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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-[(2Z)-3,3-dimethylbutan-2-ylidene]-2-(pyrimidin-2-ylsulfanyl)propanehydrazide —— C13H20N4OS
    N'-[(2Z)-3,3-dimethylbutan-2-ylidene]-2-(pyrimidin-2-ylsulfanyl)propanehydrazide
    —— (2Z,5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(4-ethoxyphenyl)imino]-1,3-thiazolidin-4-one —— C22H17ClN2O3S2
    (2Z,5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(4-ethoxyphenyl)imino]-1,3-thiazolidin-4-one
    —— tris[5-(1H-pyrazol-5-ylsulfanyl)-1H-imidazol-2-yl]borane —— C18H15BN12S3
    tris[5-(1H-pyrazol-5-ylsulfanyl)-1H-imidazol-2-yl]borane
    —— N-[(Z)-cyclohex-3-en-1-ylmethylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H17N3OS
    N-[(Z)-cyclohex-3-en-1-ylmethylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C21H19ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— (Z)-1-(furan-2-yl)-N-(3-propylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)methanimine —— C11H12N6OS
    (Z)-1-(furan-2-yl)-N-(3-propylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)methanimine
    —— 3-Methyl-5-methylsulfanylpent-2-ene —— C7H14S
    3-Methyl-5-methylsulfanylpent-2-ene
    —— (4-methoxyphenyl) N-[imidazo[1,2-b]pyridazin-3-yl-(2-methyl-6-phenylsulfanylphenyl)methyl]carbamate —— C28H24N4O3S
    (4-methoxyphenyl) N-[imidazo[1,2-b]pyridazin-3-yl-(2-methyl-6-phenylsulfanylphenyl)methyl]carbamate
    —— (5Z)-4,5-bis(phenylsulfanylmethylidene)pyrazolidin-3-one —— C17H14N2OS2
    (5Z)-4,5-bis(phenylsulfanylmethylidene)pyrazolidin-3-one
    —— (E)-1-[2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-5-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C17H14N8O3S
    (E)-1-[2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-5-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— (2R)-2-aminopropanal;ethane;methylsulfanylmethane —— C13H33N3O3S
    (2R)-2-aminopropanal;ethane;methylsulfanylmethane
    —— [(1S,2R,4S)-4-(methylcarbamothioyl)-2-[(2-methylpropan-2-yl)oxycarbonylamino]cyclohexyl]carbamic acid —— C14H25N3O4S
    [(1S,2R,4S)-4-(methylcarbamothioyl)-2-[(2-methylpropan-2-yl)oxycarbonylamino]cyclohexyl]carbamic acid
    —— 1-Ethylsulfanyl-4,4,5,5,6,6,6-heptafluorohex-2-ene —— C8H9F7S
    1-Ethylsulfanyl-4,4,5,5,6,6,6-heptafluorohex-2-ene
    —— N-[3-chloro-4-(3-methylphenyl)sulfanylphenyl]-6-[2-[(2R)-pyrrolidin-2-yl]ethynyl]thieno[2,3-d]pyrimidin-4-amine —— C25H21ClN4S2
    N-[3-chloro-4-(3-methylphenyl)sulfanylphenyl]-6-[2-[(2R)-pyrrolidin-2-yl]ethynyl]thieno[2,3-d]pyrimidin-4-amine
    —— 1,1,4-Trimethyl-4-methylsulfonylcyclohexane —— C10H20O2S
    1,1,4-Trimethyl-4-methylsulfonylcyclohexane
    —— 2-Methyl-4-methylidene-1-methylsulfinylcyclohexane —— C9H16OS
    2-Methyl-4-methylidene-1-methylsulfinylcyclohexane
    —— 5-[(6,8-dimethyl-7,8-dihydro-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)sulfanyl]-6-methyl-1H-benzimidazol-2-amine —— C15H17N7S
