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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (NZ)-N-[(2-tert-butylsulfanylphenyl)methylidene]hydroxylamine —— C11H15NOS
    (NZ)-N-[(2-tert-butylsulfanylphenyl)methylidene]hydroxylamine
    —— (Z)-1-(2-tert-butylsulfanylphenyl)-N-[(2,3,4,5,6-pentamethylphenyl)methoxy]methanimine —— C23H31NOS
    (Z)-1-(2-tert-butylsulfanylphenyl)-N-[(2,3,4,5,6-pentamethylphenyl)methoxy]methanimine
    —— N'-[2-[2-(7-aminoheptylamino)ethyldisulfanyl]ethyl]heptane-1,7-diamine;hydrochloride —— C18H43ClN4S2
    N'-[2-[2-(7-aminoheptylamino)ethyldisulfanyl]ethyl]heptane-1,7-diamine;hydrochloride
    —— (E)-2-[4-methyl-5-[(2,3,4,5,6-pentamethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-3-thiophen-2-ylprop-2-enenitrile —— C22H24N4S2
    (E)-2-[4-methyl-5-[(2,3,4,5,6-pentamethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-3-thiophen-2-ylprop-2-enenitrile
    —— (E)-2-[4-methyl-5-[(2,3,4,5,6-pentamethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-3-pyridin-2-ylprop-2-enenitrile —— C23H25N5S
    (E)-2-[4-methyl-5-[(2,3,4,5,6-pentamethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]-3-pyridin-2-ylprop-2-enenitrile
    —— (4Z)-4-[(4-chlorophenyl)methylidene]-2-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-1,3-oxazol-5-one —— C21H12Cl2N2O2S
    (4Z)-4-[(4-chlorophenyl)methylidene]-2-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-1,3-oxazol-5-one
    —— 3-[4-(trifluoromethylsulfanyl)phenyl]-4,5-dihydro-2H-benzo[g][1,2]benzoxazol-7-one —— C18H12F3NO2S
    3-[4-(trifluoromethylsulfanyl)phenyl]-4,5-dihydro-2H-benzo[g][1,2]benzoxazol-7-one
    —— [(Z)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(3-methylphenyl)carbamate —— C14H12Cl2N4O2S
    [(Z)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(3-methylphenyl)carbamate
    —— (4Z)-2-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-4-[(4-methylphenyl)methylidene]-1,3-oxazol-5-one —— C22H15ClN2O2S
    (4Z)-2-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-4-[(4-methylphenyl)methylidene]-1,3-oxazol-5-one
    —— [(Z)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(4-chlorophenyl)carbamate —— C13H9Cl3N4O2S
    [(Z)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(4-chlorophenyl)carbamate
    —— (4Z)-2-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-4-[[4-(trifluoromethyl)phenyl]methylidene]-1,3-oxazol-5-one —— C22H12ClF3N2O2S
    (4Z)-2-[2-(4-chlorophenyl)sulfanylpyridin-3-yl]-4-[[4-(trifluoromethyl)phenyl]methylidene]-1,3-oxazol-5-one
    —— [(Z)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-phenylcarbamate —— C13H10Cl2N4O2S
    [(Z)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-phenylcarbamate
    —— (Z)-4-tert-butyl-3-(3-methylsulfanylphenyl)-N-pyridin-2-yl-1,3-thiazol-2-imine —— C19H21N3S2
    (Z)-4-tert-butyl-3-(3-methylsulfanylphenyl)-N-pyridin-2-yl-1,3-thiazol-2-imine
    —— 4-[5-(Methylthio)-2-thienyl]but-3-en-2-one —— C9H10OS2
    4-[5-(Methylthio)-2-thienyl]but-3-en-2-one
    —— 1-[(Z)-(2-tert-butylsulfanylphenyl)methylideneamino]-3-(2-methylbutan-2-yl)thiourea —— C17H27N3S2
    1-[(Z)-(2-tert-butylsulfanylphenyl)methylideneamino]-3-(2-methylbutan-2-yl)thiourea
    —— 1-tert-butyl-3-[(Z)-(2-tert-butylsulfanylphenyl)methylideneamino]thiourea —— C16H25N3S2
    1-tert-butyl-3-[(Z)-(2-tert-butylsulfanylphenyl)methylideneamino]thiourea
