene)-hydrazine —— C16H16N2S2
    N,N'-Bis-(4-methylsulfanyl-benzylidene)-hydrazine
    —— Tert-butyl 3,6-bis[(4-fluorophenyl)sulfanyl]pyridine-2-carboxylate —— C22H19F2NO2S2
    Tert-butyl 3,6-bis[(4-fluorophenyl)sulfanyl]pyridine-2-carboxylate
    —— Ethyl 2-[[2-[[3-(4-fluorophenyl)sulfanyl-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyridine-2-carbonyl]amino]-1,3-thiazol-5-yl]sulfanyl]acetate —— C22H19FN6O3S4
    Ethyl 2-[[2-[[3-(4-fluorophenyl)sulfanyl-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyridine-2-carbonyl]amino]-1,3-thiazol-5-yl]sulfanyl]acetate
    —— (2Z,4Z)-4-methylhepta-2,4-diene-2-thiol —— C8H14S
    (2Z,4Z)-4-methylhepta-2,4-diene-2-thiol
    —— 2-(2,4-dichlorophenoxy)-N'-[5-nitro-2-(phenylsulfanyl)benzylidene]acetohydrazide —— C21H15Cl2N3O4S
    2-(2,4-dichlorophenoxy)-N'-[5-nitro-2-(phenylsulfanyl)benzylidene]acetohydrazide
    —— Methyl 2-[ethoxy(methylsulfanyl)methyl]sulfanylpropanoate —— C8H16O3S2
    Methyl 2-[ethoxy(methylsulfanyl)methyl]sulfanylpropanoate
    —— N-ethenylsulfanylthiohydroxylamine —— C2H5NS2
    N-ethenylsulfanylthiohydroxylamine
    —— (Methylsulfonimidoyl) hypofluorite —— CH4FNO2S
    (Methylsulfonimidoyl) hypofluorite
    —— Ethyl 2-({2-[({6-chloro-3-[(4-methoxyphenyl)sulfanyl]pyridin-2-yl}carbonyl)amino]-1,3-thiazol-5-yl}sulfanyl)-2-methylpropanoate —— C22H22ClN3O4S3
    Ethyl 2-({2-[({6-chloro-3-[(4-methoxyphenyl)sulfanyl]pyridin-2-yl}carbonyl)amino]-1,3-thiazol-5-yl}sulfanyl)-2-methylpropanoate
    —— 6-[(4-Methyl-1,2,4-triazol-3-yl)sulfanyl]-3-[4-(trifluoromethyl)phenyl]sulfanylpyridine-2-carboxylic acid —— C16H11F3N4O2S2
    6-[(4-Methyl-1,2,4-triazol-3-yl)sulfanyl]-3-[4-(trifluoromethyl)phenyl]sulfanylpyridine-2-carboxylic acid
    —— Ethyl 3-[5-[[3-(4-fluorophenyl)sulfanyl-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyridine-2-carbonyl]amino]thiophen-2-yl]sulfanyl-2,2-dimethylpentanoate —— C28H30FN5O3S4
    Ethyl 3-[5-[[3-(4-fluorophenyl)sulfanyl-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyridine-2-carbonyl]amino]thiophen-2-yl]sulfanyl-2,2-dimethylpentanoate
    —— 3-[5-[[3-(4-Fluorophenyl)sulfanyl-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyridine-2-carbonyl]amino]thiophen-2-yl]sulfanyl-2,2-dimethylpropanoic acid —— C24H22FN5O3S4
    3-[5-[[3-(4-Fluorophenyl)sulfanyl-6-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyridine-2-carbonyl]amino]thiophen-2-yl]sulfanyl-2,2-dimethylpropanoic acid
    —— 3-(4-Fluorophenyl)sulfanyl-6-pyridin-2-ylsulfanylpyridine-2-carboxylic acid —— C17H11FN2O2S2
    3-(4-Fluorophenyl)sulfanyl-6-pyridin-2-ylsulfanylpyridine-2-carboxylic acid
    —— 6-Chloro-3-(4-methoxyphenyl)sulfanylpyridine-2-carboxylic acid —— C13H10ClNO3S
    6-Chloro-3-(4-methoxyphenyl)sulfanylpyridine-2-carboxylic acid
    —— 6-Chloro-3-(4-fluorophenyl)sulfanylpyridine-2-carboxylic acid —— C12H7ClFNO2S