    5-[(6,8-dimethyl-7,8-dihydro-[1,2,4]triazolo[4,3-b]pyridazin-3-yl)sulfanyl]-6-methyl-1H-benzimidazol-2-amine
    —— 2-[(6-methyl-1H-benzimidazol-2-yl)sulfanyl]-1H-[1,2,4]triazolo[1,5-a]pyrimidin-7-one —— C13H10N6OS
    2-[(6-methyl-1H-benzimidazol-2-yl)sulfanyl]-1H-[1,2,4]triazolo[1,5-a]pyrimidin-7-one
    —— [(2R)-2-[[5-[[(2,3-difluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]propyl]carbamic acid 1,1-dimethylethyl ester 333743-25-2 C21H25F2N5O3S2
    [(2R)-2-[[5-[[(2,3-difluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]propyl]carbamic acid 1,1-dimethylethyl ester
    —— 3-(2-Ethyl-1,3-dioxolan-2-yl)-1-(3-methylsulfanylphenyl)propan-1-ol —— C15H22O3S
    3-(2-Ethyl-1,3-dioxolan-2-yl)-1-(3-methylsulfanylphenyl)propan-1-ol
    —— ethyl N-[methylidene-[4-[(4-methylsulfanyl-5-thiophen-2-ylpyrimidin-2-yl)amino]phenyl]-oxo-lambda6-sulfanyl]carbamate —— C19H20N4O3S3
    ethyl N-[methylidene-[4-[(4-methylsulfanyl-5-thiophen-2-ylpyrimidin-2-yl)amino]phenyl]-oxo-lambda6-sulfanyl]carbamate
    —— Ethane;2-(5-methylpyrazolo[1,5-a]pyridin-3-yl)-5-phenylsulfanyl-1,3,4-oxadiazole —— C18H18N4OS
    Ethane;2-(5-methylpyrazolo[1,5-a]pyridin-3-yl)-5-phenylsulfanyl-1,3,4-oxadiazole
    —— 6-[(2,6-dimethylanilino)methylidene]-2-methyl-4-phenylsulfanylcyclohexa-2,4-diene-1-thione;N-(2,6-dimethylphenyl)-1-(3,4,5-trimethyl-2-triethylsilylsulfanylphenyl)methanimine —— C46H56N2S3Si
    6-[(2,6-dimethylanilino)methylidene]-2-methyl-4-phenylsulfanylcyclohexa-2,4-diene-1-thione;N-(2,6-dimethylphenyl)-1-(3,4,5-trimethyl-2-triethylsilylsulfanylphenyl)methanimine
    —— 3-Methyl-4-[(1-propylimidazol-2-yl)methylsulfanyl]aniline —— C14H19N3S
    3-Methyl-4-[(1-propylimidazol-2-yl)methylsulfanyl]aniline
    —— N-[(Z)-(2-bromophenyl)methylideneamino]-3-(4-chlorophenyl)sulfanylpropanamide —— C16H14BrClN2OS
    N-[(Z)-(2-bromophenyl)methylideneamino]-3-(4-chlorophenyl)sulfanylpropanamide
    —— 5-(Methyldisulfanyl)-2-methylsulfanyl-1,3-thiazole —— C5H7NS4
    5-(Methyldisulfanyl)-2-methylsulfanyl-1,3-thiazole
    —— [4-[4-[Phenylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C31H30N2O3S
    [4-[4-[Phenylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 1-But-1-ynyl-3-(2-ethylbutylsulfanyl)benzene —— C16H22S
    1-But-1-ynyl-3-(2-ethylbutylsulfanyl)benzene
    —— 1-Cyclopropyl-3-(5-iminocyclohex-2-en-1-yl)thiourea —— C10H15N3S
    1-Cyclopropyl-3-(5-iminocyclohex-2-en-1-yl)thiourea
    —— 1-Sulfanylpent-3-en-1-ol —— C5H10OS
    1-Sulfanylpent-3-en-1-ol
    —— 2-Amino-6-sulfanylhexanal —— C6H13NOS
    2-Amino-6-sulfanylhexanal
    —— 2-[4-(4-chlorophenyl)sulfanyl-7-fluoro-8-propan-2-yl-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]acetic acid —— C22H21ClFNO2S
    2-[4-(4-chlorophenyl)sulfanyl-7-fluoro-8-propan-2-yl-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]acetic acid
    —— 1-[2-Diazo-1-(2-methylpropylsulfonyl)ethyl]sulfonyl-2-methylpropane —— C10H20N2O4S2