    —— 2-(4-Methylsulfanylphenyl)-[1,3]thiazolo[3,2-a]pyridin-4-ium;perchlorate;hydrate —— C14H14ClNO5S2
    2-(4-Methylsulfanylphenyl)-[1,3]thiazolo[3,2-a]pyridin-4-ium;perchlorate;hydrate
    —— 6-methyl-5-[(2Z)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]-2H-1,2,4-triazin-3-one —— C12H13N5OS
    6-methyl-5-[(2Z)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]-2H-1,2,4-triazin-3-one
    —— (Z)-but-2-enedioic acid;1-(2,6-ditert-butyl-4-phenylsulfanylphenoxy)-3-(propan-2-ylamino)propan-2-ol —— C30H43NO6S
    (Z)-but-2-enedioic acid;1-(2,6-ditert-butyl-4-phenylsulfanylphenoxy)-3-(propan-2-ylamino)propan-2-ol
    —— 3-[(3-Hydroxy-2,3-dimethylbutan-2-yl)oxy-(6-methylsulfanylpyridin-3-yl)boranyl]oxy-2,3-dimethylbutan-2-ol —— C18H32BNO4S
    3-[(3-Hydroxy-2,3-dimethylbutan-2-yl)oxy-(6-methylsulfanylpyridin-3-yl)boranyl]oxy-2,3-dimethylbutan-2-ol
    —— 4-N-butyl-4-N-ethyl-5-ethylsulfanyl-6-N-(2,4,6-trimethylphenyl)pyrimidine-4,6-diamine —— C21H32N4S
    4-N-butyl-4-N-ethyl-5-ethylsulfanyl-6-N-(2,4,6-trimethylphenyl)pyrimidine-4,6-diamine
    —— (1E)-2-[6-[[amino-[(E)-[amino-(4-pentylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-pentylsulfanylanilino)methylidene]guanidine 7211-10-1 C32H52N10S2
    (1E)-2-[6-[[amino-[(E)-[amino-(4-pentylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-pentylsulfanylanilino)methylidene]guanidine
    —— (1E)-2-[6-[[amino-[(E)-[amino-(4-butylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-butylsulfanylanilino)methylidene]guanidine 7211-09-8 C30H48N10S2
    (1E)-2-[6-[[amino-[(E)-[amino-(4-butylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-butylsulfanylanilino)methylidene]guanidine
    —— 2-[6-[[Amino-[[amino-(4-propylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-propylsulfanylanilino)methylidene]guanidine 7211-08-7 C28H44N10S2
    2-[6-[[Amino-[[amino-(4-propylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-propylsulfanylanilino)methylidene]guanidine
    —— 2-[6-[[Amino-[[amino-(4-ethylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-ethylsulfanylanilino)methylidene]guanidine 7238-23-5 C26H40N10S2
    2-[6-[[Amino-[[amino-(4-ethylsulfanylanilino)methylidene]amino]methylidene]amino]hexyl]-1-[amino-(4-ethylsulfanylanilino)methylidene]guanidine
    —— (3S)-3-amino-4-(1H-imidazol-5-yl)-1-(4-methylphenyl)sulfanylbutan-2-one;hydrochloride —— C14H18ClN3OS
    (3S)-3-amino-4-(1H-imidazol-5-yl)-1-(4-methylphenyl)sulfanylbutan-2-one;hydrochloride
    —— 4-amino-3-(methylthio)-6-[2-(2-thienyl)vinyl]-1,2,4-triazin-5(4H)-one —— C10H10N4OS2
    4-amino-3-(methylthio)-6-[2-(2-thienyl)vinyl]-1,2,4-triazin-5(4H)-one
    —— 4-(3-Aminopropylsulfanyl)butan-1-amine;dihydrochloride —— C7H20Cl2N2S
    4-(3-Aminopropylsulfanyl)butan-1-amine;dihydrochloride
    —— (2S)-2-amino-4-methylpentane-1-thiol;dihydrochloride —— C6H17Cl2NS
    (2S)-2-amino-4-methylpentane-1-thiol;dihydrochloride
    —— 3,3-Dimethyl-1-(1-oxo-pyridin-2-yl)thio-2-butanone O-Methylcarbamyloxime —— C13H19N3O3S
    3,3-Dimethyl-1-(1-oxo-pyridin-2-yl)thio-2-butanone O-Methylcarbamyloxime
    —— (NE)-N-[3,3-dimethyl-1-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-2-ylidene]hydroxylamine —— C11H16N2O2S
    (NE)-N-[3,3-dimethyl-1-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-2-ylidene]hydroxylamine
    —— [(E)-[3,3-dimethyl-1-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-2-ylidene]amino] N-phenylcarbamate —— C18H21N3O3S