    6-Chloro-3-(4-fluorophenyl)sulfanylpyridine-2-carboxylic acid
    —— 3,10-Bis(aminomethyl)dodecane-3,10-dithiol —— C14H32N2S2
    3,10-Bis(aminomethyl)dodecane-3,10-dithiol
    —— 4-Methyl-6-(methylamino)-2-methylsulfanylpyrimidine-5-carbonitrile —— C8H10N4S
    4-Methyl-6-(methylamino)-2-methylsulfanylpyrimidine-5-carbonitrile
    —— 2-Methoxy-3-prop-2-enoxysulfanylprop-1-ene —— C7H12O2S
    2-Methoxy-3-prop-2-enoxysulfanylprop-1-ene
    —— 2-[(Z)-2-hydroxy-4-oxopent-2-en-3-yl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile —— C13H14N2O2S
    2-[(Z)-2-hydroxy-4-oxopent-2-en-3-yl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— (Z)-1-(4-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12BrClN4S
    (Z)-1-(4-bromophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine —— C14H11ClN4S2
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine
    —— (Z)-1-(5-bromofuran-2-yl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C14H10BrClN4OS
    (Z)-1-(5-bromofuran-2-yl)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine —— C15H12ClN5S
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine
    —— (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine —— C15H13ClN4OS
    (Z)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(5-methylfuran-2-yl)methanimine
    —— 1-(Disulfanyl)but-1-ene —— C4H8S2
    1-(Disulfanyl)but-1-ene
    —— 6-[(S)-5-(3-amino-propyl)-2-oxo-oxazolidin-3-yl]-4H-pyrido[3,2-b][1,4]thiazin-3-one 1422209-67-3 C13H16N4O3S
    6-[(S)-5-(3-amino-propyl)-2-oxo-oxazolidin-3-yl]-4H-pyrido[3,2-b][1,4]thiazin-3-one
    —— 6-((S)-5-aminomethyl-2-oxo-oxazolidin-3-yl)-4H-pyrido[3,2-b][1,4]thiazin-3-one 1422210-05-6 C11H12N4O3S
    6-((S)-5-aminomethyl-2-oxo-oxazolidin-3-yl)-4H-pyrido[3,2-b][1,4]thiazin-3-one
    —— 5-(azidomethyl)-3-(3-oxo-4H-pyrido[3,2-b][1,4]thiazin-6-yl)-1,3-oxazolidin-2-one —— C11H10N6O3S
    5-(azidomethyl)-3-(3-oxo-4H-pyrido[3,2-b][1,4]thiazin-6-yl)-1,3-oxazolidin-2-one
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide —— C10H9N5O4S
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide
    —— [[Azanylidyne(methyl)-lambda6-sulfanylidene]amino]-(diazenyldiazenyl)diazene —— CH4N8S
    [[Azanylidyne(methyl)-lambda6-sulfanylidene]amino]-(diazenyldiazenyl)diazene
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C10H9N5O3S2
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[(Z)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide —— C15H15N5O3S
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[(Z)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide
    —— 5-ethenyl-N-methyl-2-methylsulfanylpyrimidin-4-amine —— C8H11N3S
    5-ethenyl-N-methyl-2-methylsulfanylpyrimidin-4-amine
    —— N-[(Z)-[4-[(4-ethyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]furan-2-carboxamide —— C22H18N6O4S
    N-[(Z)-[4-[(4-ethyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]furan-2-carboxamide