    1-[2-Diazo-1-(2-methylpropylsulfonyl)ethyl]sulfonyl-2-methylpropane
    —— 4-[7-cyano-2-methyl-3-(2-oxoethyl)indolizin-1-yl]sulfanyl-N-cyclopropylbenzenesulfonamide —— C21H19N3O3S2
    4-[7-cyano-2-methyl-3-(2-oxoethyl)indolizin-1-yl]sulfanyl-N-cyclopropylbenzenesulfonamide
    —— 2-[2-(5-Tert-butyl-3-methylthiophen-2-yl)ethenyl]-5-[(5-tert-butyl-2-methylthiophen-3-yl)sulfanylmethyl]-3-methylthiophene —— C26H34S4
    2-[2-(5-Tert-butyl-3-methylthiophen-2-yl)ethenyl]-5-[(5-tert-butyl-2-methylthiophen-3-yl)sulfanylmethyl]-3-methylthiophene
    —— 2,2,4-Trimethyl-4-methylsulfonylhexane —— C10H22O2S
    2,2,4-Trimethyl-4-methylsulfonylhexane
    —— 3-chloro-4-methyl-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]aniline —— C18H14ClN5O2S
    3-chloro-4-methyl-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]aniline
    —— ethane;(Z)-1-methylsulfanylprop-1-ene —— C10H26S
    ethane;(Z)-1-methylsulfanylprop-1-ene
    —— 3-(Disulfanyl)-6-methylsulfanylpyridazine —— C5H6N2S3
    3-(Disulfanyl)-6-methylsulfanylpyridazine
    —— 3-Ethyl-1-ethylsulfanyl-4,4,5,5,5-pentafluoropent-2-ene —— C9H13F5S
    3-Ethyl-1-ethylsulfanyl-4,4,5,5,5-pentafluoropent-2-ene
    —— 4-(4-hydroxyphenyl)sulfanyl-N-[[2-(1,2,3,6-tetrahydropyridin-4-yl)phenyl]methyl]pentanamide —— C23H28N2O2S
    4-(4-hydroxyphenyl)sulfanyl-N-[[2-(1,2,3,6-tetrahydropyridin-4-yl)phenyl]methyl]pentanamide
    —— 3-Methylsulfonylhexa-2,4-diene —— C7H12O2S
    3-Methylsulfonylhexa-2,4-diene
    —— 2-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]ethanethioic S-acid —— C18H20N4OS2
    2-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]ethanethioic S-acid
    —— 1,1,1,2-Tetrakis(ethylsulfanyl)ethane —— C10H22S4
    1,1,1,2-Tetrakis(ethylsulfanyl)ethane
    —— [1-[[2-Amino-6-(4-methylphenyl)sulfanylpurin-9-yl]methyl]cyclopropyl]peroxy-(1,1,1,5,5,5-hexafluoropentan-3-yl)phosphinic acid —— C21H22F6N5O4PS
    [1-[[2-Amino-6-(4-methylphenyl)sulfanylpurin-9-yl]methyl]cyclopropyl]peroxy-(1,1,1,5,5,5-hexafluoropentan-3-yl)phosphinic acid
    —— (2Z,5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(4-methylphenyl)imino]-1,3-thiazolidin-4-one —— C21H15ClN2O2S2
    (2Z,5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-[(4-methylphenyl)imino]-1,3-thiazolidin-4-one
    —— 3-Methylsulfanyloxypropan-1-amine —— C4H11NOS
    3-Methylsulfanyloxypropan-1-amine
    —— 1-(2-bromophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C20H20BrN3S
    1-(2-bromophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— 1-(2,4-dimethylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C22H25N3S
    1-(2,4-dimethylphenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— (E)-3-amino-2-[2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]but-2-enenitrile —— C14H13N5OS2
    (E)-3-amino-2-[2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]but-2-enenitrile