    [(E)-[3,3-dimethyl-1-(1-oxidopyridin-1-ium-2-yl)sulfanylbutan-2-ylidene]amino] N-phenylcarbamate
    —— (Z)-N-methoxy-2-methyl-2-phenylsulfanylpropan-1-imine —— C11H15NOS
    (Z)-N-methoxy-2-methyl-2-phenylsulfanylpropan-1-imine
    —— azane;(E)-3-phenylsulfanylprop-2-enoic acid —— C9H11NO2S
    azane;(E)-3-phenylsulfanylprop-2-enoic acid
    —— (Z)-N-methoxy-2-methyl-2-(4-methylphenyl)sulfanylpropan-1-imine —— C12H17NOS
    (Z)-N-methoxy-2-methyl-2-(4-methylphenyl)sulfanylpropan-1-imine
    —— (NZ)-N-(2-methyl-2-phenylsulfanylpropylidene)hydroxylamine —— C10H13NOS
    (NZ)-N-(2-methyl-2-phenylsulfanylpropylidene)hydroxylamine
    —— (Z)-2-(4-chlorophenyl)sulfanyl-N-methoxy-2-methylpropan-1-imine —— C11H14ClNOS
    (Z)-2-(4-chlorophenyl)sulfanyl-N-methoxy-2-methylpropan-1-imine
    —— (2E)-3-chloro-2-[(4-chlorophenyl)sulfanyl-nitrosomethylidene]-5-(trifluoromethyl)-1H-pyridine —— C13H7Cl2F3N2OS
    (2E)-3-chloro-2-[(4-chlorophenyl)sulfanyl-nitrosomethylidene]-5-(trifluoromethyl)-1H-pyridine
    —— (E)-4-(6-benzylsulfanylimidazo[2,1-b][1,3]thiazol-5-yl)but-3-en-2-one —— C16H14N2OS2
    (E)-4-(6-benzylsulfanylimidazo[2,1-b][1,3]thiazol-5-yl)but-3-en-2-one
    —— 4-chloro-N-[(E)-[5-(4-methylphenyl)sulfanyl-2-phenylimidazol-4-ylidene]methyl]aniline —— C23H18ClN3S
    4-chloro-N-[(E)-[5-(4-methylphenyl)sulfanyl-2-phenylimidazol-4-ylidene]methyl]aniline
    —— 2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-7-(4-isopropylstyryl)[1,2,4]triazolo[1,5-a]pyrimidine —— C22H17ClF3N5S
    2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-7-(4-isopropylstyryl)[1,2,4]triazolo[1,5-a]pyrimidine
    —— N-[6-[5-(oxidodiazenyl)pyridin-2-yl]sulfanylpyridin-3-yl]nitrous amide —— C10H7N6O2S-
    N-[6-[5-(oxidodiazenyl)pyridin-2-yl]sulfanylpyridin-3-yl]nitrous amide
    —— (Z)-methyl 2-(1-(4-(phenylthio)phenyl)ethylidene)hydrazinecarboxylate —— C16H16N2O2S
    (Z)-methyl 2-(1-(4-(phenylthio)phenyl)ethylidene)hydrazinecarboxylate
    —— 5-Acetyl-2-(2-butenylsulfanyl)-6-methylnicotinonitrile —— C13H14N2OS
    5-Acetyl-2-(2-butenylsulfanyl)-6-methylnicotinonitrile
    —— 2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-7-(4-methoxystyryl)[1,2,4]triazolo[1,5-a]pyrimidine —— C20H13ClF3N5OS
    2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-7-(4-methoxystyryl)[1,2,4]triazolo[1,5-a]pyrimidine
    —— (E)-4-(4-chlorophenylthio)-3-nitrobenzaldehyde O-4-nitrobenzyl oxime —— C20H14ClN3O5S
    (E)-4-(4-chlorophenylthio)-3-nitrobenzaldehyde O-4-nitrobenzyl oxime
    —— (E)-3-nitro-4-(3-(trifluoromethyl)phenylthio)benzaldehyde O-2,6-dichlorobenzyl oxime —— C21H13Cl2F3N2O3S
    (E)-3-nitro-4-(3-(trifluoromethyl)phenylthio)benzaldehyde O-2,6-dichlorobenzyl oxime
    —— 4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-(3,4-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-((4-Chlorophenyl)sulfanyl)-3-nitrobenzenecarbaldehydeo-(3,4-dichlorobenzyl)oxime
    —— 2-{[2-hydroxy-1-(hydroxymethyl)ethyl]amino}-5-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-1,3-thiazol-4(5H)-one —— C14H16N2O3S2
    2-{[2-hydroxy-1-(hydroxymethyl)ethyl]amino}-5-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-1,3-thiazol-4(5H)-one
    —— (E)-3-nitro-4-(3-(trifluoromethyl)phenylthio)benzaldehyde O-3,4-dichlorobenzyl oxime —— C21H13Cl2F3N2O3S
    (E)-3-nitro-4-(3-(trifluoromethyl)phenylthio)benzaldehyde O-3,4-dichlorobenzyl oxime